Santite

KB5O6(OH)4 · 2H2O
IMA status
  • Approved
IMA symbol
Snt
Discovered
1970
Also known as
  • IMA1969-044
  • Santiet

Where it forms, where it's found

Type locality
Larderello
  1. Pomarance
  2. Pisa Province
  3. Tuscany
  4. Italy

43.2333°, 10.8667°

4recorded occurrences
Source · OpenStreetMap

Physical

Transparency
Transparent
Colour
Colourless
Density
1.74 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 70°
Refractive index
1.422 – 1.48
Surface relief
Low
Principal indices
nα 1.422 · nβ 1.435 · nγ 1.480
Dispersion
relatively strong
Michel-Lévy diagramhighlighted lineδ = 0.0580
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]580 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation580 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
#16
Cell parameters
a = 11.10(2) Å · b = 11.18(2) Å · c = 9.08(2) Å
Ratio a:b:c
1 : 1.007 : 0.818
Z
4
Morphology

aggregates; as an efflorescent crust.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1215.999191.988
65.48%
5BBoronBoron510.81054.050
18.43%
19KPotassiumPotassium139.09839.098
13.34%
1HHydrogenHydrogen81.0088.064
2.75%
Total293.200100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1969-044
  • Santiet

In other languages

French
santite
German
IMA 1969-044 · Santit
Italian
Santite
Arabic
سانتايت · سانتيت

Classification

Strunz
10th ed.

6.EA.10

  • 6BoratesClass
  • 6.EPentaboratesDivision
  • 6.EANeso-pentaboratesGroup
  • 6.EA.10SantiteSpecies
Dana
8th ed.

26.05.02.01

  • 26Hydrated Borates Containing Hydroxyl or HalogenClass
  • 26.05PentaboratesType
  • 26.05.02Santite GroupGroup
  • 26.05.02.01SantiteSpecies
CIM

9.1.13

  • 9BoratesClass
  • 9.1Borates of the alkalis and boric acidGroup
  • 9.1.13SantiteSpecies

Group, growth & confusion

In the same group
1 members

Literature, links & citation

Citations
  1. 1938Zachariasen, W. H. (1938) The Crystal Structure of Potassium Acid Dihydronium Pentaborate KH2(H3Ο)2B5O10, (Potassium Pentaborate Tetrahydrate). Zeitschrift für Kristallographie, 98 (1-6). 266-274 doi:10.1524/zkri.1938.98.1.266 DOI: 10.1524/zkri.1938.98.1.266
  2. 1963Zachariasen, W. H., Plettinger, H. A. (1963) Refinement of the structure of potassium pentaborate tetrahydrate. Acta Crystallographica, 16 (5) 376-379 doi:10.1107/s0365110x63001006DOI: 10.1107/s0365110x63001006
  3. 1963Marezio, M., Plettinger, H. A., Zachariasen, W. H. (1963) The crystal structure of potassium tetraborate tetrahydrate. Acta Crystallographica, 16 (10) 975-980 doi:10.1107/s0365110x63002619DOI: 10.1107/s0365110x63002619
  4. 1970Merlino, Stefano, Sartori, Franco (1970) Santite, a new mineral phase from Larderello, Tuscany. Contributions to Mineralogy and Petrology, 27 (2) 159-165 doi:10.1007/bf00371981DOI: 10.1007/bf00371981
  5. 1971Fleischer, Michael (1971) New Mineral Names. American Mineralogist, 56 (3-4) 631-640
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Santite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/santite-3527},
  note      = {Accessed 2026-05-11}
}