Sideronatrite

Na2Fe3+(SO4)2(OH) · 3H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Snat
Discovered
1878
Also known as
  • Sideronatriet
  • Urusit
  • Urusita
  • +1 more

Where it forms, where it's found

Geological setting

Oxidized zone of iron-rich deposit in very arid region.

Secondary mineral in pyrite deposits in arid environments. Alteration of pyrite by sea spray or saline waters in metallic veins, and coal measures.

Type locality
San Simon Mine
  1. Santa Rosa-Huantajaya mining district (Huantajaya mining district)
  2. Iquique Province
  3. Tarapacá
  4. Chile
75recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789101.5 – 2/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Yellow · yellow-brown · straw-yellow · light orange · pale yellow to nearly colourless in transmitted light.

Semitransparent

Streak
Yellowish white
Tenacity
elastic
Cleavage
Perfect

Perfect on (010) Fair on (100)

Slightly flexible.

Density
2.22 g/cm³

Optical

Optical type
Biaxial (+) · 2V calc = 53 – 63°
Refractive index
1.508 – 1.586
Surface relief
Moderate
Principal indices
nα 1.508 · nβ 1.525 · nγ 1.586
Pleochroism
Weak

X = Nearly colourless, Y = Very pale golden yellow, Z = Pale golden yellow.

Dispersion
Strong, r > v.
Extinction
X = a; Y = b; Z = c.
Michel-Lévy diagramhighlighted lineδ = 0.0780
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]780 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation780 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
#44
Cell parameters
a = 7.265(2) Å · b = 20.522(6) Å · c = 7.120(2) Å
Ratio a:b:c
1 : 2.825 : 0.980
Z
4
Morphology

Lathlike to acicular crystals, elongated [001]; fibrous crusts; crystals are up to 3 cm in size; more commonly earthy, pulverent, nodular, massive; efflorescent crusts.

Type-locality form

Elongated crystals and crystalline masses.

Comment

Data for MDO1 polytype.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1215.999191.988
52.60%
16SSulfurSulfur232.06064.120
17.57%
26FeIronIron155.84555.845
15.30%
11NaSodiumSodium222.99045.980
12.60%
1HHydrogenHydrogen71.0087.056
1.93%
Total364.989100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Sideronatriet
  • Urusit
  • Urusita
  • Urusite

In other languages

German
Sideronatrit
Italian
Sideronatrite

Classification

Strunz
10th ed.

7.DF.20

  • 7SulfatesClass
  • 7.DSulfates (selenates, etc.) with additional anions, with H2ODivision
  • 7.DFWith large and medium-sized cationsGroup
  • 7.DF.20SideronatriteSpecies
Dana
8th ed.

31.08.03.01

  • 31Hydrated Sulfates Containing Hydroxyl or HalogenClass
  • 31.08(AB)3(XO4)2Zq·xH2OType
  • 31.08.03— unnamed intermediate level —Group
  • 31.08.03.01SideronatriteSpecies
CIM

25.11.2

  • 25SulphatesClass
  • 25.11Sulphates of Fe and other metalsGroup
  • 25.11.2SideronatriteSpecies

Group, growth & confusion

Often grow together
2 minerals

Literature, links & citation

Citations
  1. 1878Raimondi, Antonio (1878) Minerales del Perú - ó catálogo razonado de una coleccion que representa los principales tipos minerales de la republica con muestras de huano y restos de aves que lo han producido. J. Enrique, Lima.
  2. 1880Frenzel (1880) Mineralogische und petrographische Mitteilungen, Vienna: 2: 133 (as Urusite).
  3. 1890Frenzel (1890) Mineralogische und petrographische Mitteilungen, Vienna: 11: 214.
  4. 1890Genth, F.A., Penfield, S.L. (1890) Contributions to Mineralogy No 49. American Journal of Science: 40: 199-207 (201-202).
  5. 1906Scharizer (1906) Zeitschrift für Kristallographie, Mineralogie und Petrographie, Leipzig: 41: 215.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Sideronatrite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/sideronatrite-3650},
  note      = {Accessed 2026-05-11}
}