Stercorite

(NH4)Na(PO3OH) · 4H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Stc
Discovered
1850
Also known as
  • Estercorrita
  • Microcosmic Salt
  • Native Salt of Phosphorus
  • +2 more

Where it forms, where it's found

Geological setting

Guano deposit.

Type locality
Ichaboe Island
  1. ǃNamiǂNûs Constituency
  2. ǁKaras Region
  3. Namibia

-26.2895°, 14.9368°

6recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Colourless (artificial material) · white · pale yellow · brownish · colourless in transmitted light.
Streak
White
Cleavage
None Observed
Density
1.574 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 35° · 2V calc = 38°
Refractive index
1.439 – 1.469
Surface relief
Low
Principal indices
nα 1.439 · nβ 1.442 · nγ 1.469
Dispersion
dispersion not observed
Extinction
Z ≃ ⊥ {001}; OAP ≃ ⊥ {010}.
Michel-Lévy diagramhighlighted lineδ = 0.0300
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]300 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation300 nm
Order1st order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
#2
Cell parameters
a = 10.636(2) Å · b = 6.9187(14) Å · c = 6.4359(13) Å
Cell angles
α = 90.46(3) ° · β = 97.87(3) ° · γ = 7109.20(3) °
Ratio a:b:c
1 : 0.650 : 0.605
Z
2
Morphology

Crystals short prismatic (artificial); Pseudo-monoclinic. Crystalline masses and nodules (natural).

Twinning

Repeated twinning of triclinic individuals on (010) simulates monoclinic symmetry. Reentrant angles are usually lacking.

Type-locality form

Transparent crystals.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen815.999127.992
61.22%
15PPhosphorusPhosphorus130.97430.974
14.81%
11NaSodiumSodium122.99022.990
11.00%
7NNitrogenNitrogen114.00714.007
6.70%
1HHydrogenHydrogen131.00813.104
6.27%
Total209.067100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Estercorrita
  • Microcosmic Salt
  • Native Salt of Phosphorus
  • Phosphorsalz
  • Stercoriet

In other languages

French
stercorite
German
Stercorit
Spanish
stercorite
Italian
stercorite
Arabic
ستيركورايت · ستيركوريت

Classification

Strunz
10th ed.

8.CJ.05

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.CPhosphates without additional anions, with H2ODivision
  • 8.CJWith only large cationsGroup
  • 8.CJ.05StercoriteSpecies
Dana
8th ed.

39.03.01.01

  • 39Hydrated Acid Phosphates, Arsenates and VanadatesClass
  • 39.03MiscellaneousType
  • 39.03.01— unnamed intermediate level —Group
  • 39.03.01.01StercoriteSpecies
CIM

19.1.6

  • 19PhosphatesClass
  • 19.1Phosphates of the alkali metalsGroup
  • 19.1.6StercoriteSpecies

Group, growth & confusion

Often grow together
1 mineral

Literature, links & citation

Citations
  1. 1850Herapath, T.J. (1850) On some newly discovered substances from the African guano deposits. Quarterly Journal of the Chemical Society: 2: 70-74.
  2. 1914Schaschek (1914) Mineralogische und petrographische Mitteilungen, Vienna: 32: 402.
  3. 1951Palache, Charles; Berman, Harry; Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. John Wiley and Sons.
  4. 1974Ferraris, G., Franchini-Angela, M. (1974) New data on stercorite (NaNH4HPO4.4H2O) and on its isostructural arsenate. Rendiconti Società Italiana Mineralogia Petrologia: 30: 101-109.
  5. 1974Ferraris, G., Franchini-Angela, M. (1974) Hydrogen bonding in the crystalline state. Crystal structure and twinning of NaNH4HPO4·4H2O (stercorite) Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, 30 (2) 504-510 doi:10.1107/s0567740874003062DOI: 10.1107/s0567740874003062
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Stercorite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/stercorite-3765},
  note      = {Accessed 2026-05-11}
}