Tangdanite

Ca2Cu9(AsO4)4(SO4)0.5(OH)9 · 9H2O
IMA status
  • Approved
IMA symbol
Tdn
IMA approved
2012
Also known as
  • Clinotyrolite
  • Fuxiaotuite
  • IMA2011-096
  • +1 more

Where it forms, where it's found

Geological setting

supergene, within oxidized zone (a gossan) of an As-bearing Cu sulfide deposit

Type locality
Tangdan Mine
  1. Dalaobao
  2. Sahai Village
  3. Tangdan Town
  4. Dongchuan District
  5. Kunming
  6. Yunnan
  7. China

26.1801°, 103.0600°

22recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789102 – 2.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
emerald green
Streak
light green
Tenacity
sectile
Cleavage
Perfect

(100)

Fracture
None observed
Density
3.22 g/cm³

Optical

UV response
not observed

Crystallography

Crystal system
Monoclinic
Space group
C2/c
Cell parameters
a = 54.490(9) Å · b = 5.5685(9) Å · c = 10.4690(17) Å
Cell angles
β = 96.294(3) °
Ratio a:b:c
1 : 0.102 : 0.192
Unit cell volume
3157.9 ų
Z
4
Parting
not observed
Type-locality form

flaky crystals, up to 3 mm, flattened || (100) and elongated along [001], in radiating or foliated aggregates

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen3615.999575.964
36.66%
29CuCopperCopper963.546571.914
36.41%
33AsArsenicArsenic474.922299.688
19.08%
20CaCalciumCalcium240.07880.156
5.10%
1HHydrogenHydrogen271.00827.216
1.73%
16SSulfurSulfur0.532.06016.030
1.02%
Total1570.968100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Clinotyrolite
  • Fuxiaotuite
  • IMA2011-096
  • Tangdaniet

In other languages

German
Fuxiaotuit · IMA 2011-096 · Klinotirolit · Tangdanit
Italian
tangdanite

Classification

Strunz
10th ed.

8.DM.10

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DMWith large and medium-sized cations, (OH, etc.):RO4 > 2:1Group
  • 8.DM.10TangdaniteSpecies

Group, growth & confusion

Commonly confused with
2 minerals

Literature, links & citation

Citations
  1. 2006Krivovichev, S. V., Chernyshov, D. Yu., Dobelin, N., Armbruster, Th., Kahlenberg, V., Kaindl, R., Ferraris, G., Tessadri, R., Kaltenhauser, G. (2006) Crystal chemistry and polytypism of tyrolite. American Mineralogist, 91 (8) 1378-1384 doi:10.2138/am.2006.2040 DOI: 10.2138/am.2006.2040
  2. 2012Williams, P. A., Hatert, F., Pasero, M., Mills, S. J. (2012) New minerals and nomenclature modifications approved in 2012. CNMNC Newsletter No 13. Mineralogical Magazine, 76 (3) 807-817 doi:10.1180/minmag.2012.076.3.26 DOI: 10.1180/minmag.2012.076.3.26
  3. 2012Frost, Ray L., Xi, Yunfei, Couperthwaite, Sara J. (2012) Vibrational spectroscopic study of multianion mineral clinotyrolite Ca2Cu9[(As,S)O4]4(OH)10·10(H2O) Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 95. 258-262 doi:10.1016/j.saa.2012.04.007DOI: 10.1016/j.saa.2012.04.007
  4. 2014Williams, P. A., Hatert, F., Pasero, M., Mills, S. J. (2014) New minerals and nomenclature modifications approved in 2014, CNMNC Newsletter No 19. Mineralogical Magazine, 78 (1) 165-170 doi:10.1180/minmag.2014.078.1.12DOI: 10.1180/minmag.2014.078.1.12
  5. 2014Zhesheng, Ma, Guowu, Li, Chukanov, N. V., Poirier, G., Nicheng, Shi (2014) Tangdanite, a new mineral species from the Yunnan Province, China and the discreditation of ‘clinotyrolite’. Mineralogical Magazine, 78 (3) 559-569 doi:10.1180/minmag.2014.078.3.06DOI: 10.1180/minmag.2014.078.3.06
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Tangdanite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/tangdanite-42724},
  note      = {Accessed 2026-05-11}
}