Tyrolite

Ca2Cu9(AsO4)4(CO3)(OH)8 · 11H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Tyl
Discovered
1845
Also known as
  • Afrocalcocita
  • Aphrochalcit
  • Aphrochalcite
  • +12 more

Where it forms, where it's found

Type locality
Falkenstein
  1. Falkenstein mining district
  2. Schwaz District
  3. Tyrol
  4. Austria

47.3485°, 11.7432°

249recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789101.5 – 2/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Turquoise-blue · blue-green · light bluish green in transmitted light.
Streak
Paler than unpowdered colour.
Tenacity
sectile
Cleavage
Distinct/Good

In [001], well-defined.

Density
3 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 33 – 39° · 2V calc = 38°
Refractive index
1.694 – 1.73
Surface relief
High
Principal indices
nα 1.694 · nβ 1.726 · nγ 1.73
Pleochroism
Weak

X = b = Pale grass-green Y = c = Pale yellowish green Z = a = Pale grass-green

Dispersion
relatively strong
Michel-Lévy diagramhighlighted lineδ = 0.0360
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]360 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation360 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Cell parameters
a = 27.562(3) Å · b = 5.5682(7) Å · c = 10.4662(15) Å
Cell angles
β = 98.074(11) °
Ratio a:b:c
1 : 0.202 : 0.380
Unit cell volume
1590.3 ų
Morphology

Crystals tiny pseudo-hexagonal twinned aggregates flattened on (010) and bounded laterally by (100). Radiated groups, columnar; dendritic forms; commonly as fan-shaped and closely foliated aggregates; crusts and reniform masses with a radiated foliaceous structure and a drusy surface; divergent fibrous.

Twinning

On (101), repeated, yielding pseudo-hexagonal aggregates.

Comment

Space group P2/c (1M-polytype); cell parameters of 2M-polytype (C2/c) are: a = 54.520(6), b = 5.5638(6), c = 10.4647(10) Å, beta = 96.432(9)°, V = 3154.4(6) Å3.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen3815.999607.962
37.95%
29CuCopperCopper963.546571.914
35.70%
33AsArsenicArsenic474.922299.688
18.71%
20CaCalciumCalcium240.07880.156
5.00%
1HHydrogenHydrogen301.00830.240
1.89%
6CCarbonCarbon112.01112.011
0.75%
Total1601.971100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • S
  • O

Synonyms

  • Afrocalcocita
  • Aphrochalcit
  • Aphrochalcite
  • Copper froth
  • Kupaphrit
  • Kupaphrita
  • Kupaphrite
  • Kupferschaum
  • Leirochroit
  • Leirochroita
  • Leirochroite
  • Trichalcit
  • Trichalcita
  • Trichalcite
  • Tyrolita

In other languages

French
Tyrolite
German
Kupferschaum · Tirolit
Spanish
Tirolita
Italian
tirolite

Classification

Strunz
10th ed.

8.DM.10

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DMWith large and medium-sized cations, (OH, etc.):RO4 > 2:1Group
  • 8.DM.10TyroliteSpecies
Dana
8th ed.

42.04.03.01

  • 42Hydrated Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 42.04(AB)5(XO4)2Zq·xH2OType
  • 42.04.03— unnamed intermediate level —Group
  • 42.04.03.01TyroliteSpecies
CIM

22.4.5

  • 22Phosphates, Arsenates or Vanadates with other AnionsClass
  • 22.4Phosphates, arsenates or vanadates with carbonateGroup
  • 22.4.5TyroliteSpecies

Group, growth & confusion

Commonly confused with
2 minerals

Literature, links & citation

Citations
  1. Werner (as Kupferschaum).
  2. 1816Hoffmann, C.A.S. (1816) Handbuch der Mineralogie volume 3A and 3B: 3: 180 (as Kupferschaum).
  3. 1817Hoffmann, C.A.S. (1817) Handbuch der Mineralogie volume 4A: 19, 50 (as Kupferschaum).
  4. 1832Shepard C.U. (1832) Treatise on Mineralogy. First edition: vol. 1, New Haven: 1: 294 (as Kupaphrite).
  5. 1845Haidinger, Wilhelm (1845) Handbuch der bestimmenden Mineralogie, enthaltend die Terminologie, Systematik, Nomenklatur und Charakteristik der Naturgeschichte des Mineralreiches (1st ed.) Braumüller & Seidel, Vienna.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Tyrolite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/tyrolite-4070},
  note      = {Accessed 2026-05-11}
}