Tokkoite

K2Ca4Si7O18(OH)F
IMA status
  • Approved
IMA symbol
Tok
Discovered
1985
IMA approved
1985
Also known as
  • IMA1985-009
  • Tokkoiet

Where it forms, where it's found

Geological setting

Alkaline massif. Occurs in zones a few centimeters thick or in streaky, elongated, nearly monomineralic segregations.

Type locality
Magistral'nyi area
  1. Sirenevyi Kamen' Deposit
  2. Murunskii Massif
  3. Chara and Tokko Rivers Confluence
  4. Aldan Shield
  5. Russia
1recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104 – 5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Light brown · light yellow · colorless
Streak
White
Cleavage
Perfect

Perfect on (010) and good on (110)

Fracture
Splintery
Density
2.76 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 38°
Refractive index
1.57 – 1.577
Surface relief
Moderate
Principal indices
nα 1.57 · nγ 1.577
Dispersion
r > v
Michel-Lévy diagramhighlighted lineδ = 0.0070
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]70 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation70 nm
Order1st order
XPL colour

Crystallography

Crystal system
Triclinic
Cell parameters
a = 10.43 Å · b = 12.51 Å · c = 7.11 Å
Cell angles
α = 89.92 ° · β = 99.75 ° · γ = 92.89 °
Ratio a:b:c
1 : 1.199 : 0.682
Type-locality form

Radiating or columnar aggregates.

Comment

mean parameters concerning the structure refinement (Lacalamita et al., 2016): a~10.423, b~12.477, c~7.112, α~89.92, β~99.68, γ~92.97, V~910.5

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1915.999303.981
40.05%
14SiSiliconSilicon728.085196.595
25.90%
20CaCalciumCalcium440.078160.312
21.12%
19KPotassiumPotassium239.09878.196
10.30%
9FFluorineFluorine118.99818.998
2.50%
1HHydrogenHydrogen11.0081.008
0.13%
Total759.090100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Ti
  • Fe
  • Mn
  • Mg
  • Na
  • H2O

Synonyms

  • IMA1985-009
  • Tokkoiet

In other languages

German
IMA 1985-009 · Tokkoit
Italian
Tokkoite

Classification

Strunz
10th ed.

9.DG.75

  • 9SilicatesClass
  • 9.DInosilicatesDivision
  • 9.DGInosilicates with 3-periodic single and multiple chainsGroup
  • 9.DG.75TokkoiteSpecies
Dana
8th ed.

67.02.01.02

  • 67Inosilicates Unbranched Chains with W > 2Class
  • 67.02Unbranched Chains with W>2 with W=5Type
  • 67.02.01Tinaksite groupGroup
  • 67.02.01.02TokkoiteSpecies
CIM

14.6.5

  • 14Silicates not Containing AluminumClass
  • 14.6Silicates of Ca with alkali or Mg or bothGroup
  • 14.6.5TokkoiteSpecies

Group, growth & confusion

Commonly confused with
2 minerals

Literature, links & citation

Citations
  1. 1986Lazebnik, K.A., Nikishova, L.V., Lazebnik, Yu.D. (1986) Tokkoite - A new mineral of charoitites. Mineralogicheskii Zhurnal, Kiev: 8(3): 85-89. (in Russian)
  2. 1986Lazebnik, K.A., Nikishova, L.V., Lazebnik, Yu.D. (1986) Tokkoite - A new mineral of charoitites. Mineralogicheskii Zhurnal, Kiev: 8(3): 85-89.
  3. 1988Hawthorne, Frank C., Burke, Ernst A. J., Ercit, T. Scott, Grew, Edward S., Grice, Joel D., Jambor, John L., Puziewicz, Jacek, Roberts, Andrew C., Vanko, David A. (1988) New Mineral Names. American Mineralogist, 73 (1-2) 189-199
  4. 1989Rozhdestvenskaya, I. V.; Nikishova, L. V.; Lazebnik, Yu. D.; Lazebnik, K. A. (1989) The crystal structure of tokkoite and its relation to the structure of tinaksite. Zeitschrift für Kristallographie, 189 (3-4). 195-204 doi:10.1524/zkri.1989.189.3-4.195 DOI: 10.1524/zkri.1989.189.3-4.195
  5. 1990Jambor, John L.; Puziewicz, Jacek (1990) New Mineral Names. American Mineralogist, 75 (9-10). 1209-1216
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Tokkoite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/tokkoite-3989},
  note      = {Accessed 2026-05-11}
}