Ulexite

NaCaB5O6(OH)6 · 5H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Ulx
Discovered
1850
Also known as
  • Boronatro-calcite
  • Boronatrocalcit
  • Boronatrocalcita
  • +25 more

Where it forms, where it's found

Geological setting

Playas in a desert region.

Arid regions. In salt playas and desiccated saline lakes.

Type locality
Iquique Province
  1. Tarapacá
  2. Chile
127recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Silky · Vitreous
Transparency
Transparent
Colour
Colourless · white · grey with included clays.
Tenacity
brittle
Cleavage
Perfect

Perfect on (010); on (110) good; on (110) poor.

Fracture uneven across fibers.

Fracture
Irregular/Uneven
Density
1.955 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 73 – 78° · 2V calc = 68°
Refractive index
1.491 – 1.52
Surface relief
Moderate
Principal indices
nα 1.491 – 1.496 · nβ 1.504 – 1.506 · nγ 1.519 – 1.52
Dispersion
none
Extinction
X (11.5°,81°); Y (100°,21.5°); Z (107°,70°) [with c (0°,0°) and b* (0°,90°) using (φ,ρ)].
UV response
Yellow, greenish yellow, cream, white.
Michel-Lévy diagramhighlighted lineδ = 0.0260
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]260 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation260 nm
Order1st order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
#2
Cell parameters
a = 8.816(3) Å · b = 12.87 Å · c = 6.678(1) Å
Cell angles
α = 90.25 ° · β = 109.12 ° · γ = 105.1 °
Ratio a:b:c
1 : 1.460 : 0.757
Z
2
Morphology

Small nodular, rounded, or lens-like masses; loose at times (termed "cotton balls"), comprised of acicular crystals. Fibers may be radially arranged or randomly oriented towards the centers of the masses and arranged in parallel position at the periphery. Botryoidal crusts or randomly oriented fibers. Compact veins with a parallel fibrous structure. Distinct crystals rare, greatly elongated [001] (Palache et al (1951) Dana's System of Min.: 345).

Twinning

Polysynthetic, common in massive aggregates and crushed fragments. Several twin laws apply: 1. Polysynthetic on (010) and (100); 2. (340) or (230) less certain, and others of a more complex nature. The twinning distinguishes ulexite from probertite.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1715.999271.983
67.12%
5BBoronBoron510.81054.050
13.34%
20CaCalciumCalcium140.07840.078
9.89%
11NaSodiumSodium122.99022.990
5.67%
1HHydrogenHydrogen161.00816.128
3.98%
Total405.229100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Boronatro-calcite
  • Boronatrocalcit
  • Boronatrocalcita
  • boronitrocalcite
  • Cotton-ball Borax
  • Fernsehstein
  • Franklandit
  • Franklandita
  • Franklandite
  • Hayesine (of Forbes)
  • Hayesit
  • Hayesita
  • Hayesite
  • Natroborocalcit
  • Natroborocalcita
  • Natroborocalcite
  • Natronborocalcite
  • Natronkalk-borat
  • Raphit
  • Raphita
  • Raphite
  • Stiberit
  • Stiberita
  • Stiberite
  • Television Stone
  • Tinkalzit
  • Tiza
  • TV stone

In other languages

French
Uléxite
German
Fernsehstein · Televisionsstein · TV-Stein · Ulexit
Spanish
ulexita
Italian
Ulexite
Portuguese
ulexita · Ulexite
Japanese
ウレキサイト · ウレックス石 · テレビ石 · 曹灰硼石
Chinese
冰硼钠石 · 硼钠解石 · 鈉硼解石 · 钠硼解石
Simplified Chinese
冰硼钠石
Traditional Chinese
冰硼鈉石
Russian
боронатрокальцит · телевизионный камень · улексит
Arabic
أوليكسيت

Classification

Strunz
10th ed.

6.EA.25

  • 6BoratesClass
  • 6.EPentaboratesDivision
  • 6.EANeso-pentaboratesGroup
  • 6.EA.25UlexiteSpecies
Dana
8th ed.

26.05.11.01

  • 26Hydrated Borates Containing Hydroxyl or HalogenClass
  • 26.05PentaboratesType
  • 26.05.11— unnamed intermediate level —Group
  • 26.05.11.01UlexiteSpecies
CIM

9.3.21

  • 9BoratesClass
  • 9.3Borates of Ca and SrGroup
  • 9.3.21UlexiteSpecies

Group, growth & confusion

Often grow together
2 minerals

Literature, links & citation

Citations
  1. Currier, Rock (n.d.) Best of.. Ulexite. https://www.mindat.org/a/best_ulexite
  2. 1844Hayes, A.A. (1844) Borate of Lime. Borocalcius obliquus. American Journal of Science: 46: 377-377. (as Hydrous borate of lime).
  3. 1844Hayes, A.A. (1844) Hydrous borate of lime. American Journal of Science: 47: 215-215.
  4. 1847Hausmann, J.F.L. (1847) Handbuch der Mineralogie 3 volumes, Göttingen. Second edition, vol. 2, in two parts: 1429 (as Hydroborocalcite)
  5. 1849Ulex, G.L. (1849) Ueber eine natürliche borsaure Verbindung. Annalen der Chemie und Pharmacie: 70(1): 49-52. (as Boronatro-calcite)
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Ulexite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/ulexite-4085},
  note      = {Accessed 2026-05-11}
}