Uzonite

As4S5
IMA status
  • Approved
IMA symbol
Uzn
Discovered
1984
IMA approved
1984
Also known as
  • IMA1984-027
  • Usonite
  • Uzoniet

Where it forms, where it's found

Geological setting

Caldera. Realgar-enriched sand-gravel and gravel-pebble tuff sediments at 10-30 cm depth.

Type locality
Uzon Caldera
  1. Kronotsky Reserve
  2. Yelizovsky District
  3. Kamchatka Krai
  4. Russia

54.5000°, 159.9700°

3recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789101.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Pearly
Transparency
Transparent
Colour
Yellow
Streak
Yellow
Cleavage
Distinct/Good

(001)

Density
3.37 g/cm³

Optical

Optical type
Biaxial (+)
Refractive index
2.38 – 2.68
Surface relief
Very high
Principal indices
nα 2.38 · nγ 2.68
Dispersion
relatively strong
Optical colour
Grayish white
Internal reflections
Bright yellow
Tropism
Anisotropic
Reflectance R%
(18.8,20.1) 400, (18.8,20.0) 425, (18.7,19.9) 450, (18.3,19.7) 475, (18.1,19.2) 500, (19.0,19.8) 525, (19.4,20.0) 550, (19.4,19.9) 575, (19.3,19.7) 600, (19.2,19.4) 625, (19.1,19.3) 650, (19.0,19.2) 675, (18.8,19.0) 700
Reflected-light panel
18.9 %anisotropic · dual curve
Specimen sRGB 163, 112, 59
White reference100 % reflector under same lamp
R₁ R₂
Mode
Reflected colour
Grayish white
Internal reflections
Bright yellow

Crystallography

Crystal system
Monoclinic
Space group
P21/m
Cell parameters
a = 7.973 Å · b = 8.096(2) Å · c = 7.148(2) Å
Cell angles
β = 101.01(2) °
Ratio a:b:c
1 : 1.015 : 0.897
Unit cell volume
452.9 ų
Z
2
Morphology

Elongated along [001], with (110), (001), (101). (110) exhibits fine striations parallel to [111].

Twinning

Cruciform twins with twin plane (011) and axis [100].

Type-locality form

Yellow crystals up to 0.5 mm long.

Comment

Cell parameters from Bindi et al. (2003).

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
33AsArsenicArsenic474.922299.688
65.15%
16SSulfurSulfur532.060160.300
34.85%
Total459.988100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1984-027
  • Usonite
  • Uzoniet

In other languages

German
IMA 1984-027 · Tetraarsenpentasulfid · Uzonit
Italian
Uzonite

Classification

Strunz
10th ed.

2.FA.25

  • 2Sulfides and SulfosaltsClass
  • 2.FSulfides of arsenic, alkalies; sulfides with halide, oxide, hydroxide, H2ODivision
  • 2.FAWith As, (Sb), SGroup
  • 2.FA.25UzoniteSpecies
Dana
8th ed.

02.08.23

  • 02SulfidesClass
  • 02.08AmXp, with m:p = 1:1Type
  • 02.08.23— unnamed intermediate level —Group
  • 02.08.23UzoniteSpecies
CIM

3.7.7

  • 3Sulphides, Selenides, Tellurides, Arsenides and Bismuthides (except the arsenides, antimonides and bismuthides of Cu, Ag and Au, which are included in Section 1)Class
  • 3.7Sulphides etc. of V, As, Sb and BiGroup
  • 3.7.7UzoniteSpecies

Group, growth & confusion

Often grow together
1 mineral

Literature, links & citation

Citations
  1. 1973Whitfield, H.J. (1973) Crystal and molecular structure of tetra-arsenic pentasulphide. Journal of the Chemical Society, Dalton Transactions, Inorganic Chemistry: 1740-1742.
  2. 1985Popova, V.I., Pol'akov, V.O. (1985) Uzonite As4S5 — a new arsenic sulfide from Kamchatka. Zapiski Vserossiyskogo Mineralogicheskogo Obshchestva: 114: 369-373.
  3. 1986Hawthorne, Frank C., Fleischer, Michael, Grew, Edward S., Grice, Joel D., Jambor, John L., Puziewicz, J., Roberts, Andrew C., Vanko, D. A., Zilczer, J. A. (1986) New mineral names. American Mineralogist, 71. 1277-1282
  4. 2003Bindi, L., Popova, V., Bonazzi, P. (2003) Uzonite, As4S5, from the type locality: single-crystal X-ray study and effects of exposure to light. The Canadian Mineralogist, 41 (6) 1463-1468 doi:10.2113/gscanmin.41.6.1463 DOI: 10.2113/gscanmin.41.6.1463
  5. 2005(2005) Uzonite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Uzonite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/uzonite-4128},
  note      = {Accessed 2026-05-11}
}