Where it forms, where it's found
- Geological setting
Caldera. Realgar-enriched sand-gravel and gravel-pebble tuff sediments at 10-30 cm depth.
- Type locality
- Uzon Caldera
- Kronotsky Reserve
- Yelizovsky District
- Kamchatka Krai
- Russia
54.5000°, 159.9700°
Safety & handling
Physical
Optical
- Optical type
- Biaxial (+)
- Refractive index
- 2.38 – 2.68
- Surface relief
- Very high
- Principal indices
- nα 2.38 · nγ 2.68
- Dispersion
- relatively strong
- Optical colour
- Grayish white
- Internal reflections
- Bright yellow
- Tropism
- Anisotropic
- Reflectance R%
- (18.8,20.1) 400, (18.8,20.0) 425, (18.7,19.9) 450, (18.3,19.7) 475, (18.1,19.2) 500, (19.0,19.8) 525, (19.4,20.0) 550, (19.4,19.9) 575, (19.3,19.7) 600, (19.2,19.4) 625, (19.1,19.3) 650, (19.0,19.2) 675, (18.8,19.0) 700
Crystallography
- Space group
- P21/m
- Cell parameters
- a = 7.973 Å · b = 8.096(2) Å · c = 7.148(2) Å
- Cell angles
- β = 101.01(2) °
- Ratio a:b:c
- 1 : 1.015 : 0.897
- Unit cell volume
- 452.9 ų
- Z
- 2
- Morphology
Elongated along [001], with (110), (001), (101). (110) exhibits fine striations parallel to [111].
- Twinning
Cruciform twins with twin plane (011) and axis [100].
- Type-locality form
Yellow crystals up to 0.5 mm long.
- Comment
Cell parameters from Bindi et al. (2003).
Chemical composition
Synonyms
- IMA1984-027
- Usonite
- Uzoniet
In other languages
- German
- IMA 1984-027 · Tetraarsenpentasulfid · Uzonit
- Italian
- Uzonite
Classification
2.FA.25
- 2Sulfides and SulfosaltsClass
- 2.FSulfides of arsenic, alkalies; sulfides with halide, oxide, hydroxide, H2ODivision
- 2.FAWith As, (Sb), SGroup
- 2.FA.25UzoniteSpecies
02.08.23
- 02SulfidesClass
- 02.08AmXp, with m:p = 1:1Type
- 02.08.23— unnamed intermediate level —Group
- 02.08.23UzoniteSpecies
3.7.7
- 3Sulphides, Selenides, Tellurides, Arsenides and Bismuthides (except the arsenides, antimonides and bismuthides of Cu, Ag and Au, which are included in Section 1)Class
- 3.7Sulphides etc. of V, As, Sb and BiGroup
- 3.7.7UzoniteSpecies
Group, growth & confusion
Literature, links & citation
- 1973Whitfield, H.J. (1973) Crystal and molecular structure of tetra-arsenic pentasulphide. Journal of the Chemical Society, Dalton Transactions, Inorganic Chemistry: 1740-1742.
- 1985Popova, V.I., Pol'akov, V.O. (1985) Uzonite As4S5 — a new arsenic sulfide from Kamchatka. Zapiski Vserossiyskogo Mineralogicheskogo Obshchestva: 114: 369-373.
- 1986Hawthorne, Frank C., Fleischer, Michael, Grew, Edward S., Grice, Joel D., Jambor, John L., Puziewicz, J., Roberts, Andrew C., Vanko, D. A., Zilczer, J. A. (1986) New mineral names. American Mineralogist, 71. 1277-1282
- 2003Bindi, L., Popova, V., Bonazzi, P. (2003) Uzonite, As4S5, from the type locality: single-crystal X-ray study and effects of exposure to light. The Canadian Mineralogist, 41 (6) 1463-1468 doi:10.2113/gscanmin.41.6.1463 DOI: 10.2113/gscanmin.41.6.1463
- 2005(2005) Uzonite. Handbook of Mineralogy. Mineralogical Society of America
@misc{mineral2026,
author = {Mineral Index editorial board},
title = {Uzonite — Mineral Index},
year = {2026},
url = {https://mineralindex.org/minerals/uzonite-4128},
note = {Accessed 2026-05-11}
}