Alacránite

As8S9
IMA status
  • Approved
IMA symbol
Acr
Discovered
1985
IMA approved
1985
Also known as
  • Alacrániet
  • Alacránitt
  • IMA1985-033

Where it forms, where it's found

Geological setting

In hydrothermal As–S veins

in the condensation zone of a hydrothermal Hg–Sb–As system as cement in a sandy gravel (Uzon caldera, Russia); formed at low temperatures in a polymetallic hydrothermal deposit on a submarine seamount (Conical Seamount, Papua New Guinea).

Type locality
Alacrán Mine
  1. Alacrán
  2. Pampa Larga mining district
  3. Tierra Amarilla
  4. Copiapó Province
  5. Atacama
  6. Chile

-27.5969°, -70.1756°

24recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789101.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Adamantine
Transparency
Translucent
Colour
Orange to pale gray with rose-yellow internal reflections

yellow-orange in transmitted light

Streak
Yellow-orange
Tenacity
very brittle
Cleavage
Imperfect/Fair

imperfect on (100)

Fracture
Conchoidal
Density
3.43 g/cm³

Optical

Optical type
Biaxial (+)
Refractive index
2.39 – 2.52
Surface relief
Very high
Principal indices
nα 2.39 · nγ 2.52
Dispersion
r < v
Optical colour
Light gray
Internal reflections
Rose-yellow
Reflectance R%
(13.0, 14.0) 400, (13.2, 14.6) 425, (13.3, 14.8) 450, (13.4, 14.8) 475, (13.3, 14.5) 500, (13.1, 14.3) 525, (13.2, 14.5) 550, (13.4, 14.7) 575, (13.5, 14.8) 600, (13.6, 14.9) 625, (13.7, 15.0) 650, (13.8, 15.0) 675, (13.9, 15.1) 700
Reflected-light panel
13.4 %anisotropic · dual curve
Specimen sRGB 139, 94, 50
White reference100 % reflector under same lamp
R₁ R₂
Mode
Reflected colour
Light gray
Internal reflections
Rose-yellow

Crystallography

Crystal system
Monoclinic
Space group
P2/c
Cell parameters
a = 9.942 Å · b = 9.601 Å · c = 9.178 Å
Cell angles
β = 101.94 °
Ratio a:b:c
1 : 0.966 : 0.923
Unit cell volume
857.1 ų
Z
2
Morphology

Crystals are pinacoidal, prismatic, and flattened on [100] , striated parallel [001] on (100) , other faces dull or tarnished, to 1 mm; as subhedral flattened and prismatic grains.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
33AsArsenicArsenic874.922599.376
67.50%
16SSulfurSulfur932.060288.540
32.50%
Total887.916100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Alacrániet
  • Alacránitt
  • IMA1985-033

In other languages

French
alacránite
German
Alacránit
Spanish
Alacranita
Italian
alacránite
Russian
Алакранит

Classification

Strunz
10th ed.

2.FA.20

  • 2Sulfides and SulfosaltsClass
  • 2.FSulfides of arsenic, alkalies; sulfides with halide, oxide, hydroxide, H2ODivision
  • 2.FAWith As, (Sb), SGroup
  • 2.FA.20AlacrániteSpecies
Dana
8th ed.

02.08.22

  • 02SulfidesClass
  • 02.08AmXp, with m:p = 1:1Type
  • 02.08.22Realgar SeriesGroup
  • 02.08.22AlacrániteSpecies
CIM

3.7.6

  • 3Sulphides, Selenides, Tellurides, Arsenides and Bismuthides (except the arsenides, antimonides and bismuthides of Cu, Ag and Au, which are included in Section 1)Class
  • 3.7Sulphides etc. of V, As, Sb and BiGroup
  • 3.7.6AlacrániteSpecies

Group, growth & confusion

Often grow together
10 minerals

Literature, links & citation

Citations
  1. 1970Clark, Alan H. (1970) Alpha-arsenic sulfide, from Mina Alacrán, Pampa Larga, Chile. American Mineralogist, 55 (7-8) 1338-1344
  2. 1986Popova, V.I., Popov, V.A., Clark, A., Polyakov, V.O., Borisovskii, S.E. (1986) Alacránite, As8S9–a new mineral. Zapiski Vsesoyuznogo Mineralogicheskogo Obshchestva: 115(3): 360-368.
  3. 1988Hawthorne, Frank C., Burke, Ernst A. J., Ercit, T. Scott, Grew, Edward S., Grice, Joel D., Jambor, John L., Puziewicz, Jacek, Roberts, Andrew C., Vanko, David A. (1988) New Mineral Names. American Mineralogist, 73 (1-2) 189-199
  4. 2001Burns, P. C., Percival, J. B. (2001) Alacranite, As4S4: a new occurrence, new formula, and determination of the crystal structure. The Canadian Mineralogist, 39 (3) 809-818 doi:10.2113/gscanmin.39.3.809 DOI: 10.2113/gscanmin.39.3.809
  5. 2003Bonazzi, Paola, Bindi, Luca, Popova, Valentina, Pratesi, Giovanni, Menchetti, Silvio (2003) Alacranite, As8S9: structural study of the holotype and re-assignment of the original chemical formula. American Mineralogist, 88 (11) 1796-1800 doi:10.2138/am-2003-11-1220 DOI: 10.2138/am-2003-11-1220
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Alacránite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/alacranite-91},
  note      = {Accessed 2026-05-11}
}