Vauxite

Fe2+Al2(PO4)2(OH)2 · 6H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Vx
Discovered
1922
Also known as
  • Vauxiet

Where it forms, where it's found

Geological setting

Hydrothermal tin veins.

Alteration of apatite.

Type locality
Siglo Veinte Mine
  1. Llallagua
  2. Rafael Bustillo Province
  3. Potosí
  4. Bolivia

-18.4229°, -66.5925°

10recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Sky-blue · dark blue · pale blue in transmitted light.
Streak
White
Tenacity
brittle
Cleavage
None Observed
Density
2.39 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 32°
Refractive index
1.551 – 1.562
Surface relief
Moderate
Principal indices
nα 1.551 · nβ 1.555 · nγ 1.562
Pleochroism
Strong

X = Z = Colourless Y = Blue

Dispersion
r > v weak
Michel-Lévy diagramhighlighted lineδ = 0.0110
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]110 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation110 nm
Order1st order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
#2
Cell parameters
a = 9.142 Å · b = 11.599 Å · c = 6.158 Å
Cell angles
α = 98.29 ° · β = 91.93 ° · γ = 108.27 °
Ratio a:b:c
1 : 1.269 : 0.674
Z
2
Morphology

Crystals tabular (010), elongated [001] or [101]. May exhibit may forms, including (010), (110), (111), (101), (111), (101), and (140). Forms radial to subparallel aggregates; nodular.

Twinning

on (010), twin and composition plane.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1615.999255.984
57.94%
15PPhosphorusPhosphorus230.97461.948
14.02%
26FeIronIron155.84555.845
12.64%
13AlAluminiumAluminium226.98253.964
12.21%
1HHydrogenHydrogen141.00814.112
3.19%
Total441.853100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Vauxiet

In other languages

French
Vauxite
German
Vauxit
Spanish
Vauxita
Italian
Vauxite
Russian
Воксит
Arabic
فووكسيت

Classification

Strunz
10th ed.

8.DC.35

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DCWith only medium-sized cations, (OH, etc.):RO4 = 1:1 and < 2:1Group
  • 8.DC.35VauxiteSpecies
Dana
8th ed.

42.11.14.01

  • 42Hydrated Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 42.11(AB)3(XO4)2Zq·xH2OType
  • 42.11.14Vauxite GroupGroup
  • 42.11.14.01VauxiteSpecies
CIM

19.14.23

  • 19PhosphatesClass
  • 19.14Phosphates of Fe and other metalsGroup
  • 19.14.23VauxiteSpecies

Group, growth & confusion

Often grow together
1 mineral

Literature, links & citation

Citations
  1. 1922Newhouse, W.H. (1922) Notes and News. American Mineralogist: 7: 108-109.
  2. 1922Gordon, S. G. (1922) Preliminary notes on vauxite and paravauxite. Science, 56 (1437) 50 doi:10.1126/science.56.1437.50DOI: 10.1126/science.56.1437.50
  3. 1923Gordon (1923) Proceedings of the Academy of Sciences, Philadelphia: 75: 261.
  4. 1944Gordon, Samuel G. (1944) The mineralogy of the tin mines of Cerro de Llallagua, Bolivia. Proceedings of the Academy of Natural Sciences of Philadelphia, 96. 279-359
  5. 1945Fleischer, M. (1945) New mineral names. American Mineralogist, 30 (7-8). 548-550
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Vauxite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/vauxite-4164},
  note      = {Accessed 2026-05-11}
}