Wavellite

Al3(PO4)2(OH)3 · 5H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Wav
Discovered
1805
Also known as
  • Alumine phosphatée
  • Bialit
  • Bialita
  • +25 more

History

The name wavellite honours a country physician who noticed what trained chemists had missed. In 1805, the English mineralogist William Babington proposed the name in tribute to Dr. William Wavell (1750–1829), a Devon-based physician, botanist, historian, and naturalist who had brought the mineral to the attention of fellow mineralogists.

Wavell practised medicine in Barnstaple, in north Devon, where he was in partnership with Dr. William Curtis on Gracechurch Street. He had been educated in Edinburgh and corresponded with several naturalists of his generation. The type specimens came from a quarry at High Down, near the village of Filleigh, a few miles inland from his Barnstaple practice.

The discovery had a quietly important chemical edge. The same translucent green crusts had been examined before and grouped under the older name hydrargilite — an aluminium hydroxide. Non-contemporary accounts credit Wavell with detecting phosphate in the material, a constituent earlier analysts had missed. That single observation moved the mineral out of the hydroxide family and into the aluminium phosphates, where it has remained.

Industrial & practical applications

Wavellite has no significant industrial use. It is not mined as an ore, not refined into a commodity, and not produced at any meaningful scale. What demand exists comes almost entirely from mineral collectors and museums.

Collectors prize the mineral for one form in particular: tight green or yellowish-green spheres made of fine crystals radiating from a single point. Specimens of this kind reach the market from a small number of localities, including the Ouachita Mountains around Mount Ida in Arkansas, the original Devon quarry, and historic occurrences in Bolivia and the Czech Republic.

Cut stones appear from time to time. Wavellite is occasionally faceted or polished as a gemstone, but it is too soft to survive daily wear. Cut wavellite is therefore a cabinet curiosity, not a stone for rings or pendants.

Where it forms, where it's found

Geological setting

A secondary mineral of aluminous low-grade metamorphic rocks, in phosphate and limonitic deposits; more rarely as a late-forming hydrothermal vein mineral.

Type locality
High Down Quarry
  1. West Buckland
  2. North Devon
  3. Devon
  4. England
  5. UK

51.0442°, -3.9251°

357recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103.5 – 4/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Green to yellowish-green and yellow · greenish white · yellowish-brown · brown · brownish-black · blue · white and colourless · colourless in transmitted light.

Colouration may be zoned.

Streak
White.
Tenacity
brittle
Cleavage
Perfect

Perfect on (110), good on (101), distinct on (010).

Fracture
Irregular/Uneven · Sub-Conchoidal
Density
2.36 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 60 – 72° · 2V calc = 60 – 70°
Refractive index
1.518 – 1.561
Surface relief
Moderate
Principal indices
nα 1.518 – 1.535 · nβ 1.524 – 1.543 · nγ 1.544 – 1.561
Pleochroism
Weak

X= Greenish Z= Yellowish

Dispersion
r > v weak
Michel-Lévy diagramhighlighted lineδ = 0.0260
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]260 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation260 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Cell parameters
a = 9.621 Å · b = 17.363 Å · c = 6.994 Å
Ratio a:b:c
1 : 1.805 : 0.727
Z
4
Morphology

Crystals rare, stout to long prismatic parallel to [001], with (110) striated parallel to [001]. Found as hemispherical or globular aggregates with an internal radial or stellate structure of fibrous crystals; as crusts and stalactic; more rarely in chalcedony-like opaline masses.

Twinning

None reported

Comment

Space Group: Pcmn (non-standard setting).

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1615.999255.984
62.13%
13AlAluminiumAluminium326.98280.946
19.65%
15PPhosphorusPhosphorus230.97461.948
15.04%
1HHydrogenHydrogen131.00813.104
3.18%
Total411.982100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • F
  • Fe

Synonyms

  • Alumine phosphatée
  • Bialit
  • Bialita
  • Bialite
  • Bialith
  • Brazilianite (of Mawe)
  • Devonit
  • Devonita
  • Devonite (of von Moll)
  • Fischerit
  • Fischerita
  • Fischerite
  • Hydrargillite (of Davy)
  • Kapnicite
  • Kapnikite (of Kenngott)
  • Lasionit
  • Lasionita
  • Lasionite
  • Lazionit
  • Lazionita
  • Lazionite
  • Striegisan
  • Thonerdephosphat
  • Uhligite (of Slavik)
  • Wavellite (of Babington)
  • Zepharovichit
  • Zepharovichita
  • Zepharovichite

In other languages

French
wavellite
German
Fischerit · Lasionit · Wavellit
Spanish
wavelita · wavellita
Italian
Wavellite
Japanese
銀星石
Chinese
磷铝石 · 銀星石
Simplified Chinese
磷铝石
Traditional Chinese
磷鋁石
Russian
вавеллит · фишерит
Arabic
ويفيليت

Classification

Strunz
10th ed.

8.DC.50

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DCWith only medium-sized cations, (OH, etc.):RO4 = 1:1 and < 2:1Group
  • 8.DC.50WavelliteSpecies
Dana
8th ed.

42.10.02.01

  • 42Hydrated Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 42.10A3(XO4)2Zq·xH2OType
  • 42.10.02Wavellite GroupGroup
  • 42.10.02.01WavelliteSpecies
CIM

19.7.8

  • 19PhosphatesClass
  • 19.7Phosphates of Al aloneGroup
  • 19.7.8WavelliteSpecies

Group, growth & confusion

In the same group
2 members

Literature, links & citation

Citations
  1. 1805Davy, Humphrey (1805) VII. An account of some analytical experiments on a mineral production from Devonshire, consisting principally of alumine and water. Philosophical Transactions Of The Royal Society Of London, 95. 155-162 doi:10.1098/rstl.1805.0009DOI: 10.1098/rstl.1805.0009
  2. 1805Gregor, W. (1805) XXIII. Experiments on a mineral substance formerly supposed to be zeolite; with some remarks on two species of uran-glimmer. Philosophical Transactions Of The Royal Society Of London, 95. 331-348 doi:10.1098/rstl.1805.0025DOI: 10.1098/rstl.1805.0025
  3. 1809Thomson & von Moll (1809) Jahrb. Efem.: 5: 148 (as Devonite).
  4. 1819Fuchs, J. N. (1819) On lasionite and wavellite. Annals of Philosophy, S. 1 Vol. 14. 276-281
  5. 1827Curtis, Samuel and Hooker, William Jackson (1827) Memoirs of the Life and Writing of the Late Mr. William Curtis, Curtis's Botanical Magazine; or Flower Garden Displayed, v. 1 (new series), v-xxxii.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Wavellite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/wavellite-4250},
  note      = {Accessed 2026-05-11}
}