Walentaite

[Mn(H2O)6][◻As3+3Fe3+3(PO4)2O7]
IMA status
  • Approved
IMA symbol
Wlt
Discovered
1983
IMA approved
1983
Also known as
  • IMA1983-047
  • Walentaiet

Where it forms, where it's found

Geological setting

Complex zoned pegmatite.

Type locality
White Elephant Mine
  1. Cicero Peak
  2. Pringle
  3. Custer Mining District
  4. Custer County
  5. South Dakota
  6. USA

43.6554°, -103.5836°

5recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789103/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Bright yellow
Streak
Pale yellow
Tenacity
brittle
Cleavage
Perfect

On (010)

Density
2.72 g/cm³

Optical

Optical type
Biaxial (+)
Refractive index
1.738 – 1.779
Surface relief
High
Principal indices
nβ 1.738 · nγ 1.779
Pleochroism
Weak

Z = medium yellow-green, Y = pale yellow green.

Dispersion
r > v moderate (type description says dispersion not discernible).
Extinction
Z = c, Y = a.
UV response
Not fluorescent.
Notes

Absorption: Z < Y. 2V could not be measured.

Crystallography

Crystal system
Orthorhombic
Space group
Imma
Cell parameters
a = 26.188(5) Å · b = 7.360(2) Å · c = 10.367(2) Å
Ratio a:b:c
1 : 0.281 : 0.396
Morphology

Type material: Bladed crystals approximately 20 x 60 x 1-2 µm in size that are elongate on [001] and flattened perpendicular to b so that (010) is the dominant form. Aggregates forming rosettes.

Type-locality form

Rosette-like aggregates of thin, bladed crystals approximately 20 x 60 x 1-2 µm in size.

Crystal structure

Synonyms

  • IMA1983-047
  • Walentaiet

In other languages

German
IMA 1983-047 · Walentait
Italian
Walentaite
Chinese
瓦伦特石

Classification

Strunz
10th ed.

8.CH.05

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.CPhosphates without additional anions, with H2ODivision
  • 8.CHWith large and medium-sized cations, RO4:H2O < 1:1Group
  • 8.CH.05WalentaiteSpecies
Dana
8th ed.

40.05.10.01

  • 40Hydrated Normal Phosphates, Arsenates and VanadatesClass
  • 40.05AXO4·xH2OType
  • 40.05.10— unnamed intermediate level —Group
  • 40.05.10.01WalentaiteSpecies
CIM

20.9.17

  • 20Arsenates (also arsenates with phosphate, but without other anions)Class
  • 20.9Arsenates of FeGroup
  • 20.9.17WalentaiteSpecies

Group, growth & confusion

In the same group
1 members

Literature, links & citation

Citations
  1. 1984Dunn, Pete J.; Cabri, Louis J.; Ferraiolo, James A.; Grice, Joel Do.; Jambor, John L.; Mueller, Wolfgang; Shigley, James E.; Puziewicz, Jacek; Vanko, David A. (1984) New mineral names. American Mineralogist, 69 (11-12). 1190-1196
  2. 1984Dunn, P. J., Peacor, D. R., Roberts, W. L., Campbell, T. J., Ramik, R. A. (1984) Walentaite, a new calcium iron arsenate phosphate from the White Elephant mine, Pringle, South Dakota. Neues Jahrbuch für Mineralogie - Monatshefte, 1984. 169-174
  3. 1987Nickel, E.H. (1987) Tungsten-bearing walentaite from Griffins Find gold deposit, Western Australia. Australian Mineralogist, 2(1), 9–12.
  4. 2005(2005) Walentaite. Handbook of Mineralogy. Mineralogical Society of America
  5. 2019Grey, Ian Edward, Mumme, William Gus, Hochleitner, Rupert (2019) Trimeric As3+3O6 clusters in walentaite: crystal structure and revised formula. European Journal of Mineralogy, 31 (1). 111-116 doi:10.1127/ejm/2018/0030-2790DOI: 10.1127/ejm/2018/0030-2790
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Walentaite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/walentaite-4235},
  note      = {Accessed 2026-05-11}
}