Wallkilldellite-(Fe)

Ca2Fe2+3(AsO4)2(OH)4 · 9H2O
IMA status
  • Approved
IMA symbol
Wlk-Fe
IMA approved
1997
Also known as
  • IMA1997-032
  • Wallkilldelliet-(Fe)

Where it forms, where it's found

Geological setting

oxidation zone of copper arsenide deposit

Type locality
Roua Mines (Clue de Roua)
  1. Daluis
  2. Nice Arrondissement
  3. Alpes-Maritimes
  4. Provence-Alpes-Côte d'Azur
  5. France

44.0304°, 6.8677°

10recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789102 – 3/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous · Resinous
Transparency
Translucent
Colour
Brown to brownish yellow
Streak
Light brown
Cleavage
Perfect

(0001)

Density
3.0 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
1.75
Surface relief
High
Principal indices
nω 1.750
Pleochroism
Strong

O = brown; E = pale brown-yellow.

Crystallography

Crystal system
Hexagonal
Cell parameters
a = 6.548(5) Å · c = 23.49(3) Å
Z
1
Morphology

Spherules, to 0.1 mm, consisting of extremely thin radiating plates,

Comment

Point Group: 6/m 2/m 2/m, _6m2, or 6mm; space group: P63/mmc, P_62c, or P63mc. Enju and Uehara (2015), give, for well-crystallsied material, a different hexagonal cell: a = 11.341(6) Å and c = 11.57(2) Å.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen2115.999335.979
44.46%
26FeIronIron355.845167.535
22.17%
33AsArsenicArsenic274.922149.844
19.83%
20CaCalciumCalcium240.07880.156
10.61%
1HHydrogenHydrogen221.00822.176
2.93%
Total755.690100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1997-032
  • Wallkilldelliet-(Fe)

In other languages

German
IMA 1997-032 · Wallkilldellit-(Fe)
Italian
Wallkilldellite- · Wallkilldellite-(Fe)

Classification

Strunz
10th ed.

8.DL.20

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DLWith large and medium-sized cations, (OH, etc.):RO4 = 2:1Group
  • 8.DL.20Wallkilldellite-(Fe)Species

Group, growth & confusion

Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1999Sarp, H., Mari, G., and Chiappero, P.-J. (1999) La wallkilldellite-Fe, (Ca,Cu)4Fe6((As,Si)O4)4(OH)8.18H2O, un nouveau minéral de la mine de Roua (Alpes Maritimes, France) [Wallkilldellite-Fe, (Ca,Cu)4Fe6[(As,Si)O4]4(OH)8·18H2O, a new mineral from the Roua mine (Alpes-Maritimes, France)]. Riviéra Scientifique, 12, 5-12. (in French with English abstract).
  2. 2001Jambor, J.L. and Roberts, A.C. (2001) New mineral names. American Mineralogist: 86: 197-200.
  3. 2006Walenta, K. (2006) Über das neue arseniosideritähnliche Mineral aus dem Schwarzwald und seine Beziehungen zum Wallkilldellit-Fe. Erzgräber 20, 15-17. (in German).
  4. 2015ENJU, Satomi, UEHARA, Seiichiro (2015) Yukonite and wallkilldellite–(Fe) from the Kiura mine, Oita Prefecture, Japan. Journal of Mineralogical and Petrological Sciences, 110 (3) 150-155 doi:10.2465/jmps.141022b DOI: 10.2465/jmps.141022b
  5. 2021(2021) Wallkilldellite-(Fe). Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Wallkilldellite-(Fe) — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/wallkilldellite-fe-7361},
  note      = {Accessed 2026-05-11}
}