Wroewolfeite

Cu4(SO4)(OH)6 · 2H2O
IMA status
  • Approved
IMA symbol
Wwf
Discovered
1973
IMA approved
1973
Also known as
  • IMA1973-064
  • Wroewolfeiet

Where it forms, where it's found

Type locality
Loudville Lead Mines (Manhan Lead-Silver Mine
  1. Southampton Lead Mine
  2. Northampton Lead Mine)
  3. Easthampton
  4. Hampshire County
  5. Massachusetts
  6. USA

42.2811°, -72.7322°

104recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Intense blue-green · bluish
Streak
Blue-green

Optical

Optical type
Biaxial (-) · 2V measured = 53° · 2V calc = 52°
Refractive index
1.637 – 1.694
Surface relief
High
Principal indices
nα 1.637 · nβ 1.682 · nγ 1.694
Dispersion
weak
Michel-Lévy diagramhighlighted lineδ = 0.0570
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]570 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation570 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
#6
Cell parameters
a = 6.045(1) Å · b = 5.646(1) Å · c = 14.337(6) Å
Cell angles
β = 93.39(1) °
Ratio a:b:c
1 : 0.934 : 2.372
Z
2
Morphology

Tabular, ruler- or sword-shaped, blocky, prismatic.

Twinning

By reflection on (001) and (100), yielding fourlings.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
29CuCopperCopper463.546254.184
52.05%
8OOxygenOxygen1215.999191.988
39.32%
16SSulfurSulfur132.06032.060
6.57%
1HHydrogenHydrogen101.00810.080
2.06%
Total488.312100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1973-064
  • Wroewolfeiet

In other languages

German
IMA 1973-064 · Wroewolfeit
Italian
Wroewolfeite
Chinese
斜蓝铜矾

Classification

Strunz
10th ed.

7.DD.10

  • 7SulfatesClass
  • 7.DSulfates (selenates, etc.) with additional anions, with H2ODivision
  • 7.DDWith only medium-sized cations; sheets of edge-sharing octahedraGroup
  • 7.DD.10WroewolfeiteSpecies
Dana
8th ed.

31.04.02.01

  • 31Hydrated Sulfates Containing Hydroxyl or HalogenClass
  • 31.04(AB)4(XO4)Zq·xH2OType
  • 31.04.02— unnamed intermediate level —Group
  • 31.04.02.01WroewolfeiteSpecies
CIM

25.2.10

  • 25SulphatesClass
  • 25.2Sulphates of Cu and AgGroup
  • 25.2.10WroewolfeiteSpecies

Group, growth & confusion

Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1975Dunn, Pete J., Rouse, Roland C., Nelen, J. A. (1975) Wroewolfeite, a new copper sulphate hydroxide hydrate. Mineralogical Magazine, 40 (309) 1-5 doi:10.1180/minmag.1975.040.309.01 DOI: 10.1180/minmag.1975.040.309.01
  2. 1976American Mineralogist (1976): 61: 179.
  3. 1982Braithwaite, Richard S.W. (1982) Wroewolfeite in Britain. The Mineralogical Record, 13 (3) 167-174
  4. 1985Hawthorne, F. C., Groat, L. A. (1985) The crystal structure of wroewolfeite, a mineral with [Cu4(OH)6(SO4)(H2O)] sheets. American Mineralogist, 70 (9-10) 1050-1055
  5. 2005(2005) Wroewolfeite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Wroewolfeite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/wroewolfeite-4315},
  note      = {Accessed 2026-05-11}
}