Xitieshanite

Fe3+(SO4)Cl · 6H2O
IMA status
  • Approved
IMA symbol
Xit
Discovered
1983
Also known as
  • Xitieshaniet

Where it forms, where it's found

Geological setting

Oxidation zone of a lead-zinc deposit.

Type locality
Xitieshan Mine
  1. Xitieshan
  2. Da Qaidam (Dachaidan Co.)
  3. Haixi Mongol and Tibetan Autonomous Prefecture
  4. Qinghai
  5. China

37.3294°, 95.5675°

6recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Bright green · yellowish tint
Streak
Yellow
Cleavage
Imperfect/Fair
Fracture
Irregular/Uneven · Conchoidal
Density
1.99 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 77° · 2V calc = 78°
Refractive index
1.536 – 1.628
Surface relief
Moderate
Principal indices
nα 1.536 · nβ 1.570 · nγ 1.628
Pleochroism
Strong

X = colourless to pale yellow tint; Y = pale yellow; Z = light yellow with greenish tint.

Dispersion
r < v strong
Extinction
Extinction parallel or inclined, elongation positive or negative.
Michel-Lévy diagramhighlighted lineδ = 0.0920
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]920 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation920 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P21/a
Cell parameters
a = 14.102 Å · b = 6.908 Å · c = 10.673 Å
Cell angles
β = 111.26 °
Ratio a:b:c
1 : 0.490 : 0.757
Z
4
Type-locality form

Rhombic rectangular crystals or massive aggregates up to 2 x 2 cm.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1015.999159.990
54.15%
26FeIronIron155.84555.845
18.90%
17ClChlorineChlorine135.45035.450
12.00%
16SSulfurSulfur132.06032.060
10.85%
1HHydrogenHydrogen121.00812.096
4.10%
Total295.441100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Xitieshaniet

In other languages

German
IMA 1982-044 · Xitieshanit
Italian
Xitieshanite
Chinese
锡铁山石

Classification

Strunz
10th ed.

7.DC.20

  • 7SulfatesClass
  • 7.DSulfates (selenates, etc.) with additional anions, with H2ODivision
  • 7.DCWith only medium-sized cations; chains of edge-sharing octahedraGroup
  • 7.DC.20XitieshaniteSpecies
Dana
8th ed.

31.09.06.03

  • 31Hydrated Sulfates Containing Hydroxyl or HalogenClass
  • 31.09(AB)(XO4)Zq·xH2OType
  • 31.09.06Botryogen GroupGroup
  • 31.09.06.03XitieshaniteSpecies
CIM

26.28

  • 26Sulphates with HalideClass
  • 26.28— unnamed intermediate level —Group
  • 26.28XitieshaniteSpecies

Group, growth & confusion

In the same group
1 members

Literature, links & citation

Citations
  1. 1982Li, Xilin; Zhou, Jingliang; Li, Jiaju (1982): Xitieshanite - A new ferric sulfate mineral. Acta Mineralogica Sinica, 2(4), 241-247. (in Chinese with English abstract).
  2. 1983Li, X., Zhou, J., Li, J. (1983) Xitieshanite – A new ferric sulphate mineral. Geochemistry, 2, 261-267.
  3. 1984Dunn, Pete J.; Cabri, Louis J.; Ferraiolo, James A.; Grice, Joel Do.; Jambor, John L.; Mueller, Wolfgang; Shigley, James E.; Puziewicz, Jacek; Vanko, David A. (1984) New mineral names. American Mineralogist, 69 (11-12). 1190-1196
  4. 1988Zhou, Jingliang; Li, Jiaju; and Dong, Wei; (1988): The crystal structure of xitieshanite. Chinese Science Bulletin [Kexue Tongbao], 33, 502-505.
  5. 1989Jambor, John L., Burke, Ernst A. J. (1989) New Mineral Names. American Mineralogist, 74 (11-12) 1399-1404
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Xitieshanite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/xitieshanite-4341},
  note      = {Accessed 2026-05-11}
}