Fibroferrite

Fe3+(SO4)(OH) · 5H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Ffr
Discovered
1833
Also known as
  • Copiapite (of Smith)
  • Fibroferriet
  • Stypticit
  • +1 more

Where it forms, where it's found

Geological setting

Areas experiencing the oxidation of pyrite.

Type locality
Tierra Amarilla
  1. Copiapó Province
  2. Atacama
  3. Chile
112recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102 – 2.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Light yellow · golden yellow · nearly white · greenish grey · yellowish green · light green · colourless to faint yellow in transmitted light.
Cleavage
Perfect

On (001), perfect.

Density
1.84 g/cm³

Optical

Optical type
Uniaxial (+)
Refractive index
1.532 – 1.57
Surface relief
Moderate
Principal indices
nω 1.532 · nε 1.57
Pleochroism
Visible

X = Colourless Y = Colourless Z = c = Light golden yellow

Michel-Lévy diagramhighlighted lineδ = 0.0380
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]380 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation380 nm
Order1st order
XPL colour

Crystallography

Crystal system
Trigonal
Space group
#80
Cell parameters
a = 24.153(6) Å · c = 7.637(2) Å
Z
18
Morphology

Occurs as fine-fibrous crusts and masses; botryoidal; radial-fibrous structured. Fibers elongated [001].

Twinning

Repeated on (110), as triplets elongated [001].

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1015.999159.990
61.78%
26FeIronIron155.84555.845
21.56%
16SSulfurSulfur132.06032.060
12.38%
1HHydrogenHydrogen111.00811.088
4.28%
Total258.983100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Copiapite (of Smith)
  • Fibroferriet
  • Stypticit
  • Stypticite

In other languages

German
Fibroferrit
Italian
fibroferrite

Classification

Strunz
10th ed.

7.DC.15

  • 7SulfatesClass
  • 7.DSulfates (selenates, etc.) with additional anions, with H2ODivision
  • 7.DCWith only medium-sized cations; chains of edge-sharing octahedraGroup
  • 7.DC.15FibroferriteSpecies
Dana
8th ed.

31.09.12.01

  • 31Hydrated Sulfates Containing Hydroxyl or HalogenClass
  • 31.09(AB)(XO4)Zq·xH2OType
  • 31.09.12— unnamed intermediate level —Group
  • 31.09.12.01FibroferriteSpecies
CIM

25.10.18

  • 25SulphatesClass
  • 25.10Sulphates of Fe aloneGroup
  • 25.10.18FibroferriteSpecies

Group, growth & confusion

In the same group
1 members

Literature, links & citation

Citations
  1. 1833Rose, Heinrich (1833) Ueber einige in Südamerika vorkommende Eisenoxydsalze. Annalen der Physik und Chemie, 103. 309-319 doi:10.1002/andp.18331030209DOI: 10.1002/andp.18331030209
  2. 1841Prideaux (1841) Philosophical Magazine and Journal of Science: 18: 397.
  3. 1847Hausmann, J.F.L. (1847) Handbuch der Mineralogie, Göttingen. Second edition: vol. 2, in two parts: 2: 1202 (as Stypticit).
  4. 1854Smith (1854) American Journal of Science: 18: 375 (as Copiapite [of Smith]).
  5. 1889Linck G (1889) Beitrag zur Kenntniss der Sulfate von Terra amarilla bei Copiapó in Chile. Zeitschrift für Krystallographie und Mineralogie 15, 1-28
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Fibroferrite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/fibroferrite-1544},
  note      = {Accessed 2026-05-11}
}