Zigrasite

MgZr(PO4)2 · 4H2O
IMA status
  • Approved
IMA symbol
Zig
IMA approved
2008
Also known as
  • IMA2008-046
  • Zigrasiet

Where it forms, where it's found

Geological setting

A complex rare-element granitic pegmatite.

Type locality
Dunton Gem Quarry
  1. Newry
  2. Oxford County
  3. Maine
  4. USA

44.5428°, -70.7231°

1recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Pale-yellow or light tan · also orange to off-white
Streak
White
Tenacity
brittle
Cleavage
Imperfect/Fair

Imperfect in two directions, parallel to (010) and (001)

Fracture
Hackly
Density
2.76 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 65.4° · 2V calc = 71°
Refractive index
1.597 – 1.635
Surface relief
Moderate
Principal indices
nα 1.597 · nβ 1.622 · nγ 1.635
Pleochroism
Non-pleochroic
Michel-Lévy diagramhighlighted lineδ = 0.0380
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]380 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation380 nm
Order1st order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
#2
Cell parameters
a = 5.3049(2) Å · b = 9.3372(4) Å · c = 9.6282(4) Å
Cell angles
α = 97.348(1) ° · β = 91.534(1) ° · γ = 90.512(1) °
Ratio a:b:c
1 : 1.760 : 1.815
Unit cell volume
472.79 ų
Z
2
Twinning

Not mentioned in type description.

Parting
None
Type-locality form

Subhedral blocky grains sometimes exceeding 1 mm in max. dimension.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1215.999191.988
50.85%
40ZrZirconiumZirconium191.22491.224
24.16%
15PPhosphorusPhosphorus230.97461.948
16.41%
12MgMagnesiumMagnesium124.30524.305
6.44%
1HHydrogenHydrogen81.0088.064
2.14%
Total377.529100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2008-046
  • Zigrasiet

In other languages

German
IMA 2008-046 · Zigrasit
Italian
zigrasite
Chinese
水磷镁锆石

Classification

Strunz
10th ed.

8.CE.75

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.CPhosphates without additional anions, with H2ODivision
  • 8.CEWith only medium-sized cations, RO4:H2O about 1:2.5Group
  • 8.CE.75ZigrasiteSpecies
Dana
8th ed.

40.01.05.02

  • 40Hydrated Normal Phosphates, Arsenates and VanadatesClass
  • 40.01AB(XO4)·xH2OType
  • 40.01.05— unnamed intermediate level —Group
  • 40.01.05.02ZigrasiteSpecies

Group, growth & confusion

In the same group
1 members

Literature, links & citation

Citations
  1. 2008Williams, P.A., Hatert, F., Pasero, M. (2008) New minerals approved in 2008. in International Mineralogical Association: 1-13.
  2. 2009Hawthorne, F. C., Ball, N. A., Nizamoff, J. W., Simmons, W. B. (2009) Zigrasite, MgZr(PO4)2(H2O)4, a new phosphate mineral from the Dunton Quarry, Newry, Oxford County, Maine, USA. Mineralogical Magazine, 73 (3) 415-420 doi:10.1180/minmag.2009.073.3.415 DOI: 10.1180/minmag.2009.073.3.415
  3. 2009Hawthorne, F. C., Ball, N. A., Nizamoff, J. W., Simmons, W. B. (2009) Errata: Zigrasite, MgZr(PO4)2(H2O)4, a new phosphate mineral from the Dunton Quarry, Newry, Oxford County, Maine, USA. Mineralogical Magazine, 73 (6) 1063 doi:10.1180/s0026461x00053846DOI: 10.1180/s0026461x00053846
  4. 2010Hawthorne, F. C., Simmons, W. B. (2010) The crystal structure of zigrasite, MgZr(PO4)2(H2O)4, a heteropolyhedral framework structure. Mineralogical Magazine, 74 (3) 567-575 doi:10.1180/minmag.2010.074.3.567 DOI: 10.1180/minmag.2010.074.3.567
  5. 2011Piilonen, P. C., Rowe, R., Poirier, G., Tait, K. T. (2011) New Mineral Names. American Mineralogist, 96 (10) 1654-1661 doi:10.2138/am.2011.579DOI: 10.2138/am.2011.579
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Zigrasite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/zigrasite-39007},
  note      = {Accessed 2026-05-11}
}