Zinkenite

Pb9Sb22S42
IMA status
  • Approved
  • Grandfathered
IMA symbol
Zkn
Discovered
1826
Also known as
  • Bleiantimonglanz
  • Keeleyit
  • Keeleyita
  • +6 more

Where it forms, where it's found

Type locality
Graf Jost-Christian Mine
  1. Wolfsberg
  2. Sangerhausen
  3. Mansfeld-Südharz
  4. Saxony-Anhalt
  5. Germany

51.5531°, 11.0861°

237recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789103 – 3.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Metallic
Transparency
Opaque
Colour
Steel-grey
Streak
Steel-grey
Cleavage
Poor/Indistinct

On {112¯0}

Fracture
Irregular/Uneven
Density
5.25 g/cm³

Optical

Pleochroism
Weak
Optical colour
Grey-white
Anisotropism
Distinct
Tropism
Anisotropic
Reflectance R%
(39.1,44.2) 400, (39.2,44.4) 420, (39.3,44.6) 440, (39.2,44.5) 460, (39.0,44.2) 480, (38.8,43.8) 500, (38.4,43.2) 520, (37.9,42.5) 540, (37.3,41.8) 560, (36.7,41.0) 580, (36.0,40.4) 600, (35.4,39.8) 620, (34.6,39.0) 640, (34.0,38.2) 660, (33.2,37.3) 680, (32.4,36.3) 700
Reflected-light panel
36.9 %anisotropic · dual curve
Specimen sRGB 212, 153, 87
White reference100 % reflector under same lamp
R₁ R₂
Mode
Anisotropism
Distinct
Reflected colour
Grey-white

Crystallography

Crystal system
Hexagonal
Space group
#104
Cell parameters
a = 22.12 Å · c = 4.31 Å
Morphology

Crystals thin prismatic, and striated [0001] due, in part, to subparallel aggregation. Crystals seldom distinct. Columnar to radial fibrous aggregates; massive.

Comment

Some crystals exhibit a superstructure with a doubled c parameter. Cell is also given as a = 44.15 c = 8.62 A.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
51SbAntimonyAntimony22121.7602678.720
45.48%
82PbLeadLead9207.2001864.800
31.66%
16SSulfurSulfur4232.0601346.520
22.86%
Total5890.040100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Ag
  • Cu
  • Fe
  • As

Synonyms

  • Bleiantimonglanz
  • Keeleyit
  • Keeleyita
  • Keeleyite
  • Keelyit
  • Keelyita
  • Keelyite
  • Zinckenit
  • Zinckenite

In other languages

French
Zinkénite
German
Zinkenit
Spanish
Zinkenita
Italian
Zinkenite
Chinese
辉锑铅矿
Russian
цинкенит

Classification

Strunz
10th ed.

2.JB.35a

  • 2Sulfides and SulfosaltsClass
  • 2.JSulfosalts of PbS archetypeDivision
  • 2.JBGalena derivatives, with PbGroup
  • 2.JB.35aZinkeniteSpecies
Dana
8th ed.

03.08.01.01

  • 03SulfosaltsClass
  • 03.081 < ø < 2Type
  • 03.08.01Zinkenite GroupGroup
  • 03.08.01.01ZinkeniteSpecies
CIM

5.6.8

  • 5Sulphosalts - Sulpharsenites and Sulphobismuthites (those containing Sn, Ge,or V are in Section 6)Class
  • 5.6Sulpharsenites etc. of Pb aloneGroup
  • 5.6.8ZinkeniteSpecies

Group, growth & confusion

Often grow together
2 minerals

Literature, links & citation

Citations
  1. 1826Rose, Gustav (1826) Ueber den Zinkenit, eine neue Mineralgattung. Annalen der Physik, 83. 91-96 doi:10.1002/andp.18260830508 DOI: 10.1002/andp.18260830508
  2. 1826Rose, H. (1826) Ueber die chemische Zusammensetzung des Zinkenits und des Jamesonits. Annalen der Physik und Chemie: 8: 99-102.
  3. 1827Rose, G. (1827) On zinkenite, a new mineral species. The Edinburgh Journal of Science: 6: 17-20.
  4. 1890Eakins (1890) American Journal of Science: 39: 74 (as warrenite, in part).
  5. 1897Spencer, L. J. (1897) Zinckenite and Wolfsbergite (Chalcostibite) from Wolfsberg in the Harz; and the Zinckenite Group. Mineralogical Magazine and Journal of the Mineralogical Society, 11 (52). 188-191 doi:10.1180/minmag.1897.011.52.06 DOI: 10.1180/minmag.1897.011.52.06
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Zinkenite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/zinkenite-4417},
  note      = {Accessed 2026-05-11}
}