Azoproite

Mg2[(Ti,Mg),Fe3+]O2(BO3)
IMA status
  • Approved
IMA symbol
Azo
Discovered
1970
IMA approved
1970
Also known as
  • Asoproit
  • Azoproiet
  • Azoproitt
  • +1 more

Where it forms, where it's found

Geological setting

Magnesian skarns in the contact aureole of the Tazheran alkalic massif.

Type locality
Tazheranskii Massif
  1. Russia

52.8417°, 106.7156°

5recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789105.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Adamantine
Transparency
Translucent · Opaque
Colour
Black
Tenacity
brittle
Cleavage
Distinct/Good

Good on (010), less good on (001)

Fracture
Conchoidal
Density
3.63 g/cm³

Optical

Optical type
Biaxial (+)
Refractive index
1.799 – 1.855
Surface relief
Very high
Principal indices
nα 1.799 · nβ 1.822 · nγ 1.855
Pleochroism
Strong

X pale green with bluish tint, Y dark green, nearly opaque, Z reddish-brown, absorption Y>Z>X.

Dispersion
r > v medium
Michel-Lévy diagramhighlighted lineδ = 0.0560
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]560 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation560 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
Pbam
Cell parameters
a = 9.26(1) Å · b = 12.25(1) Å · c = 3.01(1) Å
Ratio a:b:c
1 : 1.323 : 0.325
Z
4
Type-locality form

Prismatic crystals 1 to 20 mm long and 0.1 to 5 mm wide.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen515.99979.995
29.91%
12MgMagnesiumMagnesium324.30572.915
27.27%
26FeIronIron155.84555.845
20.88%
22TiTitaniumTitanium147.86747.867
17.90%
5BBoronBoron110.81010.810
4.04%
Total267.432100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Asoproit
  • Azoproiet
  • Azoproitt
  • IMA1970-021

In other languages

French
azoproïte
German
Azoproit · IMA 1970-021
Italian
Azoproite

Classification

Strunz
10th ed.

6.AB.30

  • 6BoratesClass
  • 6.AMonoboratesDivision
  • 6.ABBO3, with additional anions; 1(D) + OH, etc.Group
  • 6.AB.30AzoproiteSpecies
Dana
8th ed.

24.02.01.03

  • 24Anhydrous BoratesClass
  • 24.02A2BO2[XO3]Type
  • 24.02.01Ludwigite Group (Space Group: Pbam)Group
  • 24.02.01.03AzoproiteSpecies
CIM

9.6.2

  • 9BoratesClass
  • 9.6Borates of Ti, Sn and TaGroup
  • 9.6.2AzoproiteSpecies

Group, growth & confusion

In the same group
6 members

Literature, links & citation

Citations
  1. 1970Konev, A.A., Lesedeva, V.S., Kashaev, A.A., Ushchapovskaya, Z.F. (1970) Azoproite, a new mineral of the ludwigite group. Zapiski Vsesoyuznogo Mineralogicheskogo Obshchestva: 99(2): 225-231.
  2. 1971Fleischer, Michael (1971) New Mineral Names. American Mineralogist, 56 (1-2) 358-362
  3. 2005(2005) Azoproite. Handbook of Mineralogy. Mineralogical Society of America
  4. 2011Frost, Ray L. (2011) Raman spectroscopy of selected borate minerals of the pinakiolité group. Journal of Raman Spectroscopy, 42 (3). 540-543 doi:10.1002/jrs.2745DOI: 10.1002/jrs.2745
  5. 2017Bilohuščin, Vladimír, Uher, Pavel, Koděra, Peter, Milovská, Stanislava, Mikuš, Tomáš, Bačík, Peter (2017) Evolution of borate minerals from contact metamorphic to hydrothermal stages: Ludwigite-group minerals and szaibélyite from the Vysoká – Zlatno skarn, Slovakia. Mineralogy and Petrology, 111 (4) 643-658 doi:10.1007/s00710-017-0518-yDOI: 10.1007/s00710-017-0518-y
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Azoproite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/azoproite-442},
  note      = {Accessed 2026-05-11}
}