Ludwigite

Mg2Fe3+O2(BO3)
IMA status
  • Approved
  • Grandfathered
IMA symbol
Ldw
Discovered
1874
Also known as
  • Collbranite
  • Magnesioludwigite

Where it forms, where it's found

Geological setting

In contact metamorphic deposits as high-temperature phases.

Type locality
Ocna de Fier
  1. Caraş-Severin County
  2. Romania
124recorded occurrences
Source · OpenStreetMap

Varieties

Physical

Hardness
123456789105/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Silky
Transparency
Opaque
Colour
Dark-green to black
Streak
Black, blackish green
Cleavage
None Observed

tenacity - tough

Fracture
Fibrous
Density
3.80 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 20 – 45°
Refractive index
1.83 – 2.03
Surface relief
Very high
Principal indices
nα 1.83 – 1.85 · nβ 1.83 – 1.90 · nγ 1.97 – 2.03
Pleochroism
Strong

X = Dark green Y = Dark green Z = Dark reddish brown (may be opaque)

Dispersion
r greater than v, extreme
Anisotropism
yellowish brown to bluish violet gray.
Bireflectance
Pinkish gray to dark greenish gray
Tropism
Anisotropic
Reflectance R%
(10.1,13.8) 400, (9.7,13.2) 420, (9.3,12.6) 440, (9.0,12.1) 460, (8.7,11.8) 480, (8.5,11.5) 500, (8.2,11.3) 520, (8.1,11.2) 540, (7.9,11.0) 560, (7.8,10.9) 580, (7.6,10.8) 600, (7.5,10.8) 620, (7.4,10.8) 640, (7.3,10.8) 660, (7.2,10.8) 680, (7.2,10.9) 700
Reflected-light panel
8.2 %anisotropic · dual curve
Specimen sRGB 105, 74, 42
White reference100 % reflector under same lamp
R₁ R₂
Mode
Bireflectance
Pinkish gray to dark greenish gray
Anisotropism
yellowish brown to bluish violet gray.

Crystallography

Crystal system
Orthorhombic
Space group
Pbam
Cell parameters
a = 9.2411(6) Å · b = 12.2948(9) Å · c = 3.0213(3) Å
Ratio a:b:c
1 : 1.330 : 0.327
Z
4
Morphology

Crystals prismatic [001], rare, with a rhombic cross-section and lacking terminal faces. As fibrous masses, radiating to dense felted aggregates; sheaf-like aggregates; rosettes of needle-like crystals. Granular.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen515.99979.995
40.97%
26FeIronIron155.84555.845
28.60%
12MgMagnesiumMagnesium224.30548.610
24.89%
5BBoronBoron110.81010.810
5.54%
Total195.260100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Al

Synonyms

  • Collbranite
  • Magnesioludwigite

In other languages

French
ludwigite
German
Ludwigit
Spanish
Ludwigita
Italian
Ludwigite
Japanese
ルドウィヒ石
Chinese
硼镁铁矿

Classification

Strunz
10th ed.

6.AB.30

  • 6BoratesClass
  • 6.AMonoboratesDivision
  • 6.ABBO3, with additional anions; 1(D) + OH, etc.Group
  • 6.AB.30LudwigiteSpecies
Dana
8th ed.

24.02.01.01

  • 24Anhydrous BoratesClass
  • 24.02A2BO2[XO3]Type
  • 24.02.01Ludwigite Group (Space Group: Pbam)Group
  • 24.02.01.01LudwigiteSpecies
CIM

9.8.2

  • 9BoratesClass
  • 9.8Borates of FeGroup
  • 9.8.2LudwigiteSpecies

Group, growth & confusion

In the same group
6 members
Often grow together
4 minerals
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1874Tschermak, G. (1874) Ludwigit, ein neues mineral aus dem Banate. Mineralogische und petrographische Mittheilungen, Vienna: 1874: 59-66.
  2. 1888Mallard, Ernest (1888) Sur quelques substances cristallisées préparées par Ebelmen. Bulletin de la Société française de Minéralogie, 11 (8). 305-311 doi:10.3406/bulmi.1888.3212DOI: 10.3406/bulmi.1888.3212
  3. 1889Groth (1889) Zeitschrift für Kristallographie, Mineralogie und Petrographie, Leipzig: 15: 650.
  4. 1892Dana, Edward Salisbury; Dana, James Dwight (1892) A System of Mineralogy (6th ed.). John Wiley & Sons, Inc.
  5. 1897Goldschmidt (1897): 224.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Ludwigite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/ludwigite-2454},
  note      = {Accessed 2026-05-11}
}