Bariopharmacosiderite

Ba0.5Fe3+4(AsO4)3(OH)4 · 5H2O
IMA status
  • Approved
IMA symbol
Bpsd
IMA approved
1990
Also known as
  • Bariopharmacosideriet
  • Bariopharmacosiderit
  • Barium-Pharmacosiderite
  • +2 more

Where it forms, where it's found

Type locality
Clara Mine
  1. Oberwolfach
  2. Ortenaukreis
  3. Freiburg Region
  4. Baden-Württemberg
  5. Germany

48.3797°, 8.2289°

177recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Brown · yellow · reddish brown · reddish · greenish · bluish
Cleavage
Distinct/Good

(100) and (001), both good

Fracture
Conchoidal
Density
3.05 g/cm³

Optical

Optical type
Uniaxial (+/-) · 2V measured = 39°
Refractive index
1.718 – 1.728
Surface relief
High
Principal indices
nω 1.728 · nε 1.718
Pleochroism
Non-pleochroic
Michel-Lévy diagramhighlighted lineδ = 0.0100
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]100 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation100 nm
Order1st order
XPL colour

Crystallography

Crystal system
Tetragonal
Space group
#148
Cell parameters
a = 7.97 Å · c = 8.1 Å
Z
1
Type-locality form

Cubic yellow-brown crystals up to 1 mm in size.

Comment

Pseudocubic

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen2115.999335.979
38.75%
33AsArsenicArsenic374.922224.766
25.93%
26FeIronIron455.845223.380
25.77%
56BaBariumBarium0.5137.32768.663
7.92%
1HHydrogenHydrogen141.00814.112
1.63%
Total866.900100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Bariopharmacosideriet
  • Bariopharmacosiderit
  • Barium-Pharmacosiderite
  • Barium-Pharmakosiderit
  • Bariumpharmocosiderit

In other languages

German
Bariopharmakosiderit
Spanish
Bariofarmacosiderita
Italian
Bario-farmacosiderite · bariofarmacosiderite
Russian
Бариофармакосидерит

Classification

Strunz
10th ed.

8.DK.10

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DKWith large and medium-sized cations, (OH, etc.):RO4 > 1:1 and < 2:1Group
  • 8.DK.10BariopharmacosideriteSpecies
Dana
8th ed.

42.08.1a.03

  • 42Hydrated Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 42.08(AB)5(XO4)3Zq·xH2OType
  • 42.08.1a— unnamed intermediate level —Group
  • 42.08.1a.03BariopharmacosideriteSpecies
CIM

20.2.22

  • 20Arsenates (also arsenates with phosphate, but without other anions)Class
  • 20.2Arsenates of Be, Mg, Ca or BaGroup
  • 20.2.22BariopharmacosideriteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1966Walenta, Kurt, Walenta, Kurt (1966) Beiträge zur Kenntnis seltener Arsenatmineralien unter besonderer Berücksichtigung von Vorkommen des Schwarzwaldes. 3. Folge (Schluß). [Rare arsenate minerals with special consideration of occurrences in the Black Forest. Part III (end)]. Tschermaks Mineralogische und Petrographische Mitteilungen, 11 (1). 121-164 doi:10.1007/bf01127708DOI: 10.1007/bf01127708
  2. 1967Fleischer, M. (1967) New Mineral Names. American Mineralogist, 52 (9-10) 1579-1589
  3. 1985Dunn, Pete J., Peacor, Donald R. (1985) Sodium-pharmacosiderite, a New Analog of Pharmacosiderite from Australia, and New Occurrences of Barium-pharmacosiderite. The Mineralogical Record, 16 (2) 121-124
  4. 1994Walenta, K. (1994): Über den Barium-Pharmakosiderit. Aufschluss, 45, 73-81. (in German)
  5. 2008Burke, Ernst A. J. (2008) Tidying up mineral names: an IMA-CNMNC scheme for suffixes, hyphens and diacritical marks. The Mineralogical Record, 39 (2) 131-135
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Bariopharmacosiderite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/bariopharmacosiderite-472},
  note      = {Accessed 2026-05-11}
}