Natropharmacosiderite

NaFe3+4(AsO4)3(OH)4 · 4H2O
IMA status
  • Approved
IMA symbol
Npsd
Discovered
1983
IMA approved
1983
Also known as
  • IMA1983-025
  • Na Pharmacosiderit
  • Na Pharmacosiderite
  • +3 more

Where it forms, where it's found

Geological setting

Oxidized zones of arsenic-bearing deposits.

Type locality
Marda oxidized zone
  1. Marda Project
  2. Mount Jackson Goldfield
  3. Yilgarn Shire
  4. Western Australia
  5. Australia

-30.2500°, 119.2500°

22recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789103/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Light green · dull orange · pale green in transmitted light.
Tenacity
brittle
Cleavage
Imperfect/Fair

On (001), imperfect.

Fracture
Irregular/Uneven
Density
2.79 g/cm³

Optical

Optical type
Isotropic
Surface relief
High
Principal indices
n 1.705
Isotropy testPPL ↔ XPL diagnostic
PPL intrinsic colour; no change on stage rotation
XPL extinct at every orientation
Single index
n = 1.705

Crystallography

Crystal system
Isometric
Space group
#211
Cell parameters
a = 8.012 Å
Z
1
Morphology

Crystals cubic, occur in aggregates.

Type-locality form

Clusters of randomly oriented crystals. Individual crystals are pale green, euhedral cubes without modifying forms, to 0.5 mm.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen2015.999319.980
39.84%
33AsArsenicArsenic374.922224.766
27.98%
26FeIronIron455.845223.380
27.81%
11NaSodiumSodium122.99022.990
2.86%
1HHydrogenHydrogen121.00812.096
1.51%
Total803.212100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1983-025
  • Na Pharmacosiderit
  • Na Pharmacosiderite
  • Natriumpharmakosiderit
  • Natropharmacosideriet
  • Sodium-Pharmacosiderite

In other languages

German
IMA 1983-025 · Natropharmakosiderit
Italian
natrofarmacosiderite · Sodio-farmacosiderite
Russian
Натрофармакосидерит

Classification

Strunz
10th ed.

8.DK.10

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DKWith large and medium-sized cations, (OH, etc.):RO4 > 1:1 and < 2:1Group
  • 8.DK.10NatropharmacosideriteSpecies
Dana
8th ed.

42.08.01.02

  • 42Hydrated Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 42.08(AB)5(XO4)3Zq·xH2OType
  • 42.08.01Pharmacosiderite GroupGroup
  • 42.08.01.02NatropharmacosideriteSpecies
CIM

20.9.8

  • 20Arsenates (also arsenates with phosphate, but without other anions)Class
  • 20.9Arsenates of FeGroup
  • 20.9.8NatropharmacosideriteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1985Dunn, Pete J., Peacor, Donald R. (1985) Sodium-pharmacosiderite, a New Analog of Pharmacosiderite from Australia, and New Occurrences of Barium-pharmacosiderite. The Mineralogical Record, 16 (2) 121-124
  2. 1986American Mineralogist (1986): 71: 230 (abstract).
  3. 1993Kokinos, Michael, Wise, William S. (1993) Famous Mineral Localities: The Gold Hill Mine, Tooele County, Utah. The Mineralogical Record, 24 (1) Tucson. 11-22
  4. 2005(2005) Natropharmacosiderite. Handbook of Mineralogy. Mineralogical Society of America
  5. 2010Hager, S. L., Leverett, P., Williams, P. A., Mills, S. J., Hibbs, D. E., Raudsepp, M., Kampf, A. R., Birch, W. D. (2010) The single-crystal X-ray structures of bariopharmacosiderite-C, bariopharmacosiderite-Q and natropharmacosiderite. The Canadian Mineralogist, 48 (6) 1477-1485 doi:10.3749/canmin.48.5.1477DOI: 10.3749/canmin.48.5.1477
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Natropharmacosiderite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/natropharmacosiderite-3695},
  note      = {Accessed 2026-05-11}
}