Pharmacosiderite

KFe3+4(AsO4)3(OH)4 · 6-7H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Pmsd
Discovered
1813
Also known as
  • Arsenate-zeolite
  • Arsenicated Iron Ore
  • Arseniksaures Eisen im Würfeln kryst.
  • +8 more

History

The name warns you what is inside. Pharmacosiderite joins two Greek words — pharmakon, meaning poison, and sideros, meaning iron. The poison is arsenic, which the mineral holds in quantity, and the iron is the metal it builds itself around.

Before it carried that name, miners called it cube ore. The reason is in the crystals: pharmacosiderite grows as tiny, well-formed cubes, olive-green to honey-yellow and brown, that sit on the rock in plain sight. That blocky habit set it apart from the duller crusts around it long before anyone worked out its chemistry.

The modern name was given in 1813 by the German mineralogist Johann Friedrich Ludwig Hausmann, who built it from the Greek roots for the mineral's two defining elements. He chose poison and iron because those were the parts that mattered — a warning and a description in one word.

The mineral is best known from the copper and tin country of Cornwall, in south-west England, where it occurs in abundance. It is also familiar from Saxony and Bavaria in Germany, and from Utah in the United States.

Pharmacosiderite is a secondary mineral — one that forms not when the rock first crystallises but later, as older minerals break down. It appears in the oxidation zone, the weathered upper part of a deposit where air and water attack the ore. There it grows from the slow alteration of arsenic-bearing minerals such as arsenopyrite and tennantite.

Industrial & practical applications

Pharmacosiderite has no commercial or industrial use. It is too scarce, and forms in crusts too thin, to be mined for the arsenic or the iron it contains. The mineral is wanted mainly by collectors and museums, who prize its sharp little cubes of olive-green to honey-yellow as good display examples of a secondary arsenate.

For a geologist in the field it can also serve as a quiet signpost. Because it forms only where arsenic-bearing minerals are breaking down, its presence in the weathered cap of a deposit points to arsenic in the ore below.

One twist gives the mineral a second life by name only. Chemists have built synthetic frameworks that copy its three-dimensional cubic structure but swap titanium and silicon for the iron and arsenic. These pharmacosiderite-type titanosilicates act as ion exchangers, trapping radioactive caesium and strontium from contaminated water in cleanup research. The natural mineral itself is not used this way — only its atomic blueprint is.

A word of caution for anyone handling a specimen: pharmacosiderite contains arsenic, which is toxic. Do not lick, ingest, or breathe dust from the crystals, and wash your hands after handling them.

Where it forms, where it's found

Geological setting

Oxidation zones of arsenic-bearing sulfide deposits; also in hydrothermal deposits.

Type locality
Carharrack Mine
  1. Gwennap
  2. Cornwall
  3. England
  4. UK

50.2345°, -5.1741°

439recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Pale green · green · emerald-green · dark brown · honey-yellow to yellow-brown · brownish red · hyacinth-red · green · yellow · light brown in transmitted light (biaxially sectored).
Streak
white
Tenacity
brittle
Cleavage
Imperfect/Fair

Imperfect to good on (001).

Described as "somewhat sectile"

Fracture
Irregular/Uneven
Density
2.797 g/cm³

Optical

Optical type
Isotropic · 2V measured = 80 – 90°
Refractive index
1.66 – 1.704
Surface relief
High
Principal indices
nα 1.660 – 1.697 · nβ 1.661 – 1.700 · nγ 1.663 – 1.704 · n 1.687 – 1.704
Birefringence
0.005
Pleochroism
Non-pleochroic
Extinction
May have biaxial sectors
UV response
Not fluorescent in UV
Notes

Virtually always anomalously biaxial + or - of tensional origin, with weak birefringence, possibly exhibiting six biaxial sectors based on the faces of (001). Measured 2V = large.

Isotropy testPPL ↔ XPL diagnostic
PPL intrinsic colour; no change on stage rotation
XPL extinct at every orientation
Single index
n = 1.696

Crystallography

Crystal system
Isometric
Space group
P-4 3m
Cell parameters
a = 7.96(2) Å
Z
1
Morphology

Cubic crystals, striated diagonally or replaced by a vicinal trapezohedron near {1.1.40}; and exhibiting minor (111), (111), (011), and (122); also tetrahedral. Granular, earthy.

Twinning

Lamellar, rarely as twinned tetrahedra.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen2215.999351.978
41.15%
33AsArsenicArsenic374.922224.766
26.28%
26FeIronIron455.845223.380
26.12%
19KPotassiumPotassium139.09839.098
4.57%
1HHydrogenHydrogen161.00816.128
1.88%
Total855.350100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • P

Synonyms

  • Arsenate-zeolite
  • Arsenicated Iron Ore
  • Arseniksaures Eisen im Würfeln kryst.
  • Cube Ore
  • Fer arseniaté
  • Hexaedrischer Liroconmalachit
  • Pharmacosiderit
  • Pharmakosidrit
  • Pharmakosidrite
  • Siderite (of Bergmann)
  • Würfelerz

In other languages

French
Pharmacosidérite
German
Pharmakosiderit
Spanish
farmacosiderita
Italian
farmacosiderite
Chinese
毒鐵石 · 毒铁石
Russian
фармакосидерит

Classification

Strunz
10th ed.

8.DK.10

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DKWith large and medium-sized cations, (OH, etc.):RO4 > 1:1 and < 2:1Group
  • 8.DK.10PharmacosideriteSpecies
Dana
8th ed.

42.08.1a.01

  • 42Hydrated Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 42.08(AB)5(XO4)3Zq·xH2OType
  • 42.08.1a— unnamed intermediate level —Group
  • 42.08.1a.01PharmacosideriteSpecies
CIM

20.9.9

  • 20Arsenates (also arsenates with phosphate, but without other anions)Class
  • 20.9Arsenates of FeGroup
  • 20.9.9PharmacosideriteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1786Klaproth (1786) Schriften der Gesellschaft naturforschender Freunde in Berlin, Schr.: 1: 161 (as Arseniksaures Eisen im Würfeln kryst.).
  2. 1794Lenz, D.G. (1794) Versuch einer vollständigen Anleitung zur Kenntniss der Mineralien. 2 volumes, Leipzig: 2: 18, 151 (as Würfelerz).
  3. 1794Richard Kirwan (1794) Elements of Mineralogy - second edition Vol. 1. P. Elmsly, The Strand.
  4. 1802Klaproth, M. H. (1802) XCIV. Untersuchung des Olivenerzes.IlI. Arseniksaures Eisenerz. In Beiträge zur chemischen Kenntniss der Mineralkörper Vol. 3. Rottmann. p.194-195.
  5. 1808Karsten, D.L.G. (1808) Mineralogische Tabellen, Berlin. second edition: 66: 1808 (as Würfelerz).
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Pharmacosiderite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/pharmacosiderite-3185},
  note      = {Accessed 2026-05-11}
}