Barnesite

Na2V5+6O16 · 3H2O
IMA status
  • Approved
IMA symbol
Bar
Also known as
  • Barnesiet

Where it forms, where it's found

Geological setting

In small cavities and fractures and as interstitial filling in sandstone in the oxidized zone of a vanadiferous uranium deposit

Type locality
Cactus Rat Mine
  1. The Poison Strip
  2. Thompsons Mining District
  3. Grand County
  4. Utah
  5. USA

38.8511°, -109.4834°

16recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Brilliant dark red · brownish red on exposure
Tenacity
fragile
Cleavage
Perfect

on (001), fair on (100) and (010)

Density
3.09 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 60°
Refractive index
1.797 – 2.08
Surface relief
Very high
Principal indices
nα 1.797 – 1.8 · nβ 2.01 – 2.04 · nγ 2.04 – 2.08
Pleochroism
Strong

X = yellow, Y = yellow-orange, Z = red; Orientation: Y = a, Z = b, X vs. c = 5°

Dispersion
r << v
Michel-Lévy diagramhighlighted lineδ = 0.2615
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]2615 nm5th order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation2615 nm
Order5th order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
#13
Cell parameters
a = 12.17 Å · b = 3.602 Å · c = 7.78 Å
Cell angles
β = 95.03 °
Ratio a:b:c
1 : 0.296 : 0.639
Z
1
Morphology

Subparallel to radiating aggregates of bladed to fibrous crystals, elongated along [010], to 0.5 mm; also as botryoidal to velvety coatings.

Type-locality form

Dark red microscopic bladed to fibrous crystals either in loose aggregates or in radiating clusters. In continuous coatings, it is velvety with a botryoidal appearance.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
23VVanadiumVanadium650.942305.652
46.20%
8OOxygenOxygen1915.999303.981
45.94%
11NaSodiumSodium222.99045.980
6.95%
1HHydrogenHydrogen61.0086.048
0.91%
Total661.661100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Ca

Synonyms

  • Barnesiet

In other languages

German
Barnesit
Italian
Barnesite

Classification

Strunz
10th ed.

4.HG.45

  • 4OxidesClass
  • 4.HV[5,6] VanadatesDivision
  • 4.HGUnclassified V oxidesGroup
  • 4.HG.45BarnesiteSpecies
Dana
8th ed.

47.03.01.03

  • 47Vanadium OxysaltsClass
  • 47.03Hydrated Normal Vanadium OxysaltsType
  • 47.03.01Hewettite GroupGroup
  • 47.03.01.03BarnesiteSpecies
CIM

21.1.3

  • 21Vanadates (and vanadates with arsenate or phosphate)Class
  • 21.1Vanadates of the alkalis and CuGroup
  • 21.1.3BarnesiteSpecies

Group, growth & confusion

In the same group
4 members

Literature, links & citation

Citations
  1. 1963Weeks, Alice D., Ross, Daphne R., Marvin, Richard F. (1963) The occurrence and properties of barnesite, Na2V6O16·3H2O, a new hydrated sodium vanadate mineral from Utah. American Mineralogist, 48 (11-12) 1187-1195
  2. 1986Akinovich, E. A. and Podlipaeva, N. I. (1986): A Ca-variety of barnesite from rocks of a carbonaceous-siliceous vanadium-bearing formation in southern Kazakhstan. Zapiski Vsesoyuznogo Mineralogicheskogo Obshchestva: 115: 345-351.
  3. 1990Evans, Howard T., Jr.,, Hughes, John M. (1990) Crystal chemistry of the natural vanadium bronzes. American Mineralogist, 75 (5-6) 508-521
  4. 1997Anthony, J. W. et al. (1997): Handbook of Mineralogy, Vol. 3, 43
  5. 2005(2005) Barnesite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Barnesite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/barnesite-533},
  note      = {Accessed 2026-05-11}
}