Benitoite

BaTiSi3O9
IMA status
  • Approved
  • Grandfathered
IMA symbol
Bni
Discovered
1907
Also known as
  • Benitoide

Where it forms, where it's found

Type locality
California State Gem Mine
  1. Santa Rita Peak
  2. San Benito County
  3. California
  4. USA

36.3361°, -120.6053°

22recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789106 – 6.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Sapphire blue · white to colorless · pink
Cleavage
Poor/Indistinct

Poor on (1011)

Fracture
Conchoidal
Density
3.65 g/cm³

Optical

Optical type
Uniaxial (+)
Refractive index
1.756 – 1.804
Surface relief
High
Principal indices
nω 1.756 – 1.757 · nε 1.802 – 1.804
Pleochroism
Visible

O= colorless E= purple, indigo, greenish blue

UV response
Invariably fluorescent blue in SW UV. Blue shortwave-excited luminescence excited by SW UV caused by titanate groups (TiO<sub>6</sub>)
Michel-Lévy diagramhighlighted lineδ = 0.0465
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]465 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation465 nm
Order1st order
XPL colour

Crystallography

Crystal system
Hexagonal
Space group
#109
Cell parameters
a = 6.641 Å · c = 9.7597(10) Å
Z
2
Morphology

Flat pyramidal crystals.

Twinning

By rotation around [0001]

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen915.999143.991
34.83%
56BaBariumBarium1137.327137.327
33.21%
14SiSiliconSilicon328.08584.255
20.38%
22TiTitaniumTitanium147.86747.867
11.58%
Total413.440100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Na

Synonyms

  • Benitoide

In other languages

French
bénitoïte
German
Benitoit
Spanish
Benitoíta
Italian
benitoite
Portuguese
benitoíte
Japanese
ベニトアイト · ベニト石
Chinese
藍錐礦
Traditional Chinese
藍錐礦
Russian
Бенитоит
Arabic
بينيتويت

Classification

Strunz
10th ed.

9.CA.05

  • 9SilicatesClass
  • 9.CCyclosilicatesDivision
  • 9.CA[Si3O9]6- 3-membered single rings (dreier-Einfachringe), without insular complex anionsGroup
  • 9.CA.05BenitoiteSpecies
Dana
8th ed.

59.01.01.02

  • 59Cyclosilicates Three-membered RingsClass
  • 59.01Three-Membered Rings, anhydrous, no other anionsType
  • 59.01.01Benitoite groupGroup
  • 59.01.01.02BenitoiteSpecies
CIM

14.9.9

  • 14Silicates not Containing AluminumClass
  • 14.9Silicates of TiGroup
  • 14.9.9BenitoiteSpecies

Group, growth & confusion

In the same group
4 members

Literature, links & citation

Citations
  1. 1907Louderback, G.D. and W.C. Blasdale (1907) Benitoite, a new California gem mineral, with chemical analysis by Walter C. Blasdale, University of California, Department of Geological Science Bull.: 5: 149-153.
  2. 1908Kraus, E.H. (1908) Interpretation of the chemical composition of the mineral benitoite. Science, new series: 7: 710-711.
  3. 1908Louderback, G.D. & W.C. Blasdale (1908) Benitoite, its mineralogy, paragenesis, and geological occurrence (abstract). Science, new series: 27: 411.
  4. 1908Arnold, R. (1908) Notes on the Occurrence of the Recently Described Gem Mineral, Benitoite. Science, New Series: 27(686): 312-314.
  5. 1908Blasdale, W. C. (1908) The Chemical Formula of the Mineral Benitoite. Science, 28 (712). doi:10.1126/science.28.712.233-aDOI: 10.1126/science.28.712.233-a
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Benitoite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/benitoite-624},
  note      = {Accessed 2026-05-11}
}