Benjaminite

Ag3Bi7S12
IMA status
  • Approved
  • Grandfathered
IMA symbol
Bnj
Discovered
1924
Also known as
  • Benjaminiet

Where it forms, where it's found

Geological setting

In a quartz vein near the contact of a soda-granite and an intrusive rhyolite.

Hydrothermal veins

Type locality
Keeley-Frontier Mine
  1. South Lorrain Township
  2. Cobalt-Gowganda region
  3. Timiskaming District
  4. Ontario
  5. Canada

47.1992°, -79.5056°

53recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Metallic
Transparency
Opaque
Colour
Grey · tarnishes dull or yellow to copper-red
Streak
Dull lead-gray
Cleavage
Imperfect/Fair

Fair in one direction.

Density
6.34 g/cm³

Optical

Pleochroism
Non-pleochroic
Optical colour
Creamy white to very pale brownish
Anisotropism
Strong
Tropism
Anisotropic
Reflectance R%
(44.2, 47.2) 400, (44.8, 47.8) 420, (45.2, 48.6) 440, (45.2, 49.0) 460, (45.0, 49.2) 480, (44.8, 49.2) 500, (44.5, 49.0) 520, (44.0, 48.6) 540, (43.6, 48.0) 560, (43.3, 47.6) 580, (43.1, 47.2) 600, (43.0, 46.8) 620, (42.8, 46.3) 640, (42.7, 45.9) 660, (42.6, 45.6) 680, (42.5, 45.2) 700
Reflected-light panel
43.8 %anisotropic · dual curve
Specimen sRGB 232, 164, 93
White reference100 % reflector under same lamp
R₁ R₂
Mode
Anisotropism
Strong
Reflected colour
Creamy white to very pale brownish

Crystallography

Crystal system
Monoclinic
Space group
C2/m
Cell parameters
a = 13.25(2) Å · b = 4.05(1) Å · c = 20.25(3) Å
Cell angles
β = 103.14(7) °
Ratio a:b:c
1 : 0.306 : 1.528
Z
2
Morphology

Massive and laths.

Twinning

Commonly polysynthetic.

Type-locality form

Large and small bunches and blotches in quartz. Irregular masses up to 5 cm.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
83BiBismuthBismuth7208.9801462.860
67.38%
16SSulfurSulfur1232.060384.720
17.72%
47AgSilverSilver3107.868323.604
14.90%
Total2171.184100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Benjaminiet

In other languages

French
Benjaminite
German
Benjaminit · IMA 1975-003a
Italian
Benjaminite
Chinese
本硫铋银矿

Classification

Strunz
10th ed.

2.JA.05e

  • 2Sulfides and SulfosaltsClass
  • 2.JSulfosalts of PbS archetypeDivision
  • 2.JAGalena derivatives with little or no PbGroup
  • 2.JA.05eBenjaminiteSpecies
Dana
8th ed.

03.08.10.03

  • 03SulfosaltsClass
  • 03.081 < ø < 2Type
  • 03.08.10Pavonite Group (Monoclinic: C/2c bismuth sulfosalts)Group
  • 03.08.10.03BenjaminiteSpecies
CIM

5.7.39

  • 5Sulphosalts - Sulpharsenites and Sulphobismuthites (those containing Sn, Ge,or V are in Section 6)Class
  • 5.7Sulpharsenites etc. of Pb and other metalsGroup
  • 5.7.39BenjaminiteSpecies

Group, growth & confusion

Often grow together
2 minerals

Literature, links & citation

Citations
  1. 1925Shannon, E.V. (1925): Benjaminite, a new sulfosalt mineral of the klaprothite group. Proceedings of the U.S. National Museum, 65(24), 1-9.
  2. 1953Nuffield, E. W. (1953) Benjaminite. American Mineralogist, 38 (5-6) 550-552
  3. 1969Ramdohr, Paul (1969) The Ore Minerals and their Intergrowths. Pergamon Press, Oxford. 1174pp. doi:10.1016/c2013-0-10027-xDOI: 10.1016/c2013-0-10027-x
  4. 1975Harris, D. C., Chen, T. T. (1975) Benjaminite, reinstated as valid species. The Canadian Mineralogist, 13 (4) 402-407
  5. 1975Nuffield, E. W. (1975) Benjaminite - a re-examination of the type material. The Canadian Mineralogist, 13 (4) 394-401
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Benjaminite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/benjaminite-625},
  note      = {Accessed 2026-05-11}
}