Betpakdalite-NaNa

[Na2(H2O)16Na(H2O)6][Mo6+8As5+2Fe3+3O33(OH)4]
IMA status
  • Approved
IMA symbol
Bpd-NaNa
Discovered
1940
IMA approved
2011
Also known as
  • IMA2011-078

Where it forms, where it's found

Geological setting

Upper oxidation zone of the Chiquicamata Mine, Chile, a porphyry copper deposit

Type locality
Chuquicamata Mine
  1. Chuquicamata District
  2. Calama
  3. El Loa Province
  4. Antofagasta
  5. Chile

-22.2894°, -68.9011°

1recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789103/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Yellow
Streak
Colorless to very pale yellow
Tenacity
brittle
Cleavage
Perfect

(001)

Fracture
Splintery
Density
2.87 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 60°
Refractive index
1.765 – 1.85
Surface relief
Very high
Principal indices
nα 1.765 · nβ 1.785 · nγ 1.850
Pleochroism
Non-pleochroic
Dispersion
r > v moderate
UV response
None
Michel-Lévy diagramhighlighted lineδ = 0.0850
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]850 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation850 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C2/m
Cell parameters
a = 19.2370(12) Å · b = 11.0945(7) Å · c = 15.1459(9) Å
Cell angles
β = 130.342(1) °
Ratio a:b:c
1 : 0.577 : 0.787
Unit cell volume
2463.8 ų
Morphology

Striated prismatic to bladed crystals, flattened on (001) and elongated prallel to [010] (Up to 0.4mm in length and 0.1 mm in diameter). Forms observed: (001), (110),{10-1} and {20-1}.

Twinning

Multipel, complex penetrations twins.

Type-locality form

Matrix: brecciated vein quartz intermixed with, cemented by or coated by jarosite and oxyhydroxides.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen5915.999943.941
43.98%
42MoMolybdenumMolybdenum895.950767.600
35.76%
26FeIronIron355.845167.535
7.81%
33AsArsenicArsenic274.922149.844
6.98%
11NaSodiumSodium322.99068.970
3.21%
1HHydrogenHydrogen481.00848.384
2.26%
Total2146.274100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2011-078

In other languages

German
Betpakdalit-NaNa · IMA 2011-078
Italian
betpakdalite-NaNa

Classification

Strunz
10th ed.

8.BM

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.BPhosphates, etc., with additional anions, without H2ODivision
  • 8.BMWith medium-sized and large cations, (OH, etc.):RO4 = 4:1Group
  • 8.BMBetpakdalite-NaNaSpecies

Group, growth & confusion

Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 2011Williams, P. A., Hatert, F., Pasero, M., Mills, S. J. (2011) New minerals and nomenclature modifications approved in 2011. CNMNC Newsletter No 11. Mineralogical Magazine, 75 (6) 2887-2893 doi:10.1180/minmag.2011.075.6.2887 DOI: 10.1180/minmag.2011.075.6.2887
  2. 2012Kampf, A. R., Mills, S. J., Rumsey, M. S., Dini, M., Birch, W. D., Spratt, J., Pluth, J. J., Steele, I. M., Jenkins, R. A., Pinch, W. W. (2012) The heteropolymolybdate family: structural relations, nomenclature scheme and new species. Mineralogical Magazine, 76 (5) 1175-1207 doi:10.1180/minmag.2012.076.5.09DOI: 10.1180/minmag.2012.076.5.09
  3. 2021(2021) Betpakdalite-NaNa. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Betpakdalite-NaNa — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/betpakdalite-nana-41945},
  note      = {Accessed 2026-05-11}
}