Bieberite

Co(SO4) · 7H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Bie
Discovered
1845
Also known as

Where it forms, where it's found

Type locality
"Im Lochborn" Copper mine
  1. Bieber
  2. Biebergemünd
  3. Main-Kinzig-Kreis
  4. Darmstadt
  5. Hesse
  6. Germany

50.1408°, 9.3619°

47recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous
Transparency
Translucent · Opaque
Colour
Red-pink · flesh-red · colourless to pale rose in transmitted light.
Cleavage
Perfect

On (001) perfect; on (110) fair.

Density
1.96 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 88° · 2V calc = 88°
Refractive index
1.477 – 1.489
Surface relief
Low
Principal indices
nα 1.477 · nβ 1.483 · nγ 1.489
Dispersion
none
Michel-Lévy diagramhighlighted lineδ = 0.0120
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]120 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation120 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
#13
Cell parameters
a = 14.04 Å · b = 6.49 Å · c = 10.92 Å
Cell angles
β = 105.27 °
Ratio a:b:c
1 : 0.462 : 0.778
Morphology

As crusts and stalactites.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1115.999175.989
62.61%
27CoCobaltCobalt158.93358.933
20.97%
16SSulfurSulfur132.06032.060
11.40%
1HHydrogenHydrogen141.00814.112
5.02%
Total281.094100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Biberit
  • Biberita
  • Biberite
  • Bieberiet
  • Biebrit
  • Biebrita
  • Biebrite
  • Cobalt Vitriol
  • Cobalt-melanterite
  • Kobaltvitriol
  • Red Vitriol
  • Rhodhalit
  • Rhodhalita
  • Rhodhalite
  • Rhodhalose
  • Sulphate of Cobalt

In other languages

French
biebérite
German
Bieberit · Kobaltvitriol · Rhodhalose · Roter Vitriol · Schwefelsaurer Kobalt
Spanish
Bieberita
Italian
Bieberite
Japanese
赤礬

Classification

Strunz
10th ed.

7.CB.35

  • 7SulfatesClass
  • 7.CSulfates (selenates, etc.) without additional anions, with H2ODivision
  • 7.CBWith only medium-sized cationsGroup
  • 7.CB.35BieberiteSpecies
Dana
8th ed.

29.06.10.04

  • 29Hydrated Acid and Normal SulfatesClass
  • 29.06AXO4·xH2OType
  • 29.06.10Melanterite Group (Heptahydrates, Monoclinic: P21/c)Group
  • 29.06.10.04BieberiteSpecies
CIM

25.12.1

  • 25SulphatesClass
  • 25.12Sulphates of Co and NiGroup
  • 25.12.1BieberiteSpecies

Group, growth & confusion

In the same group
5 members

Literature, links & citation

Citations
  1. 1791Sage (1791) Le Journal de physique et le radium, Paris: 39: 53 (as Cobalt Vitriol).
  2. 1797Klaproth, M. H. (1797) Untersuchung des natürlichen Kobaltvitriols von Herrengrund. In Beiträge zur chemischen Kenntniss der Mineralkörper Vol. 2. Rottmann, Berlin. p.320
  3. 1808Kopp (1808) Allgemeines Journal der Chemie, Berlin 1798-1803 (Scherer’s Journal): 6: 157 (as Kobaltvitriol).
  4. 1832Beudant, François-Sulpice (1832) Traité élémentaire de minéralogie. Deuxiéme Edition [Elementary Treatise on Mineralogy. Second Edition] (2nd ed.) Vol. 2 - Tome II [Volume II]. Chez Verdière.
  5. 1845Haidinger, W. (1845) Erste Klasse: Akrogenide. IV. Ordnung. Salze. VII. Vitriolsalz. Bieberit. in Handbuch der Bestimmenden Mineralogie, Bei Braumüller and Seidel (Wien): 487-492.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Bieberite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/bieberite-664},
  note      = {Accessed 2026-05-11}
}