Melanterite

Fe(SO4) · 7H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Mln
Also known as
  • Alcaparossa Verde
  • Atramentum
  • Atramentum sutorium viride
  • +15 more

Where it forms, where it's found

Geological setting

A secondary mineral formed by the oxidation of iron sulfide minerals, such as pyrite and marcasite, it is found occurring naturally in sheltered crevices and cavities in sulfidic sedimentary and metamorphic rocks, and in coal and lignite deposits. It also forms readily on the walls, timbers, and other structures in mines.

848recorded occurrences
Source · OpenStreetMap

Varieties

Physical

Hardness
123456789102/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent · Opaque
Colour
Colorless to white or green · also greenish-blue to blue with increased Cu content · colourless to pale green in transmitted light.

Usually a yellowish-white after exposure to air and moisture.

Streak
White.
Tenacity
brittle
Cleavage
Perfect

Perfect on (001), distinct on (110).

Fracture
Conchoidal
Density
1.89 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 86° · 2V calc = 80°
Refractive index
1.47 – 1.486
Surface relief
Low
Principal indices
nα 1.47 – 1.471 · nβ 1.4765 – 1.4795 · nγ 1.486
Dispersion
none
Michel-Lévy diagramhighlighted lineδ = 0.0155
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]155 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation155 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P21/c
Cell parameters
a = 14.077 Å · b = 6.509 Å · c = 11.054 Å
Cell angles
β = 105.6 °
Ratio a:b:c
1 : 0.462 : 0.785
Z
4
Morphology

Crystals rare, equant to short prismatic parallel to [001] with prominent (110) and (001); thick tabular (010) or (101), also pseudo-octahedral due to equal development of (110), (001), and (101); more typically found as beard-like efflorescences, or as capillary to fibrous aggregates; it may also be stalactic or concretionary.

Twinning

None reported.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1115.999175.989
63.30%
26FeIronIron155.84555.845
20.09%
16SSulfurSulfur132.06032.060
11.53%
1HHydrogenHydrogen141.00814.112
5.08%
Total278.006100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Cu
  • Mg

Synonyms

  • Alcaparossa Verde
  • Atramentum
  • Atramentum sutorium viride
  • Atramentum viride
  • Copperas
  • Copperasin
  • Eisenvitriol
  • Fer sulfaté
  • Green Vitriol
  • Iron Vitriol
  • Kupferwasser
  • Melanteria
  • Mélantérie
  • Melantherite
  • Sulphate of Iron
  • Vitriolum
  • Vitriolum viride
  • Vitrolo verde

In other languages

French
7782-63-0 · Chalcite · Chalcitris · Couperose verte · Cuprojarosite · Cuprokirovite · Fer sulfaté · FeSO4,7H2O · Luckite · Luckyite · Mélantérie · Mélantérite · Mélantérite cuprifère · Pisanite · Sommairite · Vitriol vert · Yarroshite
German
Melanterit · Pisanit
Spanish
Melanterita
Italian
Melanterite · Vetriolo di ferro
Japanese
緑礬
Chinese
水绿矾
Arabic
الزاج القبرصي · زاج قبرصي · كبريتات الحديدوز · ميلانتريت

Classification

Strunz
10th ed.

7.CB.35

  • 7SulfatesClass
  • 7.CSulfates (selenates, etc.) without additional anions, with H2ODivision
  • 7.CBWith only medium-sized cationsGroup
  • 7.CB.35MelanteriteSpecies
Dana
8th ed.

29.06.10.01

  • 29Hydrated Acid and Normal SulfatesClass
  • 29.06AXO4·xH2OType
  • 29.06.10Melanterite Group (Heptahydrates, Monoclinic: P21/c)Group
  • 29.06.10.01MelanteriteSpecies
CIM

25.10.5

  • 25SulphatesClass
  • 25.10Sulphates of Fe aloneGroup
  • 25.10.5MelanteriteSpecies

Group, growth & confusion

In the same group
5 members
Often grow together
6 minerals
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1167–1174.
  2. 1832Beudant, François-Sulpice (1832) Traité élémentaire de minéralogie. Deuxiéme Edition [Elementary Treatise on Mineralogy. Second Edition] (2nd ed.) Vol. 2 - Tome II [Volume II]. Chez Verdière.
  3. 1843Chapman, E.J. (1843) Practical Mineralogy. London, Paris, and Leipzig: 14 (as Melantherite).
  4. 1850Haidinger, Wm. (1850) Handbuch der bestimmenden Mineralogie. Vienna, 2nd. Edition: 489 (as Melanterit).
  5. 1867Erofejeff (1867) Konigliche Akademie der Wissenschaften, Vienna, Sitzber.: 56: 63.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Melanterite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/melanterite-2633},
  note      = {Accessed 2026-05-11}
}