Where it forms, where it's found
- Geological setting
Oxidation of pyrite in a mine fire with reactions to fire fighting techniques (water, steam, CO2).
Oxidation of pyritic ore; may be formed under pseudo-fumarolic conditions from mine fires.
- Type locality
- United Verde Mine
- Jerome
- Verde Mining District
- Black Hills (Black Hill Range)
- Yavapai County
- Arizona
- USA
34.7500°, -112.1222°
Physical
Optical
- Optical type
- Biaxial (+/-)
- Refractive index
- 1.593 – 1.741
- Surface relief
- High
- Principal indices
- nα 1.593 – 1.604 · nβ 1.665 – 1.674 · nγ 1.731 – 1.741
- Birefringence
- moderately high
- Pleochroism
- Visible
X = Colourless; Y = Faint yellow; Z = Light yellow.
- Dispersion
- r < v weak
- Extinction
- Z = b; X ∧ c = –18°.
- Notes
2V large.
Crystallography
- Space group
- P21/m
- Cell parameters
- a = 6.51 Å · b = 7.37 Å · c = 5.85 Å
- Cell angles
- β = 108.87 °
- Ratio a:b:c
- 1 : 1.132 : 0.899
- Z
- 2
- Morphology
Crystals commonly tabular (001) or (100) with a propensity for elongation [010]; also octahedral (anthropogenic).
- Twinning
Very common on (05).
- Epitaxy
Oriented growths.
- Type-locality form
Coatings on rock and as cement, binding them together. Where the coatings are thin, individual crystals to 1 mm.
Chemical composition
Synonyms
- Butleriet
In other languages
- German
- Butlerit
- Italian
- Butlerite
- Chinese
- 基铁矾
Classification
7.DC.10
- 7SulfatesClass
- 7.DSulfates (selenates, etc.) with additional anions, with H2ODivision
- 7.DCWith only medium-sized cations; chains of edge-sharing octahedraGroup
- 7.DC.10ButleriteSpecies
31.09.01.01
- 31Hydrated Sulfates Containing Hydroxyl or HalogenClass
- 31.09(AB)(XO4)Zq·xH2OType
- 31.09.01— unnamed intermediate level —Group
- 31.09.01.01ButleriteSpecies
25.10.15
- 25SulphatesClass
- 25.10Sulphates of Fe aloneGroup
- 25.10.15ButleriteSpecies
Group, growth & confusion
Literature, links & citation
- 1922Posnjak, E.; Merwin, H. E. (1922) The system, Fe2O3—SO3—H2O. Journal Of The American Chemical Society, 44 (9). 1965-1994 doi:10.1021/ja01430a016DOI: 10.1021/ja01430a016
- 1938Bandy, Mark C. (1938) Mineralogy of three sulphate deposits of northern Chile. American Mineralogist, 23 (11) 669-760
- 1941Gordon (1941) Academy of Sciences, Philadelphia, Not. Nat., no. 89.
- 1942Fleischer, M. (1942) New mineral names. American Mineralogist, 27 (2). 144
- 1951Palache, Charles; Berman, Harry; Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. John Wiley and Sons.
@misc{mineral2026,
author = {Mineral Index editorial board},
title = {Butlerite — Mineral Index},
year = {2026},
url = {https://mineralindex.org/minerals/butlerite-810},
note = {Accessed 2026-05-11}
}
