Butlerite

Fe3+(SO4)(OH) · 2H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Btl
Discovered
1928
Also known as
  • Butleriet

Where it forms, where it's found

Geological setting

Oxidation of pyrite in a mine fire with reactions to fire fighting techniques (water, steam, CO2).

Oxidation of pyritic ore; may be formed under pseudo-fumarolic conditions from mine fires.

Type locality
United Verde Mine
  1. Jerome
  2. Verde Mining District
  3. Black Hills (Black Hill Range)
  4. Yavapai County
  5. Arizona
  6. USA

34.7500°, -112.1222°

39recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Dark orange · light yellow-orange in transmitted light.
Streak
Pale yellow
Cleavage
Perfect

On (100), perfect. another cleavage direction (pinacoidal) is imperfect.

Density
2.548 g/cm³

Optical

Optical type
Biaxial (+/-)
Refractive index
1.593 – 1.741
Surface relief
High
Principal indices
nα 1.593 – 1.604 · nβ 1.665 – 1.674 · nγ 1.731 – 1.741
Birefringence
moderately high
Pleochroism
Visible

X = Colourless; Y = Faint yellow; Z = Light yellow.

Dispersion
r < v weak
Extinction
Z = b; X ∧ c = –18°.
Notes

2V large.

Michel-Lévy diagramhighlighted lineδ = 0.1375
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]1375 nm3rd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation1375 nm
Order3rd order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P21/m
Cell parameters
a = 6.51 Å · b = 7.37 Å · c = 5.85 Å
Cell angles
β = 108.87 °
Ratio a:b:c
1 : 1.132 : 0.899
Z
2
Morphology

Crystals commonly tabular (001) or (100) with a propensity for elongation [010]; also octahedral (anthropogenic).

Twinning

Very common on (105).

Epitaxy

Oriented growths.

Type-locality form

Coatings on rock and as cement, binding them together. Where the coatings are thin, individual crystals to 1 mm.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen715.999111.993
54.65%
26FeIronIron155.84555.845
27.25%
16SSulfurSulfur132.06032.060
15.64%
1HHydrogenHydrogen51.0085.040
2.46%
Total204.938100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Butleriet

In other languages

German
Butlerit
Italian
Butlerite
Chinese
基铁矾

Classification

Strunz
10th ed.

7.DC.10

  • 7SulfatesClass
  • 7.DSulfates (selenates, etc.) with additional anions, with H2ODivision
  • 7.DCWith only medium-sized cations; chains of edge-sharing octahedraGroup
  • 7.DC.10ButleriteSpecies
Dana
8th ed.

31.09.01.01

  • 31Hydrated Sulfates Containing Hydroxyl or HalogenClass
  • 31.09(AB)(XO4)Zq·xH2OType
  • 31.09.01— unnamed intermediate level —Group
  • 31.09.01.01ButleriteSpecies
CIM

25.10.15

  • 25SulphatesClass
  • 25.10Sulphates of Fe aloneGroup
  • 25.10.15ButleriteSpecies

Group, growth & confusion

Often grow together
1 mineral
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1922Posnjak, E.; Merwin, H. E. (1922) The system, Fe2O3—SO3—H2O. Journal Of The American Chemical Society, 44 (9). 1965-1994 doi:10.1021/ja01430a016DOI: 10.1021/ja01430a016
  2. 1938Bandy, Mark C. (1938) Mineralogy of three sulphate deposits of northern Chile. American Mineralogist, 23 (11) 669-760
  3. 1941Gordon (1941) Academy of Sciences, Philadelphia, Not. Nat., no. 89.
  4. 1942Fleischer, M. (1942) New mineral names. American Mineralogist, 27 (2). 144
  5. 1951Palache, Charles; Berman, Harry; Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. John Wiley and Sons.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Butlerite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/butlerite-810},
  note      = {Accessed 2026-05-11}
}