Parabutlerite

Fe3+(SO4)(OH) · 2H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Pbtl
Discovered
1938
Also known as
  • Parabutleriet

Where it forms, where it's found

Type locality
Alcaparrosa Mine
  1. Sierra Gorda
  2. Antofagasta Province
  3. Antofagasta
  4. Chile

-22.6329°, -69.1855°

21recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Colour
Pale orange to pale orange-brown · light yellow in transmitted light.
Tenacity
brittle
Cleavage
Poor/Indistinct

On (110), poor.

Fracture
Conchoidal
Density
2.55 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 87° · 2V calc = 90°
Refractive index
1.598 – 1.737
Surface relief
High
Principal indices
nα 1.598 · nβ 1.663 · nγ 1.737
Pleochroism
Visible

Alcaparrosa material: X = b = Light yellow Y = c = Greenish yellow Z = a = Brownish yellow Argentinian material: X = b = Colourless Y = c = Faint yellow Z = a = Light yellow

Dispersion
r < v weak
Notes

NOTE: 2V value for Argentinian material = 43°30'.

Michel-Lévy diagramhighlighted lineδ = 0.1390
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]1390 nm3rd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation1390 nm
Order3rd order
XPL colour

Crystallography

Crystal system
Orthorhombic
Cell parameters
a = 20.0789(8) Å · b = 7.4024(7) Å · c = 7.2294(15) Å
Ratio a:b:c
1 : 0.369 : 0.360
Morphology

Crystals prismatic [001]. The prism zone is striated [001].

Twinning

On (142), rare.

Epitaxy

Intergrowths, with (011) of parabutlerite nearly parallel to (001) and (100) of butlerite.

Comment

Space group Pnma(0β0)​s0s; the structure is commensurately modulated, with a = 20.0789 (8), b = 7.4024 (7), c = 7.2294 (15) Å and q = 0.4b* (Plášil et al., 2017).

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen715.999111.993
54.65%
26FeIronIron155.84555.845
27.25%
16SSulfurSulfur132.06032.060
15.64%
1HHydrogenHydrogen51.0085.040
2.46%
Total204.938100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Parabutleriet

In other languages

German
Parabutlerit
Spanish
Parabutlerita
Italian
Parabutlerite
Chinese
副基铁矾

Classification

Strunz
10th ed.

7.DC.10

  • 7SulfatesClass
  • 7.DSulfates (selenates, etc.) with additional anions, with H2ODivision
  • 7.DCWith only medium-sized cations; chains of edge-sharing octahedraGroup
  • 7.DC.10ParabutleriteSpecies
Dana
8th ed.

31.09.02.01

  • 31Hydrated Sulfates Containing Hydroxyl or HalogenClass
  • 31.09(AB)(XO4)Zq·xH2OType
  • 31.09.02— unnamed intermediate level —Group
  • 31.09.02.01ParabutleriteSpecies
CIM

25.10.16

  • 25SulphatesClass
  • 25.10Sulphates of Fe aloneGroup
  • 25.10.16ParabutleriteSpecies

Group, growth & confusion

Often grow together
1 mineral
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1938Bandy, Mark C. (1938) Mineralogy of three sulphate deposits of northern Chile. American Mineralogist, 23 (11) 669-760
  2. 1941Gordon (1941) Academy of Sciences of Philadelphia, Not. Nat., no. 89.
  3. 1951Palache, Charles; Berman, Harry; Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. John Wiley and Sons.
  4. 1964Cesbron, Fabien (1964) Contribution à la Minéralogie des sulfates de fer hydratés. Bulletin de Minéralogie, 87 (2) 125-143 doi:10.3406/bulmi.1964.5721DOI: 10.3406/bulmi.1964.5721
  5. 1970Borène, Jacques (1970) Structure cristalline de la parabutlérite. Bulletin de Minéralogie, 93 (2) 185-189 doi:10.3406/bulmi.1970.6452DOI: 10.3406/bulmi.1970.6452
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Parabutlerite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/parabutlerite-3081},
  note      = {Accessed 2026-05-11}
}