Calciohilairite

CaZrSi3O9 · 3H2O
IMA status
  • Approved
IMA symbol
Chlr
Discovered
1988
Also known as
  • Calciohilairiet
  • IMA1984-023

Where it forms, where it's found

Geological setting

Miarolitic cavities in peralkaline granite.

Type locality
Washington Pass
  1. Golden Horn Batholith
  2. Okanogan County
  3. Washington
  4. USA

48.5242°, -120.6531°

11recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
White to pale blue
Cleavage
None Observed
Fracture
Conchoidal
Density
2.68 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
1.619 – 1.622
Surface relief
Moderate
Principal indices
nω 1.622 · nε 1.619
UV response
Not fluorescent
Michel-Lévy diagramhighlighted lineδ = 0.0030
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]30 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation30 nm
Order1st order
XPL colour

Crystallography

Crystal system
Trigonal
Space group
#93
Cell parameters
a = 20.870(4) Å · c = 16.002(4) Å
Z
24
Morphology

Two trigonal prisms {11-20}, {2-1-10} and two rhombohedrons {10-12} and {00-12}.

Twinning

None observed

Type-locality form

White to pale blue unaltered and altered crystals, to 2 mm.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1215.999191.988
46.42%
40ZrZirconiumZirconium191.22491.224
22.06%
14SiSiliconSilicon328.08584.255
20.37%
20CaCalciumCalcium140.07840.078
9.69%
1HHydrogenHydrogen61.0086.048
1.46%
Total413.593100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Na
  • Cu
  • Al
  • Fe
  • Ti

Synonyms

  • Calciohilairiet
  • IMA1984-023

In other languages

German
Calciohilairit · IMA 1984-023
Italian
Calciohilairite

Classification

Strunz
10th ed.

9.DM.10

  • 9SilicatesClass
  • 9.DInosilicatesDivision
  • 9.DMInosilicates with 6-periodic single chainsGroup
  • 9.DM.10CalciohilairiteSpecies
Dana
8th ed.

59.02.03.02

  • 59Cyclosilicates Three-membered RingsClass
  • 59.02Three-Membered Rings, hydratedType
  • 59.02.03Hilairite groupGroup
  • 59.02.03.02CalciohilairiteSpecies
CIM

14.10.21

  • 14Silicates not Containing AluminumClass
  • 14.10Silicates of Zr or HfGroup
  • 14.10.21CalciohilairiteSpecies

Group, growth & confusion

In the same group
4 members

Literature, links & citation

Citations
  1. 1988Boggs, Russell C. (1988) Calciohilairite: CaZrSi3O9·3H2O, the calcium analogue of hilairite from the Golden Horn batholith, northern Cascades, Washington. American Mineralogist, 73 (9-10) 1191-1194
  2. 1995Salvi, Stefano, Williams-Jones, Anthony E. (1995) Zirconosilicate phase relations in the Strange Lake (Lac Brisson) Pluton, Quebec-Labrador, Canada. American Mineralogist, 80 (9) 1031-1040 doi:10.2138/am-1995-9-1019 DOI: 10.2138/am-1995-9-1019
  3. 2001(2001) Calciohilairite. Handbook of Mineralogy. Mineralogical Society of America
  4. 2002Pushcharovskii, D.Yu., Pekov, I.V., Pazero, M. Gobechiya, E.R., Merlino, S., Zubkova, N.V. (2002) Crystal structure of cation-deficient calciohilairite and probable decationing mechanisms in minerals with mixed frameworks. Kristallographia: 47(5): 814-818. (in Russian)
  5. 2003Pekov, Igor V., Chukanov, Nikita V., Kononkova, Natalia N., Pushcharovsky, Dmitirii Yu. (2003) Rare-metal «zeolites» of the hilairite group. New Data on Minerals, 38. 20-33
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Calciohilairite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/calciohilairite-831},
  note      = {Accessed 2026-05-11}
}