Hilairite

Na2ZrSi3O9 · 3H2O
IMA status
  • Approved
IMA symbol
Hlr
Discovered
1965
Also known as
  • Hilairiet
  • Ilerite
  • IMA1972-019

Where it forms, where it's found

Type locality
Poudrette quarry (De-Mix quarry
  1. Demix quarry
  2. Uni-Mix quarry
  3. Carrière Mont Saint-Hilaire
  4. MSH)
  5. Mont Saint-Hilaire
  6. La Vallée-du-Richelieu RCM
  7. Montérégie
  8. Québec
  9. Canada

45.5628°, -73.1417°

20recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent · Opaque
Colour
Pale to dark brown · white · yellow · colorless · flesh-pink · rose-red
Tenacity
brittle
Cleavage
None Observed
Fracture
Conchoidal
Density
2.724 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
1.596 – 1.609
Surface relief
Moderate
Principal indices
nω 1.609 · nε 1.596
Michel-Lévy diagramhighlighted lineδ = 0.0130
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]130 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation130 nm
Order1st order
XPL colour

Crystallography

Crystal system
Trigonal
Space group
#93
Cell parameters
a = 10.556(1) Å · c = 15.855(2) Å
Z
6
Morphology

Prism {11-20} and rhombohedron {01-12}. Typically elongated along the prism.

Twinning

Multiple twinning by rotation about [2-201] and about [0001], common; typically multiply twinned after both laws, involving four, eight, or more individuals.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1215.999191.988
45.77%
40ZrZirconiumZirconium191.22491.224
21.75%
14SiSiliconSilicon328.08584.255
20.08%
11NaSodiumSodium222.99045.980
10.96%
1HHydrogenHydrogen61.0086.048
1.44%
Total419.495100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Ti
  • Al
  • Fe
  • Mn
  • Mg
  • Ca
  • K

Synonyms

  • Hilairiet
  • Ilerite
  • IMA1972-019

In other languages

German
Hilairit · IMA 1972-019
Italian
Hilairite

Classification

Strunz
10th ed.

9.DM.10

  • 9SilicatesClass
  • 9.DInosilicatesDivision
  • 9.DMInosilicates with 6-periodic single chainsGroup
  • 9.DM.10HilairiteSpecies
Dana
8th ed.

59.02.03.01

  • 59Cyclosilicates Three-membered RingsClass
  • 59.02Three-Membered Rings, hydratedType
  • 59.02.03Hilairite groupGroup
  • 59.02.03.01HilairiteSpecies
CIM

14.10.10

  • 14Silicates not Containing AluminumClass
  • 14.10Silicates of Zr or HfGroup
  • 14.10.10HilairiteSpecies

Group, growth & confusion

In the same group
4 members

Literature, links & citation

Citations
  1. 1974Chao, George Y., Watkinson, David H., Chen, T. T. (1974) Hilairite, Na2ZrSi3O9•3H2O, a new mineral from Mont St. Hilaire, Quebec. The Canadian Mineralogist, 12 (4) 237-240
  2. 1981Ilyushin, G.D., Voronkov, A.A., Nevskii, N.N., Ilyukin, V.V., Belov, N.V. (1981) Crystal structure of hilairite, Na2ZrSi3O9•3H2O. Soviet Physics Doklady: 26: 916-917.
  3. 2001(2001) Hilairite. Handbook of Mineralogy. Mineralogical Society of America
  4. 2003Pekov, Igor V., Chukanov, Nikita V., Kononkova, Natalia N., Pushcharovsky, Dmitirii Yu. (2003) Rare-metal «zeolites» of the hilairite group. New Data on Minerals, 38. 20-33
  5. 2007Zubkova, N. V., Pekov, I. V., Turchkova, A. G., Pushcharovskiĭ, D. Yu., Merlino, S., Pasero, M., Chukanov, N. V. (2007) Crystal structures of potassium-exchanged forms of catapleiite and hilairite. Crystallography Reports, 52 (1) 65-70 doi:10.1134/s1063774507010075DOI: 10.1134/s1063774507010075
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Hilairite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/hilairite-1901},
  note      = {Accessed 2026-05-11}
}