Chalcophanite

ZnMn4+3O7 · 3H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Cph
Discovered
1875
Also known as
  • Chalcophane
  • Chalcophaniet
  • Chalcophanit
  • +1 more

Where it forms, where it's found

Geological setting

Oxidation zone of a franklinite and zincite deposit.

Type locality
Passaic pit (Marshall Mine
  1. Passaic Mine)
  2. Sterling Hill
  3. Ogdensburg
  4. Sussex County
  5. New Jersey
  6. USA

41.0825°, -74.6061°

202recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Metallic
Transparency
Transparent · Opaque
Colour
Iron-black · bluish black · dark red (in thin plates)

Deep red-brown to opaque in transmitted light.

Streak
Dark brown, red-brown
Tenacity
brittle
Cleavage
Perfect

On (0001)

Fracture
Irregular/Uneven
Density
3.907 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
2.72
Surface relief
Very high
Principal indices
nω 2.72 · nε 2.72
Pleochroism
Strong

O = nearly opaque E = deep red

Optical colour
White
Anisotropism
Extremely high
Bireflectance
Well defined; in gray and white.
Internal reflections
Deep red
Tropism
Anisotropic
Reflectance R%
(11.4,38.0) 400, (11.0,36.6) 420, (10.6,35.2) 440, (10.3,33.8) 460, (10.0,32.2) 480, (9.8,30.7) 500, (9.8,29.2) 520, (9.7,28.0) 540, (9.5,26.9) 560, (9.3,26.2) 580, (9.3,25.8) 600, (9.2,25.4) 620, (9.2,24.8) 640, (9.0,24.4) 660, (8.9,24.0) 680, (8.9,23.8) 700
UV response
Not fluorescent in UV,
Reflected-light panel
9.7 %anisotropic · dual curve
Specimen sRGB 115, 80, 44
White reference100 % reflector under same lamp
R₁ R₂
Mode
Bireflectance
Well defined; in gray and white.
Anisotropism
Extremely high
Reflected colour
White
Internal reflections
Deep red

Crystallography

Crystal system
Trigonal
Space group
R-3
Cell parameters
a = 7.541 Å · c = 20.824 Å
Z
6
Morphology

Minute crystals tabular (0001), or with (0001) and (1011) equally developed, exhibiting a pseudo-octahedral habit. Commonly in drusy, botryoidal or stalactitic crusts with the tabular crystals arranged on edge. Massive; dense, granular, or platy, fibrous.

Type-locality form

Druses of crystals and foliated aggregates lining cavities. Also stalactitic and plumose forms.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
25MnManganeseManganese354.938164.814
41.59%
8OOxygenOxygen1015.999159.990
40.38%
30ZnZincZinc165.38065.380
16.50%
1HHydrogenHydrogen61.0086.048
1.53%
Total396.232100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Chalcophane
  • Chalcophaniet
  • Chalcophanit
  • Hydrofranklinite

In other languages

German
Chalkophanit
Spanish
Calcofanita
Italian
calcofanite · chalcophanite
Russian
халькофанит

Classification

Strunz
10th ed.

4.FL.20

  • 4OxidesClass
  • 4.FHydroxides (without V or U)Division
  • 4.FLHydroxides with H2O +- (OH); sheets of edge-sharing octahedraGroup
  • 4.FL.20ChalcophaniteSpecies
Dana
8th ed.

07.08.02.01

  • 07Multiple OxidesClass
  • 07.08AB3X7Type
  • 07.08.02Chalcophanite GroupGroup
  • 07.08.02.01ChalcophaniteSpecies
CIM

7.5.8

  • 7Oxides and HydroxidesClass
  • 7.5Oxides of Zn, Cd and HgGroup
  • 7.5.8ChalcophaniteSpecies

Group, growth & confusion

In the same group
3 members
Often grow together
2 minerals
Commonly confused with
3 minerals

Literature, links & citation

Citations
  1. 1875Moore G E (1875) On chalcophanite, a new mineral species. The American Chemist 6, 1-2
  2. 1894Penfield, S.L., Kreider, D.A. (1894) Mineralogical notes; On the Identity of Hydrofranklinite and Ghalcophanite. American Journal of Science: 48: 141-143.
  3. 1914Ford, W.E. (1914) Mineralogical notes; Occurrence of Chalcophanite at Leadville, Colorado. American Journal of Science: 38: 502-502.
  4. 1931Orcel, Jean, Pavlovitch, Stoyan (1931) Les caractères microscopiques des oxydes de manganèse et des manganites naturels (Détermination de leurs pouvoirs réflecteurs) Bulletin de Minéralogie, 54 (5) 108-179 doi:10.3406/bulmi.1931.4130 DOI: 10.3406/bulmi.1931.4130
  5. 1938Ramdohr, P. (1938): Zbl. Min.: 134.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Chalcophanite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/chalcophanite-947},
  note      = {Accessed 2026-05-11}
}