Chlorophoenicite

(Mn,Mg,Zn)3Zn2(AsO4)(OH,O)6
IMA status
  • Approved
  • Grandfathered
IMA symbol
Cpo
Discovered
1924
Also known as
  • Chlorophoeniciet
  • Chlorophoenicita
  • Chlorophönizit

Where it forms, where it's found

Geological setting

Secondary veinlets in massive ore in a metamorphosed Pre-Cambrian sedimentary Zn-Fe-Mn deposit.

Type locality
Buckwheat pit
  1. Franklin Mine
  2. Franklin
  3. Sussex County
  4. New Jersey
  5. USA

41.1147°, -74.5872°

3recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789103 – 3.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Usually colorless to white · also light gray-green (natural light) · pink to light purplish red (strong artificial light)

White material common at the Sterling Mine and Franklin.

Streak
Colorless
Tenacity
brittle
Cleavage
Distinct/Good

On (100), good.

Fracture
Splintery
Density
3.46 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 81 – 85° · 2V calc = 84°
Refractive index
1.682 – 1.697
Surface relief
High
Principal indices
nα 1.682 · nβ 1.690 · nγ 1.697
Birefringence
0.015
Dispersion
r > v, relatively strong
UV response
Not fluorescent in UV.
Michel-Lévy diagramhighlighted lineδ = 0.0150
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]150 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation150 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C2/m
Cell parameters
a = 22.973 Å · b = 3.287 Å · c = 7.310 Å
Cell angles
β = 106.18 °
Ratio a:b:c
1 : 0.143 : 0.318
Z
2
Morphology

Usually acicular. Crystals may be long prismatic [010] and deeply striated [010], with etched and dull terminal faces. Face (100) is relatively smooth while {h0l} faces are uneven or warped.

Type-locality form

Usually in acicular, white crystals. Sometimes in somewhat rod-like crystals with an acute rhombic cross-section and definite pyramidal terminations. Rarely may be pale grayish green when crystals are rod-like.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
30ZnZincZinc565.380326.900
36.26%
8OOxygenOxygen1615.999255.984
28.39%
25MnManganeseManganese354.938164.814
18.28%
33AsArsenicArsenic174.92274.922
8.31%
12MgMagnesiumMagnesium324.30572.915
8.09%
1HHydrogenHydrogen61.0086.048
0.67%
Total901.583100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Chlorophoeniciet
  • Chlorophoenicita
  • Chlorophönizit

In other languages

German
Chlorophoenicit
Italian
Clorofenicite · clorophoenicite

Classification

Strunz
10th ed.

8.BE.35

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.BPhosphates, etc., with additional anions, without H2ODivision
  • 8.BEWith only medium-sized cations, (OH, etc.):RO4 > 2:1Group
  • 8.BE.35ChlorophoeniciteSpecies
Dana
8th ed.

41.01.01.01

  • 41Anhydrous Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 41.01(AB)m(XO4)pZq, where m:p > 4:1Type
  • 41.01.01Phoenicite GroupGroup
  • 41.01.01.01ChlorophoeniciteSpecies
CIM

20.3.17

  • 20Arsenates (also arsenates with phosphate, but without other anions)Class
  • 20.3Arsenates of Zn, Cd or HgGroup
  • 20.3.17ChlorophoeniciteSpecies

Group, growth & confusion

In the same group
3 members
Often grow together
3 minerals
Commonly confused with
2 minerals

Literature, links & citation

Citations
  1. 1924Foshag, W. F., Gage, R. B. (1924) Chlorophoenicite, a new mineral from Franklin Furnace, New Jersey (preliminary description) Journal of the Washington Academy of Sciences, 14 (15) 362-363
  2. 1925Foshag, W.F. (1925) New minerals: new species. American Mineralogist, 10, 39-41.
  3. 1927Foshag, W.F. (1927) New Mineral Names. American Mineralogist, 12 (10). 379-380
  4. 1927Foshag, William F., Berman, Harry, Gage, Robert B. (1927) The occurrence and properties of chlorophoenicite, a new arsenate from Franklin, New Jersey. Proceedings of the United States National Museum, 70 (2669). 1-6 doi:10.5479/si.00963801.70-2669.1DOI: 10.5479/si.00963801.70-2669.1
  5. 1935Palache, Charles (1935) The minerals of Franklin and Sterling Hill, Sussex County, New Jersey. Professional Paper 180. US Geological Survey 135 pp. doi:10.3133/pp180 DOI: 10.3133/pp180
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Chlorophoenicite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/chlorophoenicite-946},
  note      = {Accessed 2026-05-11}
}