Cotunnite

PbCl2
IMA status
  • Approved
  • Grandfathered
IMA symbol
Cot
Discovered
1825
Also known as
  • Chlorblei
  • Cottunite
  • Cotunnia
  • +1 more

Where it forms, where it's found

Geological setting

Alteration product of galena under arid, saline conditions.

Type locality
Mount Vesuvius
  1. Metropolitan City of Naples
  2. Campania
  3. Italy
83recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789101.5 – 2/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Colourless · white · light yellow · light green
Tenacity
sectile
Cleavage
Perfect

On (010).

Fracture
Sub-Conchoidal
Density
5.8 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 67° · 2V calc = 68°
Refractive index
2.199 – 2.26
Surface relief
Very high
Principal indices
nα 2.199 · nβ 2.217 · nγ 2.26
Dispersion
relatively strong
Michel-Lévy diagramhighlighted lineδ = 0.0610
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]610 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation610 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Orthorhombic
Cell parameters
a = 7.6222(5) Å · b = 9.0448(7) Å · c = 4.5348(4) Å
Ratio a:b:c
1 : 1.187 : 0.595
Z
4
Morphology

Usually flattened (010) and elongated [001]. Doubly terminated with equivalent faces unequally developed. Reentrant angles may be present in the prism zone due to oscillatory combination of (210) and (110). Massive, granular.

Twinning

On (120) (artificial crystals).

Comment

Space group Pnam (non-standard setting)

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
82PbLeadLead1207.200207.200
74.51%
17ClChlorineChlorine235.45070.900
25.49%
Total278.100100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Chlorblei
  • Cottunite
  • Cotunnia
  • Lead chloride

In other languages

German
Cotunnit
Spanish
Cotunnita
Italian
Cotunnite
Japanese
コチュン石
Chinese
氯铅矿
Arabic
Lead chloride · Lead(II) chloride · PbCl2 · ثنائي كلوريد الرصاص · ثنائي كلوريد رصاص · كلوريد الرصاص · كلوريد الرصاص الثنائي · كلوريد رصاص ثنائي

Classification

Strunz
10th ed.

3.AB.85

  • 3HalidesClass
  • 3.ASimple halides, without H2ODivision
  • 3.ABM:X = 1:2Group
  • 3.AB.85CotunniteSpecies
Dana
8th ed.

09.02.07.01

  • 09Normal HalidesClass
  • 09.02AX2Type
  • 09.02.07Cotunnite GroupGroup
  • 09.02.07.01CotunniteSpecies
CIM

8.8.4

  • 8Halides - Fluorides, Chlorides, Bromides and Iodides; also Fluoborates and FluosilicatesClass
  • 8.8Halides of PbGroup
  • 8.8.4CotunniteSpecies

Group, growth & confusion

Often grow together
3 minerals

Literature, links & citation

Citations
  1. 1825Monticelli, T., Covelli, N. (1825) Cotunnia (Piombo muriato). Prodromo della Mineralogia Vesuviana, Napoli: 1: 47-52.
  2. 1830Von Kobell, F. (1830) Charakteristik der Mineralien. Part 1 (1830); part 2 (1831), Nürnberg: 2: 179.
  3. 1895Stöber (1895) Académie royale des sciences de Belgique, Brussels, Bull.: 30(3): 345.
  4. 1910Lacroix, A. (1910) Minéralogie de la France et de ses colonies Vol. 4. Library Polytechnique, Paris.
  5. 1912Hintze, Carl (1912) Handbuch der Mineralogie. Berlin and Leipzig. 6 volumes: 1 [2B]: 2350.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Cotunnite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/cotunnite-1141},
  note      = {Accessed 2026-05-11}
}