Crookesite

Cu7TlSe4
IMA status
  • Approved
  • Grandfathered
IMA symbol
Crk
Discovered
1866
Also known as
  • Crookesiet

Where it forms, where it's found

Geological setting

Hydrothermal deposits

Type locality
Skrikerum Mine
  1. Valdemarsvik
  2. Östergötland County
  3. Sweden

58.1605°, 16.4199°

17recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789102.5 – 3/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Metallic
Transparency
Opaque
Colour
Lead Grey
Tenacity
brittle
Cleavage
Distinct/Good

Two at right angles

Density
6.90 g/cm³

Optical

Anisotropism
Weak but distinct in brownish tones
Tropism
Anisotropic
Reflectance R%
(33.6,35.9) 400, (33.3,35.8) 420, (32.7,35.8) 440, (32.4,35.7) 460, (32.5,35.6) 480, (32.8,35.3) 500, (33.1,35.1) 520, (33.1,34.8) 540, (33.0,34.7) 560, (32.7,34.6) 580, (32.6,34.7) 600, (32.4,35.0) 620, (32.2,35.2) 640, (31.9,35.2) 660, (31.6,35.3) 680, (31.2,35.3) 700
Reflected-light panel
32.6 %anisotropic · dual curve
Specimen sRGB 205, 144, 79
White reference100 % reflector under same lamp
R₁ R₂
Mode
Anisotropism
Weak but distinct in brownish tones

Crystallography

Crystal system
Tetragonal
Cell parameters
a = 10.435 Å · c = 3.954 Å
Z
2
Morphology

Disseminated specks and in veinlets.

Type-locality form

As finely divided, disseminated specks.

Comment

Point Group: 4/m, 4, or _4 ; Space Group: I4/m, I4, or I_4.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
29CuCopperCopper763.546444.822
46.09%
34SeSeleniumSelenium478.971315.884
32.73%
81TlThalliumThallium1204.380204.380
21.18%
Total965.086100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Fe

Synonyms

  • Crookesiet

In other languages

French
crookesite
German
Crookesit
Spanish
Crookesita
Italian
Crookesite
Japanese
クルックス鉱
Chinese
硒铊铜银矿 · 硒铊银铜矿
Simplified Chinese
硒铊铜银矿
Traditional Chinese
硒鉈銅銀礦

Classification

Strunz
10th ed.

2.BD.50

  • 2Sulfides and SulfosaltsClass
  • 2.BMetal Sulfides, M: S > 1: 1 (mainly 2: 1)Division
  • 2.BDWith Hg, TlGroup
  • 2.BD.50CrookesiteSpecies
Dana
8th ed.

02.04.12.01

  • 02SulfidesClass
  • 02.04AmBnXp, with (m+n):p = 2:1Type
  • 02.04.12— unnamed intermediate level —Group
  • 02.04.12.01CrookesiteSpecies
CIM

3.5.12

  • 3Sulphides, Selenides, Tellurides, Arsenides and Bismuthides (except the arsenides, antimonides and bismuthides of Cu, Ag and Au, which are included in Section 1)Class
  • 3.5Sulphides etc. of Hg and TlGroup
  • 3.5.12CrookesiteSpecies

Group, growth & confusion

Often grow together
4 minerals

Literature, links & citation

Citations
  1. 1867Nordenskiöld, A. E. (1867) Sur les minéraux sélénifères et thallifères de Skrikerum. Bulletin de la Société Chimique de Paris, S. 2 Vol. 7. 409-414
  2. 1944Palache, Charles, Berman, Harry, Frondel, Clifford (1944) The System of Mineralogy (7th ed.) Vol. 1 - Elements, Sulfides, Sulfosalts, Oxides. John Wiley and Sons, New York.
  3. 1950Earley, J. W. (1950) Description and synthesis of the selenide minerals. American Mineralogist, 35 (5-6) 337-364
  4. 1969Ramdohr, Paul (1969) The Ore Minerals and their Intergrowths. Pergamon Press, Oxford. 1174pp. doi:10.1016/c2013-0-10027-xDOI: 10.1016/c2013-0-10027-x
  5. 1987Johan, Z. (1987) Crookesite, TlCu7Se4; new data and isotypism with NH4Cu7S4 (La crookesite, TlCu7Se4: nouvelles données et isotypie avec NH4Cu7S4.). Comptes Rendus de L’Académie des Sciences Paris: 304: 1121–1124 (in French).
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Crookesite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/crookesite-1159},
  note      = {Accessed 2026-05-11}
}