Klockmannite

Cu5.2Se6
IMA status
  • Approved
  • Grandfathered
IMA symbol
Kl
Discovered
1928

Where it forms, where it's found

Type locality
Las Asperezas mine
  1. Sierra de Cacho
  2. Villa Castelli
  3. General Lamadrid Department
  4. La Rioja Province
  5. Argentina

-28.9189°, -68.6839°

63recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789102 – 2.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Opaque
Colour
Gray-black to black. May tarnish to blue-black.

Metallic luster when freshly exposed. May become dull.

Streak
Gray to black
Cleavage
Perfect

(0001)

Density
5.99 g/cm³

Optical

Anisotropism
Strong; brownish gray to gray-white
Tropism
Anisotropic
Reflectance R%
(16.2,38.9) 400, (16.6,40.2) 420, (16.9,40.8) 440, (17.0,40.6) 460, (17.0,40.2) 480, (17.0,39.6) 500, (16.8,38.9) 520, (16.4,38.0) 540, (15.8,37.0) 560, (15.0,36.0) 580, (14.3,34.7) 600, (13.9,33.6) 620, (13.9,32.5) 640, (14.5,31.5) 660, (15.8,30.5) 680, (17.7,29.9) 700
UV response
Not fluorescent in UV
Reflected-light panel
15.9 %anisotropic · dual curve
Specimen sRGB 140, 103, 58
White reference100 % reflector under same lamp
R₁ R₂
Mode
Anisotropism
Strong; brownish gray to gray-white

Crystallography

Crystal system
Hexagonal
Space group
P63/mmc
Cell parameters
a = 3.94 Å · c = 17.25 Å
Z
6
Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
34SeSeleniumSelenium678.971473.826
58.91%
29CuCopperCopper5.263.546330.439
41.09%
Total804.265100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Ag

In other languages

French
Klockmannite
German
Klockmannit
Spanish
Klockmannita
Italian
Klockmannite

Classification

Strunz
10th ed.

2.CA.05b

  • 2Sulfides and SulfosaltsClass
  • 2.CMetal Sulfides, M: S = 1: 1 (and similar)Division
  • 2.CAWith CuGroup
  • 2.CA.05bKlockmanniteSpecies
Dana
8th ed.

02.08.12.02

  • 02SulfidesClass
  • 02.08AmXp, with m:p = 1:1Type
  • 02.08.12Covellite GroupGroup
  • 02.08.12.02KlockmanniteSpecies
CIM

3.1.14

  • 3Sulphides, Selenides, Tellurides, Arsenides and Bismuthides (except the arsenides, antimonides and bismuthides of Cu, Ag and Au, which are included in Section 1)Class
  • 3.1Sulphides etc. of CuGroup
  • 3.1.14KlockmanniteSpecies

Group, growth & confusion

Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1928Ramdohr, P. (1928) Klockmannit, ein neues natürliches Kupferselenid. Centralblatt für Mineralogie, Geologie und Paläontologie: 1928: 225-232.
  2. 1929Foshag, W.F. (1929) New mineral names. American Mineralogist, 14, 41-42.
  3. 1931Schneiderhöhn, Hans, Ramdohr, Paul (1931) Lehrbuch der Erzmikroskopie Vol. 2. Borntraeger.
  4. 1944Palache, Charles, Berman, Harry, Frondel, Clifford (1944) The System of Mineralogy (7th ed.) Vol. 1 - Elements, Sulfides, Sulfosalts, Oxides. John Wiley and Sons, New York.
  5. 1949Earle, J. W. (1949) Studies of natural and artificial selenides: I-Klockmannite, CuSe. American Mineralogist, 34 (5-6) 435-440
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Klockmannite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/klockmannite-2226},
  note      = {Accessed 2026-05-11}
}