Daubréeite

BiO(OH)
IMA status
  • Approved
  • Grandfathered
IMA symbol
Dau
Discovered
1876
Also known as
  • Daubréeiet
  • Daubreit
  • Daubreita
  • +2 more

Where it forms, where it's found

Geological setting

Oxidation zone of bismuth deposit.

Type locality
Constancia mine
  1. Cerro Tazna
  2. Cotagaita Municipality
  3. Nor Chichas Province
  4. Potosí
  5. Bolivia
12recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102 – 2.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Greasy · earthy
Transparency
Transparent
Colour
Creamy-white · greyish · yellowish-brown · colourless in transmitted light.
Tenacity
waxy
Cleavage
Perfect

On (001)

Very plastic

Density
6.4 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
1.91 – 2.15
Surface relief
Very high
Principal indices
nω 2.15 · nε 1.91
Michel-Lévy diagramhighlighted lineδ = 0.2400
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]2400 nm5th order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation2400 nm
Order5th order
XPL colour

Crystallography

Crystal system
Tetragonal
Space group
#185
Cell parameters
a = 3.85 Å · c = 7.4 Å
Z
2
Morphology

Massive only; compact, earthy, columnar to platy-fibrous.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
83BiBismuthBismuth1208.980208.980
86.36%
8OOxygenOxygen215.99931.998
13.22%
1HHydrogenHydrogen11.0081.008
0.42%
Total241.986100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Daubréeiet
  • Daubreit
  • Daubreita
  • Daubreite
  • Daubréite

In other languages

French
Daubréeite
German
Daubréeit
Italian
Daubréeite
Chinese
羟氯铋矿

Classification

Strunz
10th ed.

4.F0.25

  • 4OxidesClass
  • 4.FHydroxides (without V or U)Division
  • 4.F0— unnamed intermediate level —Group
  • 4.F0.25DaubréeiteSpecies
Dana
8th ed.

10.02.01.03

  • 10Oxyhalides and HydroxyhalidesClass
  • 10.02A(O,OH)XqType
  • 10.02.01Bismoclite GroupGroup
  • 10.02.01.03DaubréeiteSpecies
CIM

8.9.6

  • 8Halides - Fluorides, Chlorides, Bromides and Iodides; also Fluoborates and FluosilicatesClass
  • 8.9Halides of Sb and BiGroup
  • 8.9.6DaubréeiteSpecies

Group, growth & confusion

In the same group
6 members

Literature, links & citation

Citations
  1. 1876Domeyko, I. (1876) Daubréite (oxychlorure de bismuth), espèce minérale nouvelle. Comptes Rendus Hebdomadaires des Séances de l’Académie des Sciences, 82, 922-923.
  2. 1879Domeyko, I. (1879) Elementos de Mineralogia, 3rd. edition: 297.
  3. 1935Bannister, F. A. (1935) The crystal-structure of the bismuth oxyhalides. Mineralogical Magazine and Journal of the Mineralogical Society, 24 (149) 49-58 doi:10.1180/minmag.1935.024.149.01 DOI: 10.1180/minmag.1935.024.149.01
  4. 1951Palache, Charles; Berman, Harry; Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. John Wiley and Sons.
  5. 2005(2005) Daubréeite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Daubréeite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/daubreeite-1229},
  note      = {Accessed 2026-05-11}
}