Paralaurionite

PbCl(OH)
IMA status
  • Approved
  • Grandfathered
IMA symbol
Plri
Discovered
1899
Also known as
  • Laurionite-2M
  • Paralaurioniet
  • Rafaëlit (of Arzruni and Thaddéeff)
  • +2 more

Where it forms, where it's found

Geological setting

Lead slag

Lead-rich slags, also found in the oxide zone of some lead deposits in arid areas.

Type locality
Lavrion Slag Localities
  1. Lavreotiki
  2. East Attica
  3. Attica
  4. Greece
49recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789103/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Colourless · white · yellow · violet · green
Streak
White
Cleavage
Perfect

On (001).

Density
6.15 g/cm³

Optical

Optical type
Biaxial (-)
Refractive index
2.05 – 2.2
Surface relief
Very high
Principal indices
nα 2.05 · nβ 2.15 · nγ 2.2
Pleochroism
Visible

Violet-tinted crystals are pleochroic with absorption Y is greater than X, Z.

Dispersion
r < v strong
Notes

Plates on (100) exhibit abnormal interference figures due to twinning.

Michel-Lévy diagramhighlighted lineδ = 0.1500
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]1500 nm3rd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation1500 nm
Order3rd order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C2/m
Cell parameters
a = 10.865(4) Å · b = 4.006(2) Å · c = 7.233(3) Å
Cell angles
β = 117.24(4) °
Ratio a:b:c
1 : 0.369 : 0.666
Morphology

Crystals thin tabular (100) or lath-like by elongation [001]. The terminations of the plates or laths are rectangular or wedge-shaped as a result of development of pyramidal faces at the corners. Forms on type material: (100) large, (001) small, {10_1) minute, (201) small, (401) small, (601) small, (111) large, (110) large.

Twinning

Twin plane (100), very common, as symmetrical contact twins with composition face (100), simulating orthorhombic holohedry.

Type-locality form

Pseudo-rhombic tabular (to 10x15 mm) to prismatic (to 5 mm length). Similar to laurionite or fiedlerite.

Comment

OD structure. I-centred setting has a ~ 9.92 A, β ~ 103°.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
82PbLeadLead1207.200207.200
79.80%
17ClChlorineChlorine135.45035.450
13.65%
8OOxygenOxygen115.99915.999
6.16%
1HHydrogenHydrogen11.0081.008
0.39%
Total259.657100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Laurionite-2M
  • Paralaurioniet
  • Rafaëlit (of Arzruni and Thaddéeff)
  • Rafaelite (of Arzruni and Thaddéeff)
  • Rafaelite (of Arzruni)

In other languages

French
Paralaurionite · Rafaelite
German
Paralaurionit
Spanish
Paralaurionita
Italian
Paralaurionite

Classification

Strunz
10th ed.

3.DC.05

  • 3HalidesClass
  • 3.DOxyhalides, hydroxyhalides and related double halidesDivision
  • 3.DCWith Pb (As,Sb,Bi), without CuGroup
  • 3.DC.05ParalaurioniteSpecies
Dana
8th ed.

10.02.03.01

  • 10Oxyhalides and HydroxyhalidesClass
  • 10.02A(O,OH)XqType
  • 10.02.03— unnamed intermediate level —Group
  • 10.02.03.01ParalaurioniteSpecies
CIM

8.8.8

  • 8Halides - Fluorides, Chlorides, Bromides and Iodides; also Fluoborates and FluosilicatesClass
  • 8.8Halides of PbGroup
  • 8.8.8ParalaurioniteSpecies

Group, growth & confusion

In the same group
6 members
Often grow together
3 minerals
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1899Herbert Smith, G. F., Prior, G. T. (1899) On some lead minerals from Laurium, namely, Laurionite, Phosgenite, Fiedlerite, and (new species) Paralaurionite. Mineralogical Magazine and Journal of the Mineralogical Society, 12 (55) 102-110 doi:10.1180/minmag.1899.012.55.06 DOI: 10.1180/minmag.1899.012.55.06
  2. 1899Herbert Smith, G. F. (1899) Note on the Identity of Paralaurionite and Rafaelite. Mineralogical Magazine and Journal of the Mineralogical Society, 12 (56) 183 doi:10.1180/minmag.1899.012.56.08 DOI: 10.1180/minmag.1899.012.56.08
  3. 1899Arzruni, A.; Thaddéeff, K. (1899) Neue Minerale aus Chile, ein neues Vorkommen von Utahit und ein neues Wismuthcarbonat von Schneeberg. Zeitschrift für Kristallographie, Mineralogie und Petrographie, 31 (1-6). 229-247 doi:10.1524/zkri.1899.31.1.229 DOI: 10.1524/zkri.1899.31.1.229
  4. 1900Smith, G. F. Herbert (1900) Ueber die Identität von Rafaelit und Paralaurionit. Zeitschrift für Kristallographie, 32 (1-6). 217-219 doi:10.1524/zkri.1900.32.1.217DOI: 10.1524/zkri.1900.32.1.217
  5. 1910Ktenas, Const.-A. (1910) Sur les relations cristallographiques entre la laurionite et la paralaurionite. Bulletin de Minéralogie, 33 (3). 173-188 doi:10.3406/bulmi.1910.3422DOI: 10.3406/bulmi.1910.3422
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Paralaurionite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/paralaurionite-3096},
  note      = {Accessed 2026-05-11}
}