Davidlloydite

Zn3(AsO4)2 · 4H2O
IMA status
  • Approved
IMA symbol
Dld
IMA approved
2011
Also known as
  • Davidlloydiet
  • IMA2011-053

Where it forms, where it's found

Geological setting

Third oxidation zone, Tsumeb mine

Type locality
Tsumeb Mine (Ongopolo Mine)
  1. Tsumeb
  2. Oshikoto Region
  3. Namibia

-19.2270°, 17.7276°

1recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789103 – 4/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Colorless
Streak
White
Tenacity
brittle
Cleavage
Distinct/Good

(010)

Fracture
Irregular/Uneven · Hackly
Density
3.661 g/cm³

Optical

Optical type
Biaxial · 2V measured = 65.4° · 2V calc = 70°
Refractive index
1.671 – 1.695
Surface relief
High
Principal indices
nα 1.671 · nβ 1.687 · nγ 1.695
Pleochroism
Non-pleochroic
Dispersion
weak r < v
UV response
None
Michel-Lévy diagramhighlighted lineδ = 0.0240
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]240 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation240 nm
Order1st order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
#2
Cell parameters
a = 5.9756(4) Å · b = 7.6002(5) Å · c = 5.4471(4) Å
Cell angles
α = 84.2892(9) ° · β = 90.4920(9) ° · γ = 87.9958(9) °
Ratio a:b:c
1 : 1.272 : 0.912
Z
1
Morphology

Type material occurs as elongated prisms (~10:1 length-to-width ratio) that are flattened on (010).

Twinning

None observed.

Parting
none
Type-locality form

subparallel to slightly diverging elongated prisms lying partly on and partly embedded in fine-grained calcioandyrobertsite.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
30ZnZincZinc365.380196.140
35.92%
8OOxygenOxygen1215.999191.988
35.16%
33AsArsenicArsenic274.922149.844
27.44%
1HHydrogenHydrogen81.0088.064
1.48%
Total546.036100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Davidlloydiet
  • IMA2011-053

In other languages

German
Davidlloydit · IMA 2011-053
Italian
davidlloydite

Classification

Strunz
10th ed.

8.CA

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.CPhosphates without additional anions, with H2ODivision
  • 8.CAWith small and large/medium cationsGroup
  • 8.CADavidlloyditeSpecies

Group, growth & confusion

In the same group
5 members

Literature, links & citation

Citations
  1. 1974Nabar, Mahadeo Anant, Patkar, V. S. (1974) Unit cell of Zn3 (AsO4)2.4H2O. Bulletin de Minéralogie, 97 (6) 479-480 doi:10.3406/bulmi.1974.6936DOI: 10.3406/bulmi.1974.6936
  2. 2011Williams, P. A., Hatert, F., Pasero, M., Mills, S. J. (2011) New minerals and nomenclature modifications approved in 2011, CNMNC Newsletter No. 10. Mineralogical Magazine, 75 (5) 2549-2561 doi:10.1180/minmag.2011.075.5.2549 DOI: 10.1180/minmag.2011.075.5.2549
  3. 2012Hawthorne, Frank C., Cooper, Mark A., Abdu, Yassir A., Ball, Neil A., Back, Malcolm E., Tait, Kim T. (2012) Davidlloydite, ideally Zn3(AsO4)2(H2O)4, a new arsenate mineral from the Tsumeb mine, Otjikoto (Oshikoto) region, Namibia: description and crystal structure. Mineralogical Magazine, 76 (1) 45-57 doi:10.1180/minmag.2012.076.1.45 DOI: 10.1180/minmag.2012.076.1.45
  4. 2012Belakovskiy, D., Welch, M. D., Camara, F., Gatta, G. D., Tait, K. T. (2012) New Mineral Names. American Mineralogist, 97 (8) 1523-1530 doi:10.2138/am.2012.596DOI: 10.2138/am.2012.596
  5. 2022(2022) Davidlloydite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Davidlloydite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/davidlloydite-42229},
  note      = {Accessed 2026-05-11}
}