Parahopeite

Zn3(PO4)2 · 4H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Phop
Discovered
1907
Also known as
  • Parahopeiet

Where it forms, where it's found

Geological setting

A secondary mineral in the oxidized zone of a zinc-bearing hydrothermal mineral deposit.

Type locality
Kabwe Mine
  1. Kabwe
  2. Kabwe District
  3. Central Province
  4. Zambia

-14.4553°, 28.4336°

11recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Colourless · yellow-brown · golden brown

Colourless in transmitted light.

Streak
White
Cleavage
Perfect

On (010), perfect.

Density
3.31 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 90°
Refractive index
1.614 – 1.637
Surface relief
Moderate
Principal indices
nα 1.614 · nβ 1.625 · nγ 1.637
Dispersion
r > v, moderately strong
Extinction
X ≃ a; Y ∧ c = 30° on {100}.
Notes

2V nearly 90°.

Michel-Lévy diagramhighlighted lineδ = 0.0230
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]230 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation230 nm
Order1st order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
#2
Cell parameters
a = 5.76 Å · b = 7.54 Å · c = 5.27 Å
Cell angles
α = 93.44 ° · β = 91.2 ° · γ = 91.4 °
Ratio a:b:c
1 : 1.309 : 0.915
Morphology

Crystals elongated [001] and tabular (100); frequently grouped in sub-parallel aggregates or fan-like or tufted groups. Ledoux et al. (1917) report the following forms: Pinacoids - (100), (001), (010) Prisms - (310), (110) (120), (160), (110), (120), (160) Brachydomes - (021), (032), (011), (012), (011) Marcodomes - (203} Pyramids (111), (111), (111), (111), (423), (131), (231), (322), (112), (121), {5+12}, (143), (162), (271), (121), (131)

Twinning

On (100), polysynthetic, common.

Type-locality form

Crystals, resembling hemimorphite. Platy crystals thickly grouped together on tarbuttite. Thin, platy crystals are clustered in tufts on nodular, ochreous limonite.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
30ZnZincZinc365.380196.140
42.81%
8OOxygenOxygen1215.999191.988
41.91%
15PPhosphorusPhosphorus230.97461.948
13.52%
1HHydrogenHydrogen81.0088.064
1.76%
Total458.140100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Parahopeiet

In other languages

German
Parahopeit
Italian
Parahopeite

Classification

Strunz
10th ed.

8.CA.70

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.CPhosphates without additional anions, with H2ODivision
  • 8.CAWith small and large/medium cationsGroup
  • 8.CA.70ParahopeiteSpecies
Dana
8th ed.

40.03.03.01

  • 40Hydrated Normal Phosphates, Arsenates and VanadatesClass
  • 40.03A3(XO4)2·xH2OType
  • 40.03.03— unnamed intermediate level —Group
  • 40.03.03.01ParahopeiteSpecies
CIM

19.6.4

  • 19PhosphatesClass
  • 19.6Phosphates of ZnGroup
  • 19.6.4ParahopeiteSpecies

Group, growth & confusion

In the same group
5 members
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1908Spencer, L. J. (1908) On Hopeite and other zinc phosphates and associated minerals from the Broken Hill mines, North-Western Rhodesia. Mineralogical Magazine and Journal of the Mineralogical Society, 15 (68) 1-38 doi:10.1180/minmag.1908.015.68.02 DOI: 10.1180/minmag.1908.015.68.02
  2. 1917Ledoux, A., Walker, T.C., Wheatley, A.C. (1917) The crystallization of Parahopeite. Mineralogical Magazine: 18(84): 101-106.
  3. 1918Walker (1918) University of Toronto Studies, Geology Series, no. 10: 16.
  4. 1921Larsen, Esper S. (1921) The microscopic determination of the nonopaque minerals. Bulletin 679. US Geological Survey doi:10.3133/b679 DOI: 10.3133/b679
  5. 1940Wolfe, C. W. (1940) Classification of minerals of the type A3(XO4)2·nH2O (concluded) American Mineralogist, 25 (12) 787-809
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Parahopeite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/parahopeite-3092},
  note      = {Accessed 2026-05-11}
}