Hopeite

Zn3(PO4)2 · 4H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Hop
Discovered
1822
Also known as
  • Hibbenite
  • Prismatoidischer Zinkphyllit
  • Stilbite duovigésimale
  • +2 more

Where it forms, where it's found

Type locality
Altenberg mine
  1. Kelmis
  2. Liège
  3. Wallonia
  4. Belgium

50.7143°, 6.0091°

28recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous
Transparency
Transparent · Translucent
Colour
Yellow · white · colourless · grey or brown · colourless in transmitted light.
Streak
White
Tenacity
brittle
Cleavage
Perfect

On (010), perfect; on (100), good; on (001), poor.

Fracture
Irregular/Uneven
Density
3 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 36° · 2V calc = 26 – 82°
Refractive index
1.572 – 1.592
Surface relief
Moderate
Principal indices
nα 1.572 – 1.574 · nβ 1.582 – 1.591 · nγ 1.59 – 1.592
Dispersion
r < v, perceptible.
Michel-Lévy diagramhighlighted lineδ = 0.0180
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]180 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation180 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
#71
Cell parameters
a = 10.597(3) Å · b = 18.318(8) Å · c = 5.031(1) Å
Ratio a:b:c
1 : 1.729 : 0.475
Unit cell volume
976.6 ų
Z
4
Morphology

Crystals tabular (010) to prismatic [001] and occurring individually or as tufted or divergent aggregates and crusts. Face development is frequently irregular. The crystals may simulate disphenoidal or hemimorphic symmetry. Reniform masses; compact.

Twinning

None observed.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
30ZnZincZinc365.380196.140
42.81%
8OOxygenOxygen1215.999191.988
41.91%
15PPhosphorusPhosphorus230.97461.948
13.52%
1HHydrogenHydrogen81.0088.064
1.76%
Total458.140100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Hibbenite
  • Prismatoidischer Zinkphyllit
  • Stilbite duovigésimale
  • α-Hopeite
  • β-Hopeite

In other languages

French
Hopeite · Stilbite duovigésimale
German
Hopeit
Spanish
Hopeíta
Italian
Hopeite

Classification

Strunz
10th ed.

8.CA.30

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.CPhosphates without additional anions, with H2ODivision
  • 8.CAWith small and large/medium cationsGroup
  • 8.CA.30HopeiteSpecies
Dana
8th ed.

40.03.04.01

  • 40Hydrated Normal Phosphates, Arsenates and VanadatesClass
  • 40.03A3(XO4)2·xH2OType
  • 40.03.04Hopeite GroupGroup
  • 40.03.04.01HopeiteSpecies
CIM

19.6.3

  • 19PhosphatesClass
  • 19.6Phosphates of ZnGroup
  • 19.6.3HopeiteSpecies

Group, growth & confusion

In the same group
5 members
Often grow together
2 minerals
Commonly confused with
2 minerals

Literature, links & citation

Citations
  1. 1822Brewster, D. (1822): New mineral from Aachen, near Altenberg. Edinburgh Philosophical Journal: 6: 184.
  2. 1823Brewster, D. (1823): Art. XXII.-Proceedings of the Royal Society of Edinburgh. (Continued from Vol. VIII. p. 386). Edinburgh Philosophy Journal: 9: 186-186.
  3. 1826Brewster, David (1826) Description of Hopeite, a New Mineral, from Altenberg near Aix-la-Chapelle. Transactions of the Royal Society of Edinburgh, 10 (1). p.107-111. doi:10.1017/s0080456800024182DOI: 10.1017/s0080456800024182
  4. 1832Breithaupt, A. (1832): Vollständige Characteristik etc., 2nd. Edition: 38 (as Prismatoidischer Zinkphyllit).
  5. 1879Friedel, Charles; Sarasin, Édouard (1879) Sur la composition de la Hopéite. Bulletin de la Société française de Minéralogie, 2 (6). 153-156 doi:10.3406/bulmi.1879.1508DOI: 10.3406/bulmi.1879.1508
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Hopeite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/hopeite-1999},
  note      = {Accessed 2026-05-11}
}