Duttonite

V4+O(OH)2
IMA status
  • Approved
  • Grandfathered
IMA symbol
Dtn
Discovered
1956
Also known as
  • Duttoniet

Where it forms, where it's found

Geological setting

Vanadium-uranium deposits in sandstone.

Secondary mineral foemed by low temperature hydrothermal alteration of vanadium minerals.

Type locality
Peanut Mine
  1. Bull Canyon
  2. Montrose County
  3. Colorado
  4. USA

38.2120°, -108.7661°

9recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Pale brown

Becomes greenish on alteration.

Cleavage
Perfect

Good to perfect on (001)

Density
3.24 g/cm³

Optical

Optical type
Biaxial (+)
Refractive index
1.81 – 2.01
Surface relief
Very high
Principal indices
nα 1.810 · nβ 1.900 · nγ 2.01
Pleochroism
Visible

X= pale pinkish brown Y= pale yellow-brown Z= pale brown

Dispersion
r < v moderate
Extinction
X = a; Y = c; Z = b.
Michel-Lévy diagramhighlighted lineδ = 0.2000
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]2000 nm4th order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation2000 nm
Order4th order
XPL colour

Crystallography

Crystal system
Monoclinic
Cell parameters
a = 8.80(2) Å · b = 3.95(1) Å · c = 5.96(2) Å
Cell angles
β = 90.67(5) °
Ratio a:b:c
1 : 0.449 : 0.677
Z
4
Morphology

Crusts and masses of six sided pseudo-orthorhombic crystals. Forms include (001), (100), and (110).

Type-locality form

Randomly oriented six-sided platy crystals, ranging in size from minute up to 0.5 mm.

Comment

Space Group: I2/c.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
23VVanadiumVanadium150.94250.942
50.46%
8OOxygenOxygen315.99947.997
47.54%
1HHydrogenHydrogen21.0082.016
2.00%
Total100.955100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Duttoniet

In other languages

German
Duttonit
Italian
Duttonite
Chinese
羟钒石

Classification

Strunz
10th ed.

4.HE.35

  • 4OxidesClass
  • 4.HV[5,6] VanadatesDivision
  • 4.HEPhyllovanadatesGroup
  • 4.HE.35DuttoniteSpecies
Dana
8th ed.

06.02.07.01

  • 06Hydroxides and Oxides Containing HydroxylClass
  • 06.02X(OH)2Type
  • 06.02.07— unnamed intermediate level —Group
  • 06.02.07.01DuttoniteSpecies
CIM

7.12.5

  • 7Oxides and HydroxidesClass
  • 7.12Oxides of V, Nb and TaGroup
  • 7.12.5DuttoniteSpecies

Group, growth & confusion

Often grow together
2 minerals

Literature, links & citation

Citations
  1. 1956Fleischer, M. (1956) New mineral names. American Mineralogist, 41 (11-12). 958-960
  2. 1956THOMPSON, M. E., ROACH, C. H., MEYROWITZ, R. (1956) Duttonite, New Vanadium Mineral from Peanut Mine, Montrose County, Colorado. Science, 123 (3205). 990 doi:10.1126/science.123.3205.990DOI: 10.1126/science.123.3205.990
  3. 1957Thompson, M. E., Roach, Carl H., Meyrowitz, Robert (1957) Duttonite, a new quadrivalent vanadium oxide from the Peanut Mine, Montrose County, Colorado. American Mineralogist, 42 (7-8) 455-460
  4. 1958Evans, H. T., Mrose, M. E. (1958) The crystal structures of three new vanadium oxide minerals. Acta Crystallographica, 11 (1) 56-58 doi:10.1107/s0365110x58000141DOI: 10.1107/s0365110x58000141
  5. 1970Schwarzmann, E. (1970) Notizen: Synthese von Duttonit VO(OH)2. Zeitschrift für Naturforschung B, 25. 1485-1486 doi:10.1515/znb-1970-1239DOI: 10.1515/znb-1970-1239
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Duttonite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/duttonite-1335},
  note      = {Accessed 2026-05-11}
}