Ferricopiapite

Fe3+0.67Fe3+4(SO4)6(OH)2 · 20H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Fcpi
Discovered
1938
Also known as
  • Challantite
  • Ferricopiapiet
  • Ferrocopiapita
  • +1 more

Where it forms, where it's found

Geological setting

Oxidation zone of pyrite deposits in arid environments.

Type locality
Atacama
  1. Chile
55recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5 – 3/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Colour
Yellow · yellow-orange
Cleavage
Perfect

Perfect on (010)

Density
2.14 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 69 – 80°
Refractive index
1.496 – 1.592
Surface relief
Moderate
Principal indices
nα 1.496 – 1.53 · nβ 1.531 – 1.55 · nγ 1.579 – 1.592
Pleochroism
Visible

Shades of yellow

Dispersion
relatively strong r > v
Michel-Lévy diagramhighlighted lineδ = 0.0725
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]725 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation725 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
#2
Cell parameters
a = 7.394(5) Å · b = 18.36(2) Å · c = 7.324(8) Å
Cell angles
α = 93.8(1) ° · β = 102.2(1) ° · γ = 98.9(1) °
Ratio a:b:c
1 : 2.483 : 0.991
Z
1
Morphology

Pseudo-orthorhombic plates; scaly, granular aggregates.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen4615.999735.954
59.76%
26FeIronIron4.6755.845260.796
21.18%
16SSulfurSulfur632.060192.360
15.62%
1HHydrogenHydrogen421.00842.336
3.44%
Total1231.446100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Challantite
  • Ferricopiapiet
  • Ferrocopiapita
  • Ferrocopiapite

In other languages

German
Ferricopiapit
Italian
Ferricopiapite

Classification

Strunz
10th ed.

7.DB.35

  • 7SulfatesClass
  • 7.DSulfates (selenates, etc.) with additional anions, with H2ODivision
  • 7.DBWith only medium-sized cations; insular octahedra and finite unitsGroup
  • 7.DB.35FerricopiapiteSpecies
Dana
8th ed.

31.10.05.04

  • 31Hydrated Sulfates Containing Hydroxyl or HalogenClass
  • 31.10MiscellaneousType
  • 31.10.05Copiapite GroupGroup
  • 31.10.05.04FerricopiapiteSpecies
CIM

25.10.12

  • 25SulphatesClass
  • 25.10Sulphates of Fe aloneGroup
  • 25.10.12FerricopiapiteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1938Berry, L.G. (1938) Composition and optics of copiapite. in Nineteenth Annual Meeting, Mineralogical Society of America, Waldorf-Astoria Hotel, New York City, December 28-30, 1938, Program, abstracts, and time schedule for presentation of papers. American Mineralogist: 23(12)pt2: 3-3.
  2. 1939(1939) American Mineralogist : 24: 182.
  3. 1947Berry, L.G. (1947) Composition and optics of copiapite. University of Toronto Studies: VI. Geological Series, 51, 21-34.
  4. 1951Palache, Charles; Berman, Harry; Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. John Wiley and Sons.
  5. 1973Fanfani, Luca, Nunzi, Antonio, Zanazzi, Pier Francesco, Zanzari, and Anna Rosa (1973) The copiapite problem: The crystal structure of a ferrian copiapite. American Mineralogist, 58 (3-4) 314-322
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Ferricopiapite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/ferricopiapite-1490},
  note      = {Accessed 2026-05-11}
}