Copiapite

Fe2+Fe3+4(SO4)6(OH)2 · 20H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Cpi
Discovered
1833
Also known as
  • Atramenstein
  • Basisches schwefelsaures Eisenoxyd
  • Elaeit
  • +29 more

Where it forms, where it's found

Geological setting

Areas of pyrite oxidation.

Type locality
Copiapó Province
  1. Atacama
  2. Chile
387recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5 – 3/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent · Opaque
Colour
Crystals: sulfur-yellow to orange · massive material: greenish-yellow to olive-green.
Streak
Not reported
Tenacity
fragile
Cleavage
Perfect

on (010), perfect; on (101), imperfect.

Fracture
Irregular/Uneven · Micaceous
Density
2.08 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 45 – 74° · 2V calc = 48 – 72°
Refractive index
1.506 – 1.6
Surface relief
Moderate
Principal indices
nα 1.506 – 1.54 · nβ 1.528 – 1.549 · nγ 1.575 – 1.6
Dispersion
none
Michel-Lévy diagramhighlighted lineδ = 0.0645
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]645 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation645 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
#2
Cell parameters
a = 7.337 Å · b = 18.76 Å · c = 7.379 Å
Cell angles
α = 91.47 ° · β = 102.18 ° · γ = 98.95 °
Ratio a:b:c
1 : 2.557 : 1.006
Z
1
Morphology

Crystals rare, tabular (010), sometimes highly modified. Commonly found as scaly aggregates or fine-granular encrustations.

Twinning

Contact twinning with twin axis [101] and composition plane (010), uncommon.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen4615.999735.954
58.88%
26FeIronIron555.845279.225
22.34%
16SSulfurSulfur632.060192.360
15.39%
1HHydrogenHydrogen421.00842.336
3.39%
Total1249.875100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Cu
  • Ca
  • Al

Synonyms

  • Atramenstein
  • Basisches schwefelsaures Eisenoxyd
  • Elaeit
  • Elaeita
  • Elaeite
  • Eläit
  • Eläita
  • Eläite
  • Ferrocopiapit
  • Flaveit
  • Flaveita
  • Flaveite
  • Gelb Atrament
  • Gelbeisenerz (of Breithaupt)
  • Gul Atrament Sten
  • Ihlëite
  • Janosit
  • Janosita
  • Janosite
  • Lapis atramentarius flavus
  • Misleyit
  • Misleyita
  • Misleyite
  • Niveit
  • Niveita
  • Niveite
  • Pseudo-copiapite
  • Pseudocopiapite
  • Violite
  • Xanthosiderit (of Glocker)
  • Yellow Copperas
  • Μισυ

In other languages

French
Copiapite
German
Basisches schwefelsaures Eisenoxyd · Copiapit
Spanish
Copiapita
Italian
copiapite

Classification

Strunz
10th ed.

7.DB.35

  • 7SulfatesClass
  • 7.DSulfates (selenates, etc.) with additional anions, with H2ODivision
  • 7.DBWith only medium-sized cations; insular octahedra and finite unitsGroup
  • 7.DB.35CopiapiteSpecies
Dana
8th ed.

31.10.05.01

  • 31Hydrated Sulfates Containing Hydroxyl or HalogenClass
  • 31.10MiscellaneousType
  • 31.10.05Copiapite GroupGroup
  • 31.10.05.01CopiapiteSpecies
CIM

25.10.22

  • 25SulphatesClass
  • 25.10Sulphates of Fe aloneGroup
  • 25.10.22CopiapiteSpecies

Group, growth & confusion

Often grow together
4 minerals

Literature, links & citation

Citations
  1. De natura fossilium - Lib. I-X
  2. Dioscorides (as Μισυ).
  3. 1546Agricola, Georgius (1546) Interpretatio Germanica vocum rei metallicae (as Gelb Atrament).
  4. 1747Wallerius, J.G (1747) Mineralogia, eller Mineralriket. Stockholm: 159 (as Misy, Gul Atrament, and Lapis atramentarius flavus).
  5. 1813Hausmann, Johann Friedrich Ludwig (1813) Handbuch der Mineralogie (1st ed.). Vandenhoeck und Ruprecht.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Copiapite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/copiapite-1124},
  note      = {Accessed 2026-05-11}
}