Ferrihollandite

Ba(Mn4+6Fe3+2)O16
IMA status
  • Approved
IMA symbol
Fhol
Also known as
  • Ferrihollandiet

Where it forms, where it's found

Geological setting

In quartz-veins traversing the manganese-ore deposit.

Type locality
Kajlidongri Mine
  1. Jhabua District
  2. Madhya Pradesh
  3. India

22.9457°, 74.4682°

8recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104 – 6/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Opaque
Colour
Greyish-black · black
Streak
Black

Crystallography

Crystal system
Monoclinic
Cell parameters
a = 10.0001(7) Å · b = 5.7465(4) Å · c = 9.8076(8) Å
Cell angles
β = 90.713(2) °
Ratio a:b:c
1 : 0.575 : 0.981
Unit cell volume
563.56 ų
Morphology

Prismatic and usually striated along [010], probably as a consequence of twinning on (101) or (101), owing to the pseudo-tetragonal symmetry.

Twinning

Twinning on (101) or (101).

Epitaxy

Rutile with c-axis parallel to the b-axis of ferrihollandite (Biagioni et al. 2014).

Type-locality form

Black crystals that look like a tetragonal prism and a flat tetragonal pyramid.

Comment

Space group P2/n. Pseudo-tetragonal. Data from Biagioni et al. (2014).

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
25MnManganeseManganese654.938329.628
39.50%
8OOxygenOxygen1615.999255.984
30.67%
56BaBariumBarium1137.327137.327
16.45%
26FeIronIron255.845111.690
13.38%
Total834.629100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Ferrihollandiet

In other languages

German
Ferrihollandit
Italian
ferrihollandite

Classification

Strunz
10th ed.

4.DK

  • 4OxidesClass
  • 4.DMetal: Oxygen = 1:2 and similarDivision
  • 4.DKWith large (+- medium-sized) cations; tunnel structuresGroup
  • 4.DKFerrihollanditeSpecies

Group, growth & confusion

Commonly confused with
5 minerals

Literature, links & citation

Citations
  1. 1906Fermor, L., Leigh (1906) Manganese in India. Transactions of the Mining and Geological Institute of India,, 1 (2) 69-133
  2. 1979Potter, Russell M., Rossman, George R (1979) The tetravalent manganese oxides: identification, hydration, and structural relationships by infrared spectroscopy. American Mineralogist, 64 (11-12) 1199-1218
  3. 2012Williams, P. A., Hatert, F., Pasero, M., Mills, S. J. (2012) New minerals and nomenclature modifications approved in 2012. CNMNC Newsletter No 13. Mineralogical Magazine, 76 (3) 807-817 doi:10.1180/minmag.2012.076.3.26 DOI: 10.1180/minmag.2012.076.3.26
  4. 2013Biagioni, Cristian, Capalbo, Carmen, Pasero, Marco (2013) Nomenclature tunings in the hollandite supergroup. European Journal of Mineralogy, 25 (1) 85-90 doi:10.1127/0935-1221/2013/0025-2255 DOI: 10.1127/0935-1221/2013/0025-2255
  5. 2014Biagioni, Cristian, Capalbo, Carmen, Lezzerini, Marco, Pasero, Marco (2014) Ferrihollandite, BaMn4+6Fe3+2O16, from Apuan Alps, Tuscany, Italy: description and crystal structure. European Journal of Mineralogy, 26 (1) 171-178 doi:10.1127/0935-1221/2013/0025-2353 DOI: 10.1127/0935-1221/2013/0025-2353
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Ferrihollandite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/ferrihollandite-43558},
  note      = {Accessed 2026-05-11}
}