Manjiroite

Na(Mn4+7Mn3+)O16
IMA status
  • Approved
IMA symbol
Mji
Discovered
1967
Also known as
  • IMA1966-009
  • Manjiroiet

Where it forms, where it's found

Geological setting

Bedded manganese oxide deposit.

Bedded manganese deposites, also mangabe-rich gossans

Type locality
Kohare mine
  1. Karumai
  2. Iwate Prefecture
  3. Japan
26recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103 – 3.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Dull
Transparency
Opaque
Colour
Dark brownish-gray
Streak
Brownish black
Tenacity
brittle
Cleavage
None Observed

Probably has a good cleavage similar to other minerals in its group.

Fracture
Conchoidal · Sub-Conchoidal
Density
4.29 g/cm³

Optical

Optical type
Uniaxial
UV response
Not fluorescent in UV

Crystallography

Crystal system
Tetragonal
Space group
I4/m
Cell parameters
a = 9.916 Å · c = 2.864 Å
Z
1
Morphology

Frequently botryoidal, sometimes fibrous

Type-locality form

Fine-grained black masses, may break with a conchoidal fracture.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
25MnManganeseManganese854.938439.504
61.17%
8OOxygenOxygen1615.999255.984
35.63%
11NaSodiumSodium122.99022.990
3.20%
Total718.478100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1966-009
  • Manjiroiet

In other languages

German
IMA 1966-009 · Manjiroit
Spanish
Manjiroíta
Italian
Manjiroite
Japanese
万次郎鉱

Classification

Strunz
10th ed.

4.DK.05a

  • 4OxidesClass
  • 4.DMetal: Oxygen = 1:2 and similarDivision
  • 4.DKWith large (+- medium-sized) cations; tunnel structuresGroup
  • 4.DK.05aManjiroiteSpecies
Dana
8th ed.

07.09.01.03

  • 07Multiple OxidesClass
  • 07.09AB8X16Type
  • 07.09.01Cryptomelane Group (Hard black, fine-grained)Group
  • 07.09.01.03ManjiroiteSpecies
CIM

7.2.3

  • 7Oxides and HydroxidesClass
  • 7.2Oxides of the alkali metalsGroup
  • 7.2.3ManjiroiteSpecies

Group, growth & confusion

Often grow together
2 minerals
Commonly confused with
5 minerals

Literature, links & citation

Citations
  1. 1967Nambu, Matsuo, Tanida, Katsutoshi (1967) Manjiroite, a new manganese dioxide mineral, from Kohare Mine, Iwate Prefecture, Japan. The Journal of the Japanese Association of Mineralogists, Petrologists and Economic Geologists, 58 (2) 39-54 doi:10.2465/ganko1941.58.39 DOI: 10.2465/ganko1941.58.39
  2. 1968Fleisher, Michael (1968) New Mineral Names. American Mineralogist, 53 (11-12) 2103-2106
  3. 1979Potter, Russell M., Rossman, George R (1979) The tetravalent manganese oxides: identification, hydration, and structural relationships by infrared spectroscopy. American Mineralogist, 64 (11-12) 1199-1218
  4. 1980Nambu, Matsuo, Tanida, Katsutoshi (1980) Cryptomelane-Manjiroite-Hollandite Series Minerals. Journal of the Mineralogical Society of Japan, 14. 62-85 doi:10.2465/gkk1952.14.special3_62 DOI: 10.2465/gkk1952.14.special3_62
  5. 2013Biagioni, Cristian, Capalbo, Carmen, Pasero, Marco (2013) Nomenclature tunings in the hollandite supergroup. European Journal of Mineralogy, 25 (1) 85-90 doi:10.1127/0935-1221/2013/0025-2255 DOI: 10.1127/0935-1221/2013/0025-2255
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Manjiroite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/manjiroite-2566},
  note      = {Accessed 2026-05-11}
}