Ferrowyllieite

NaNaFe2+(Fe2+Al)(PO4)3
IMA status
  • Approved
IMA symbol
Fwyl
Discovered
1979
Also known as
  • Ferrowyllieiet

Where it forms, where it's found

Geological setting

Large pods in granite pegmatite.

Type locality
Victory Mine
  1. Custer
  2. Custer Mining District
  3. Custer County
  4. South Dakota
  5. USA

43.7825°, -103.5692°

7recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Greenish black · also dark bluish green · dark greenish gray · dark green · dark brown.
Streak
Light gray
Tenacity
very brittle
Cleavage
Perfect

(010) perfect; (101) poor to good

Fracture
Irregular/Uneven
Density
3.601 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 50° · 2V calc = 76°
Refractive index
1.688 – 1.696
Surface relief
High
Principal indices
nα 1.688 · nβ 1.690 – 1.691 · nγ 1.696
Birefringence
0.008
Pleochroism
Strong

X=smoky gray; Y=smoky bluish green; Z=green

Dispersion
r < v strong
UV response
Not fluorescent
Michel-Lévy diagramhighlighted lineδ = 0.0080
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]80 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation80 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
#14
Cell parameters
a = 10.868 Å · b = 12.382 Å · c = 6.354 Å
Ratio a:b:c
1 : 1.139 : 0.585
Z
4
Morphology

Found in primary crystals or masses to over 10 cm which are crystallographically single crystals. Only a few sharp crystals were found amongst the abundance of massive specimens.

Type-locality form

Crude euhedral crystals, to 10 cm, in interlocking aggregates

Comment

P21/n; new axes Am Min (1974) v. 59, p.280-290.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1215.999191.988
40.89%
26FeIronIron255.845111.690
23.78%
15PPhosphorusPhosphorus330.97492.922
19.79%
11NaSodiumSodium222.99045.980
9.79%
13AlAluminiumAluminium126.98226.982
5.75%
Total469.562100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Ferrowyllieiet

In other languages

German
Ferrowyllieit
Italian
Ferrowyllieite
Chinese
磷铝铁钠石

Classification

Strunz
10th ed.

8.AC.15

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.APhosphates, etc. without additional anions, without H2ODivision
  • 8.ACWith medium-sized and large cationsGroup
  • 8.AC.15FerrowyllieiteSpecies
Dana
8th ed.

38.02.04.01

  • 38Anhydrous Normal Phosphates, Arsenates, and VanadatesClass
  • 38.02(AB)5(XO4)3Type
  • 38.02.04Alluaudite-Wyllieite Group (Wyllieite Subgroup)Group
  • 38.02.04.01FerrowyllieiteSpecies
CIM

19.14.5

  • 19PhosphatesClass
  • 19.14Phosphates of Fe and other metalsGroup
  • 19.14.5FerrowyllieiteSpecies

Group, growth & confusion

Literature, links & citation

Citations
  1. 1973Moore, Paul B., Ito, Jun (1973) Wyllieite, Na2Fe2+2Al(PO4)3: a New Species. The Mineralogical Record, 4 (3) 131-136
  2. 1974Moore, Paul Brian, Molin-Case, and JoAnn (1974) Contribution to pegmatite phosphate giant crystal paragenesis: II. The crystal chemistry of wyllieite, Na2Fe2+2Al[PO4]3, a primary phase. American Mineralogist, 59 (3-4) 280-290
  3. 1979Moore, Paul B., Ito, Jun (1979) Alluaudites, wyllieites, arrojadites: crystal chemistry and nomenclature. Mineralogical Magazine, 43 (326) 227-235 doi:10.1180/minmag.1979.043.326.04 DOI: 10.1180/minmag.1979.043.326.04
  4. 1980Fleischer, Michael, Cabri, Louis J., Chao, G. Y., Pabst, Adolf (1980) New Mineral Names. American Mineralogist, 65 (7-8) 808-814
  5. 2005(2005) Ferrowyllieite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Ferrowyllieite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/ferrowyllieite-1536},
  note      = {Accessed 2026-05-11}
}