Wyllieite

NaNaMn(Fe2+Al)(PO4)3
IMA status
  • Approved
IMA symbol
Wyl
Discovered
1972
IMA approved
1972
Also known as
  • IMA1972-015
  • Wyllieiet

Where it forms, where it's found

Geological setting

Zoned, complex granite pegmatites

Type locality
Old Mike mine (Great Northern
  1. Old Mike M.S.2212)
  2. Custer
  3. Custer Mining District
  4. Custer County
  5. South Dakota
  6. USA

43.8183°, -103.6164°

18recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104 – 4.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous · sub-metallic
Transparency
Translucent
Colour
deep bluish-green to deep oily-green · gray-green · to greenish-black
Streak
dirty olive green
Tenacity
very brittle
Cleavage
Perfect

(010) perfect, (101) distinct

Density
3.61 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 90° · 2V calc = 82°
Refractive index
1.685 – 1.692
Surface relief
High
Principal indices
nα 1.685 · nβ 1.688 · nγ 1.692
Pleochroism

Thick plates show pleochroism, X smoky blue-gray, Y smoky bluish-green, Z green. Abs Z>Y>X.

Dispersion
r > v weak
Michel-Lévy diagramhighlighted lineδ = 0.0070
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]70 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation70 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Cell parameters
a = 11.967(2) Å · b = 12.462(3) Å · c = 6.409(1) Å
Cell angles
β = 114.52 ° · γ = 2 °
Ratio a:b:c
1 : 1.041 : 0.536
Z
4
Type-locality form

Masses and crude crystals to 10 cm. Likely previously misidentified as triphylite-lithiophilite.

Comment

Space Group: P21/n

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1215.999191.988
40.96%
15PPhosphorusPhosphorus330.97492.922
19.83%
26FeIronIron155.84555.845
11.92%
25MnManganeseManganese154.93854.938
11.72%
11NaSodiumSodium222.99045.980
9.81%
13AlAluminiumAluminium126.98226.982
5.76%
Total468.655100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1972-015
  • Wyllieiet

In other languages

German
IMA 1972-015 · Wyllieit
Italian
Wyllieite
Chinese
磷铝铁锰钠石

Classification

Strunz
10th ed.

8.AC.15

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.APhosphates, etc. without additional anions, without H2ODivision
  • 8.ACWith medium-sized and large cationsGroup
  • 8.AC.15WyllieiteSpecies
Dana
8th ed.

38.02.04.02

  • 38Anhydrous Normal Phosphates, Arsenates, and VanadatesClass
  • 38.02(AB)5(XO4)3Type
  • 38.02.04Alluaudite-Wyllieite Group (Wyllieite Subgroup)Group
  • 38.02.04.02WyllieiteSpecies
CIM

19.14.4

  • 19PhosphatesClass
  • 19.14Phosphates of Fe and other metalsGroup
  • 19.14.4WyllieiteSpecies

Group, growth & confusion

Often grow together
1 mineral

Literature, links & citation

Citations
  1. 1973Moore, Paul B., Ito, Jun (1973) Wyllieite, Na2Fe2+2Al(PO4)3: a New Species. The Mineralogical Record, 4 (3) 131-136
  2. 1974Fleischer, Michael (1974) New mineral names. American Mineralogist, 59 (1-2). 208-212
  3. 1974Moore, Paul Brian, Molin-Case, and JoAnn (1974) Contribution to pegmatite phosphate giant crystal paragenesis: II. The crystal chemistry of wyllieite, Na2Fe2+2Al[PO4]3, a primary phase. American Mineralogist, 59 (3-4) 280-290
  4. 1979Moore, Paul B., Ito, Jun (1979) Alluaudites, wyllieites, arrojadites: crystal chemistry and nomenclature. Mineralogical Magazine, 43 (326) 227-235 doi:10.1180/minmag.1979.043.326.04 DOI: 10.1180/minmag.1979.043.326.04
  5. 1980Fleischer, Michael, Cabri, Louis J., Chao, G. Y., Pabst, Adolf (1980) New Mineral Names. American Mineralogist, 65 (7-8) 808-814
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Wyllieite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/wyllieite-4321},
  note      = {Accessed 2026-05-11}
}